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(¤@) Photolytic Study of 2-Azido-1-(2-pyridinyl)ethan- one and Its Derivatives (¤G) Pyrolytic Study of 2-(Azidomethyl)pyridine and Its Derivatives (¤T) Pyrolytic Study of 2-Cyclohexeno[b]furylmethyl BenzoateSong, Yu-Huei 09 August 2011 (has links)
¤@. Photolysis of 2-azido-1-(2- pyridyl)ethanone (68),2-azido-1-(3-pyridyl)ethanone)
(69),2-azido-1-(1-methyl-2-pyrryl)ethanone (53) and 2-azido-1-(1-methyl-3-indo yl)ethanone gave Norrish products (71, 7 3-76), (84-86, 89), (92-94) and (93, 95-98).
¤G. Pyrolysis of 2-(azidomethyl)pyridine (9) and 4-(azidomethyl)pyr idine (10) gave the expected products 1,3,5-tri-2-pyridyl-2,4-diaza-1,4-pentadiene (13) and 1,3,5-tri-4-pyridyl-2,4-diaza-1,4-pentadiene (21).
¤T. Pyrolysis of 2-cyclohexeno[b]furylmethyl benzoate (31) gave 2-methylbenzo[b]-
furan (40) and benzene products.
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