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Fertilizer P accumulates in soils, with potential for movement to waterways, causing eutrophication. Fertilizer P reactions in monoculture corn (Zea mays L.) production over time will determine environmentally sound soil management practices. Soil P changes over time were determined on a Chicot sandy clay loam (Grey Brown Luvisol) and a Ste. Rosalie clay (Humic Gleysol). Fertilizer P was added at 44 and 132 kg P ha$ sp{-1}$ and to the Chicot soil only, manure containing 60 kg P for the first five years. Mehlich-3 (M3) extraction, soil P fractionation, $ sp{31}$P NMR analysis, P in leaching water, and path analysis were measured. Added P increased M3 P more when manure was also added, and in clay soils. To increase M3 P by 1 kg ha$ sp{-1}$ required from 3.6 to 8.1 kg ha$ sp{-1}$ fertilizer P, and when "net" fertilizer additions were used, fertilizer required was from 1.8 to 5.3 kg P ha$ sp{-1}.$ Moderately labile organic P (Po) decreased at 0 added P. With P at the rate of plant removal, inorganic (Pi) and Po fractions were unchanged. Excess P increased labile P and resistant P through moderately labile Pi. More P remained in labile Pi fractions when manure P was added, or in the soil with the higher clay content. Soil organic P levels increased upon fertilization only in the sandy loam soil. Labile and moderately labile Po could be estimated using monoester phosphate values determined by $ sp{31}$P NMR. Inorganic P values in gravitational water increased above 0.05 mg P L$ sp{-1}$ when soil labile Pi increased above 108 mg kg$ sp{-1}$ in the sandy loam soil and 69 mg L$ sp{-1}$ in the clay soil. Thus soil P movement was related to inorganic P additions. Increased fertilizer P did not increase organic P leaching losses. Fertilizer P in corn production may result in groundwater eutrophication.

Typescript. / Thesis (Ph. D.)--University of Hawaii at Manoa, 1980. / Bibliography: leaves [207]-216. / Microfiche. / xvi, 216 leaves, bound ill. 28 cm

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Typescript (photocopy). / Digitized by Kansas Correctional Industries

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Fertilizer applications of urea and triple superphosphate (TSP) suffer from low efficiency for corn production. Band or broadcast application of urea with acidic-P fertilizers may increase fertilizer efficiency. Urea and acidic-P fertilizer interactions in soil-fertilizer microsites were investigated using two Quebec soils. Adding acidic phosphates such as TSP and monoammonium phosphate (MAP) to urea reduced pH in microsites, urea hydrolysis, NH$ sb3$ volatilization, and increased soil NH$ sb4$- and NO$ sb3$-N contents. Ammonia loss decreased as P$ rm sb2O sb5$: urea-N ratios increased. Adding urea to P fertilizer increased soil pH and P sorption when using CaCl$ sb2$ as the electrolyte. Urea application increased 0.5 M NaHCO$ sb3$ extractable P. Banding urea with TSP caused dissolution of organic matter in soils, and increased P diffusion and P concentration in soil solution sampled with filter paper or in 1 M KCl extraction. Two years of field experiments demonstrated that banding urea with TSP or MAP increased soil extractable P (Mehlich-3), N and P nutrient uptake, plant growth and development of corn. Greater P fertilizer efficiencies and higher yields were achieved by banding urea-acidic P fertilizers.