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The synthesis and chemistry of cyclic dienones and related compoundsWilliams, J. G. January 1988 (has links)
No description available.
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The photochemistry of two 4,4-dinaphythyl subsituted 2,5-cyclohexadienonesLynch, Doreen Catherine. January 1985 (has links)
Thesis (Ph. D.)--University of Wisconsin--Madison, 1985. / Typescript. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references.
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Cyclohexadienones as intermediates in gibberellin synthesisJohnson, David Westley. January 1975 (has links) (PDF)
No description available.
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Enantioselective conjugate addition reactions to α,β-unsaturated-α,γ-substituted-2,5-cyclohexadienonesMulligan, Kirk Michael 03 December 2007
Enantioselective conjugate addition (ECA) reactions between organometallic reagents and cyclohexadienone 165 are being investigated. Previous studies have shown that ECAs, of organometallic reagents to á,â-unsaturated cyclohexadienones, are useful in many natural product syntheses. The substrates used in earlier studies were simple 2,5-cyclohexadienones, with a proton at the C-3 position, resulting in the synthesis of a trisubstituted C-3 atom. ECAs that afford all-carbon quaternary stereogenic centers are a much more challenging problem and few examples have been reported. Some natural products contain a ã-hydroxy group, however, no ECA substrates have incorporated this motif. ECAs have been accomplished with substrates having a g-ether substituent. The cyclohexadienone 165 system presents three challenging problems to overcome for an ECA reaction: the tertiary methyl substituents at the 3 and 5 positions, facial selectivity and enantioselectivity. An ECA to 165 using an organoaluminum reagent and an external chiral ligand 26 was successful in producing a product that showed the reaction was moderately stereoselective. A diastereoselective conjugate addition reaction (DCA) to 165 using a chiral auxiliary 68 was also successful in producing a product that showed the reaction was moderately enantioenriched. Lastly, a variable temperature NMR study was performed to establish the presence of dynamic motions of the C=N bond present in sulfinyl imines 229 and 230. As a result, the sulfinyl imines 229 and 230 were found to be interconverting at -78°C.
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Enantioselective conjugate addition reactions to α,β-unsaturated-α,γ-substituted-2,5-cyclohexadienonesMulligan, Kirk Michael 03 December 2007 (has links)
Enantioselective conjugate addition (ECA) reactions between organometallic reagents and cyclohexadienone 165 are being investigated. Previous studies have shown that ECAs, of organometallic reagents to á,â-unsaturated cyclohexadienones, are useful in many natural product syntheses. The substrates used in earlier studies were simple 2,5-cyclohexadienones, with a proton at the C-3 position, resulting in the synthesis of a trisubstituted C-3 atom. ECAs that afford all-carbon quaternary stereogenic centers are a much more challenging problem and few examples have been reported. Some natural products contain a ã-hydroxy group, however, no ECA substrates have incorporated this motif. ECAs have been accomplished with substrates having a g-ether substituent. The cyclohexadienone 165 system presents three challenging problems to overcome for an ECA reaction: the tertiary methyl substituents at the 3 and 5 positions, facial selectivity and enantioselectivity. An ECA to 165 using an organoaluminum reagent and an external chiral ligand 26 was successful in producing a product that showed the reaction was moderately stereoselective. A diastereoselective conjugate addition reaction (DCA) to 165 using a chiral auxiliary 68 was also successful in producing a product that showed the reaction was moderately enantioenriched. Lastly, a variable temperature NMR study was performed to establish the presence of dynamic motions of the C=N bond present in sulfinyl imines 229 and 230. As a result, the sulfinyl imines 229 and 230 were found to be interconverting at -78°C.
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Cyclohexadienones as intermediates in gibberellin synthesis / by David JohnsonJohnson, David Westley January 1975 (has links)
iii, 143 leaves : diags ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Thesis (Ph.D.)--University of Adelaide, Dept. of Organic Chemistry, 1976
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Cyclohexadienones as intermediates in gibberellin synthesis /Johnson, David Westley. January 1975 (has links) (PDF)
Thesis (Ph.D.) -- University of Adelaide, Department of Organic Chemistry, 1976.
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