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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Espectroscopia de impedância em Fe3O2BO3 e α-MnO2 dopado com cobre / Impedance spectroscopy in Fe3O2BO3 and α-MnO2 doped with copper

Silva, Everlin Carolina Ferreira da [UNESP] 29 February 2016 (has links)
Submitted by EVERLIN CAROLINA FERREIRA DA SILVA null (everlinferreira@hotmail.com) on 2016-04-19T16:13:05Z No. of bitstreams: 1 DissertaçãoFinal.pdf: 3642722 bytes, checksum: f19af99a16e56b2846a689e39c66c05b (MD5) / Approved for entry into archive by Ana Paula Grisoto (grisotoana@reitoria.unesp.br) on 2016-04-20T19:11:13Z (GMT) No. of bitstreams: 1 silva_ecf_me_rcla.pdf: 3642722 bytes, checksum: f19af99a16e56b2846a689e39c66c05b (MD5) / Made available in DSpace on 2016-04-20T19:11:13Z (GMT). No. of bitstreams: 1 silva_ecf_me_rcla.pdf: 3642722 bytes, checksum: f19af99a16e56b2846a689e39c66c05b (MD5) Previous issue date: 2016-02-29 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / A técnica de espectroscopia de impedância foi aplicada para caracterizar um monocristal da ludwigita homometálica Fe3O2BO3, em que uma transição de ordenamento de carga (CO) ocorre em temperatura ambiente (~ 300 K) conforme reportada na literatura. Utilizando diferentes valores de amplitude do sinal AC aplicado, pudemos pelo estudo do comportamento da condutividade AC identificar nessas medidas o fenômeno de soltura de ondas de densidade de carga (CDW) e usamos a teoria de Bardeen, na faixa de temperatura em que foi possível aplica-la, para obter a razão entre a massa do condensado MF e a massa m do elétron, da ordem de 109 - 107. As características deste material foram comparadas a uma amostra de um sistema sem ordenamento de carga reportada, uma pastilha prensada de α-MnO2 dopado com cobre. Para ambos os materiais informação sobre o comportamento da constante dielétrica também foi obtido. / The impedance spectroscopy technique was applied to the characterization of a single crystal of the homometallic ludwigite Fe3O2BO3, in which a charge ordering transition (CO) occurs around room temperature (~ 300K), as reported in the literature. By using different values of the AC amplitude signal we could study the AC conductivity behavior and identify the depinning of the charge-density wave phenomenon (CDW). Applying the Bardeen theory, in a proper temperature range, to obtain the rate of the mass of the condensate MF in relation to that of the electron m, we found a ratio the order of 109 - 107 . The characteristics of this material were compared with a system without reported charge ordering transition, Cu doped α-MnO2 pressed pellets. For both materials, information about the behavior of the dielectric constant was also obtained.

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