Two major pillars of the state responsibility system are administrative losses compensation system and national compensation system. The ¡§Destruction Fire Operation¡¨ which causes innocent third person¡¦s property loss forms administrative losses compensation responsibility or national compensation responsibility promptly. The fire protection law in Taiwan has been revised and enlarged the 19th item 2 since August, 1995. From the view of protecting people¡¦s right, it is admirable to compensate people propriety loss caused by disaster. However the related compensation stipulate seems not enough. The essay based on legal principle state responsibility researches the national compensation responsibility of the ¡§Destruction Fire Operation¡¨. Meanwhile, we confirm it is true that the theory and practice are agreed with from two cases happened in Kaohsiung county. The essay researches the motive, the range and restriction, the structure and method. We have detail description on the meaning of the ¡§Destruction Fire Operation¡¨ compensation responsibility as well as extended compensation responsibility resulted from fire-fighting. We analyze and discuss the current legal provisions of ¡§Destruction Fire Operation¡¨, and practices of fire operation compensation and compensation cases.