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The Global ETD Search service is a free service for researchers
to find electronic theses and dissertations. This service is
provided by the
Networked Digital Library of Theses and Dissertations.
Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
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Showing 1 to 2 of 2 (0.102 seconds)Spelling suggestions: "subject:"compostos organometallic (íntese)"" "subject:"compostos organometallic (asíntese)""
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Síntese enantiosseletiva de fenilselenolactonas e feniltelurolactonas / Enantioselective synthesis of phenylselenolactones and phenyltelurolactonesNogueira, Alessandro Leal 07 June 2002 (has links)
Este trabalho descreve uma nova metodologia sintética que combina a química de espécies organometálicas contendo Se e Te com biotransformações usando lipases, para a síntese enantiosseletiva de fenilselenolactonas 7a e feniltelurolactonas 7b. Estas lactonas foram obtidas pela resolução cinética de álcoois secundários racêmicos 6, pela ação da lipase de pâncreas de porco (PPL- Sigma-Aldrich) em meio orgânico anidro. (Ver arquivo PDF). / This work describes a novel synthetic methodology that combines the chemistry of organic compounds, organometalic species containing Se and Te and biotransformations using lipases for the enantioselective synthesis of phenylselenolactones 7a and phenyltelurolactones 7b. These lactones were obtained by kinetic resolution of racemic sec-alcohols 6 by the action of pig pancreatic lipases (PPL- Sigma-Aldrich) in organic media (Scheme1). (See files PDF)
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Síntese enantiosseletiva de fenilselenolactonas e feniltelurolactonas / Enantioselective synthesis of phenylselenolactones and phenyltelurolactonesAlessandro Leal Nogueira 07 June 2002 (has links)
Este trabalho descreve uma nova metodologia sintética que combina a química de espécies organometálicas contendo Se e Te com biotransformações usando lipases, para a síntese enantiosseletiva de fenilselenolactonas 7a e feniltelurolactonas 7b. Estas lactonas foram obtidas pela resolução cinética de álcoois secundários racêmicos 6, pela ação da lipase de pâncreas de porco (PPL- Sigma-Aldrich) em meio orgânico anidro. (Ver arquivo PDF). / This work describes a novel synthetic methodology that combines the chemistry of organic compounds, organometalic species containing Se and Te and biotransformations using lipases for the enantioselective synthesis of phenylselenolactones 7a and phenyltelurolactones 7b. These lactones were obtained by kinetic resolution of racemic sec-alcohols 6 by the action of pig pancreatic lipases (PPL- Sigma-Aldrich) in organic media (Scheme1). (See files PDF)
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