The geology of the Shamrocke area is described relative to its regional setting and position within the stratigraphic succession of the Lomagundi System. The stratigraphy in the immediate vicinity of the Shamrocke Mine is detailed and discussed relative to the work of others south of the project area and in other regions. The petrography of the rocks of the Shamrocke Mine area is described and the results of a great deal of mineralogical work recorded. Maps of the project area are presented at various scales from field and photogeological evidence. The thesis area is situated on the South Zambezi Escarpment of Rhodesia, and the geology described included the basaI succession of the Lomagundi System and the pre-Lomagundi Escarpment Series. The Shamrocke Mine is located on a copper orebody associated with a granulite or granofels zone within the Dolomite Series of the Lomagundi System. This ore zone granulite appears to be a metasomatised calcareous grit some 1000 feet above the upper contact of the Deweras Series (basal Lomagundi) and, within the graphitic schist and phyllite, below a dolomitic horizon in the Dolomite Series. The Lomagundi succession in the Mine area unconformably overlies the pre-Lomagundi gneiss and meta-arkose of the older, metamorphosed and deformed Escarpment Series. The basal meta-arkose, meta-quartzite and coarse schist of the Deweras Series ascends southwards through the Dolomite Series (graphitic phyllite and schist, granulite, calcareous grit, dolomite, limestone), and the Argillaceous Series (schist, phyllite, quartzite), the beds dipping steeply to the south at an angle of between 50º and 70º. Post-Lomagundi plagioclase amphibolite (altered, intrusive meta-diabase) forms Iarge semi-concordant and transgressive sills throughout the area, particularly along the contact between the Deweras and Dolomite Series. The Shamrocke Mine is on the northern limb of a large synclinal structure, the Rusere Syncline, which forms a large embayment of Lomagundi rocks into the pre-Lomagundi gneisses and granodiorites northeast from the Mine. The fold is overturned to the east and southeast. The copper mineralisation within the area and in the areas to the south is considered to be invariably associated with the basal rocks of the Lomagundi System. It occurs within both the Deweras and Dolomite Series rocks and more often than not Iies close to the contact between these two Series. The sulphide mineralisation of the Shamrocke orebody is considered, from the results of the present study, to be metasomatically emplaced during carbonate metasomatism, either from an extraneous source or from within the ore zone rock itself. The present writer favours the origin of the copper sulphide to be original syngenetic sulphide of the basal rocks of the Lomagundi depository, which has been mobilised and metasomatically relocated, possibly by the effects of regional metamorphism related to intense deformation. It is perhaps not fortuitous that the majority of the copper occurrences in the area occur where the basaI beds of the succession have been cross-folded. The copper ore comprises a simple suite of minerals, the main constituents being chalcopyrite, cubanite and pyrrhotite. The deposit is compared relative to the other copper deposits of the Lomagundi System.

The Kluane Ranges are underlain by a sequence of stratified rocks ranging in age from Permian to Triassic, cut by .Cretaceous and Tertiary intrusions. Flow and pyroclastic rocks of Lower Permian Station Creek Formation were probably part of a volcanic arc environment. Argillaceous and tuffaceous rocks of the Transition Zone of Station Creek Formation and overlying sedimentary rocks of Lower Permian Hasen Creek Formation were deposited in a subaqueous environment, possibly a back-arc basin. Upper Triassic basalts of the Nikolai Greenstone are largely subaerial and were probably a product of rift volcanism. Lower Triassic Kluane gabbro-ultramafic complexes are sill- or sheet-like bodies, divisible into a Lower Group (within the Transition Zone) that consist of peridotite and dunite with associated nickel-copper sulphide deposits, and an Upper Group (within Hasen Creek rocks) that consist of gabbro and peridotite but with no known associated nickel-copper deposits. The ultramafic rocks are piagioclase-bearing and chemically are pyroxenitic and peridotitic komatiites. Bulk chemical composition of the Quill Creek complex is similar to that of pyrolite and calculations show the complex could have formed from an upper mantle diapir, affected by 40 percent partial melting and composed of residual olivine crystals and ultramafic liquid. Prominent copper lode deposits in the Kluane Ranges include: (1) vein and disseminated types in Station Creek volcanic rocks; (2) nickel-copper associated with Kluane complexes; and (3) vein-type in the Nikolai Greenstone. A narrow, positive range of sulphur isotopic compositions for vein sulphides in Station Creek Formation contrast sharply with a large range for those in the Nikolai Greenstone. The former deposits resulted from only local mobilization of sulphur (and metals) during metamorphism in a closed system, whereas mineralization in the Nikolai Greenstone involved considerable variation in chemical parameters of ore fluids in an open system with more than one source of sulphur. Anomalously negative sulphur isotopic values for nickel-copper sulphide bodies resulted from contamination of magmatic sulphur by 30 to 60 percent sulphur from wall rocks. Much of this contamination occurred prior to or during segregation of an immiscible sulphide liquid as at Quill Creek, with further contamination during injection of still liquid sulphide bodies into footwall rocks in the case of Canalask deposit. Substantial contaminant.sulphur may have been crucial in achieving sulphur saturation of magmas of Lower Group Kluane complexes and subsequent formation of associated nickel-copper sulphide deposits. Isotopic data for both magmatic sulphides and sulphur-bearing country rock support a strong case for a general sulphur contamination model for nickel-copper deposits related to mafic and ultramafic intrusions on a worldwide scale. Pyrite in wallrock is considered to be the most likely general source of sulphur contributed to ultramafic magmas and several different stages of sulphur contamination are possible throughout consolidation of the magmas and its associated sulphides. Sulphur transfer to the magma can occur by bulk country rock assimilation or by fluid ingress where the fluid derives sulphur from the contact zone by incongruent melting of pyrite or by complete dissociation of pyrite. Important features of this model, having economic implications, are: (1) emplacement of the ultramafic complex as a magma; (2) presence of sulphur-bearing country rocks; and (3) presence of a sulphur-depletion halo adjacent to the ultramafite. / Science, Faculty of / Earth, Ocean and Atmospheric Sciences, Department of / Graduate

No description available.

The Cenozoic Ailaoshan – Red River shear zone marks the present day western margin of the South China Block. Along this margin are well preserved late Paleoproterozoic to early Neoproterozoic sedimentary and volcanic successions. This work examines the ages and tectonic environments for the formation of the successions, as well as significance of the regional tectono-magmatic events on the formation of widespread iron oxide-copper deposits. The oldest succession is the Paleoproterozoic Dahongshan Group. A new SHRIMP UPb age of 1675 ± 8 Ma for a tuffaceous schist unit confirms its Paleoproterozoic age. Detrital zircon ages of the Dahongshan Group range between Archean to Paleoproterozoic (ca. 2780 – 1860 Ma). They include a population of ca. 2400 – 2100 Ma grains, which have no known source region on the exposed Yangtze Block. Previous geochemical studies of metavolcanic rocks from the Dahongshan Group have suggested that these rocks were erupted in an oceanic setting. However, this study shows that the metavolcanics are extremely altered and cannot be used for reliable tectonic discrimination. Based on the characteristics of sedimentary rocks in the Dahongshan Group, it is suggested that these rocks were deposited in a continental setting. Overlying the Dahongshan Group is a thick sedimentary sequence which has been variably termed the Kunyang, Dongchuan, Huili or Xide Groups. In the past, these rocks have been considered as a Mesoproterozoic rift succession. However, no precise age constraints were available for the succession. In this study, this sequence is found to contain at least two separate tectonostratigraphic units. The oldest (ca.1140 Ma) is comprised of alkaline basalt with a geochemical and isotopic character similar to that of modern intracontinental rift basalts. The presence of Cathaysia-derived sediments in this unit indicates sedimentary transportation from the southerly Cathaysia Block to the northerly Yangtze Block (in present coordinates) in South China at that time, which suggests an “impactogen” scenario. The thick sedimentary sequence of what has traditionally been defined as the Kunyang Group has been found to have significantly younger depositional age of ca.1000 – 960 Ma. The composition of sedimentary rocks and the provenance of detrital zircons from the Kunyang Group are consistent with a foreland basin setting. The depositional age of this sequence coincides with the timing of Sibao Orogeny as determined elsewhere in the South China Block. Summary Page ii Numerous iron oxide - copper (gold) deposits occur within the rocks of the Dahongshan and Kunyang Groups. Previous studies have classified these deposits into two deposit styles: the Dahongshan-type Paleoproterozoic VMS mineralisation hosted within the Dahongshan Group, and the Dongchuan-type diagenetic carbonate and shale-hosted deposits hosted within the Kunyang Group. However, both deposit types share similarities with the iron oxide – copper (gold) deposit class, such as stratabound disseminated and massive copper ores, abundance of iron oxide occurring mostly as low Ti - magnetite and haematite, and variable enrichments in Au, Ag, Co, F, Mo, P and REE. 40Ar/39Ar data from both deposit types indicate mineralisation ages of ca. 850 – 830 Ma and 780 – 740 Ma.

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Abstract At least 30 gold deposits verified by means of one or more notable diamond drill hole results have been discovered in Central Lapland in the last 20 years, and these can be divided spatially into groups, between which the metal composition varies. The deposits contain varying amounts of sulphides and sulpharsenides as well as gold. Pyrite is the most common sulphide mineral in the gold deposits associated with volcanic rocks, and usually pyrrhotite in those associated with sedimentary rocks. The principal sulphide minerals in those connected with banded iron formations are pyrite and arsenopyrite. A separate group of formations consists of the palaeoplacer gold deposits associated with the molasse-like quartzites and conglomerates of Central Lapland. The iron oxide-copper-gold deposits of Central Lapland, which are a significant potential source of copper and gold, are mostly associated with skarn rocks at the eastern contact of the acidic intrusive rocks of Western Lapland and with skarn rocks occurring as interlayers in metavolcanic and metasedimentary rocks. The gold deposits that have led to actual mining activities in Central Lapland are Saattopora in Kittilä and Pahtavaara in Sodankylä. Apart from the Laurinoja iron oxide-copper-gold ore body in Kolari, copper concentrate has been produced from the Saattopora gold ore deposit and the Pahtavuoma copper ore deposit. Only one gold ore in Central Lapland is being actively exploited at present, that of the Pahtavaara mine, which was worked in 1995–2000 and reopened in 2003. The best starting point for successful gold ore exploration in Central Lapland can be achieved through a thorough knowledge of the deformation zones and their structures and alteration processes and the application of geochemical methods. Magnetic surveys can be of help in identifying and locating deformation zones of interest for exploration purposes and the majority of the associated shear zones and faults. Ore-critical zones usually feature graphite-bearing schists and iron sulphide-bearing sequences that can be traced by electrical methods and used as marker zones to verify the results of geological mapping. Geological, geophysical and geochemical techniques have been used in great diversity, and in particular till geochemistry and bedrock drilling have been methods by which the gold and copper deposits in Central Lapland have been discovered. A total of 7.6 million tonnes of gold and copper ores, including the Laurinoja iron oxide-copper-gold ore, were extracted in Central Lapland over the period 1982–2000. The resulting production of gold during this period was 10 800 kg, together with 21 000 tonnes of copper in concentrates and 4500 kg of silver. The gold and copper ores have been concentrated by gravity separation and/or flotation, since the ores so far taken into production has been of the free milling type. However, a substantial proportion of the deposits in the area contain copper, nickel, cobalt and arsenic as well, in the form of sulphides or sulpharsenides, so that the achievement of commercially saleable products calls for the use of different leaching processes. Deposits have also been found in Central Lapland that have consisted partly or entirely of refractory gold ore in which gold is lying in the crystal lattice of pyrite and/or arsenopyrite, the processing of which by the above-mentioned methods is not economic, as it requires pre-treatment by bio-oxidation or pressure oxidation in order to convert the gold to a cyanide-soluble form.

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No description available.