The present manuscript discusses the use of two diesel injections in diesel-ignited propane dual fuel Low Temperature Combustion (LTC). Using propane fumigation into the intake runners of a single cylinder research engine, the maximum and minimum percent energy substitution (PES) values were obtained to be 90% and 53%, respectively at 3.3 bar BMEP. An optimal PES value of 80% was used to explore the effects of a secondary injection on the engine-out emissions. The secondary injection proved to have a strong influence on combustion phasing (CA50). As combustion is phased closer to TDC the IFCE shows and increase of 4% at 5 bar BMEP and 6% at 3.3 bar BMEP. Finally, a relationship between the IFCE and the CO to CO2 conversion was developed. An increase in the carbon to hydrogen ratio of the fuel shows a reduction of the CO output of the engine while the CO2 concentration increases. More importantly however, the CO to CO2 conversion shows a direct effect on the IFCE. It is shown that a decrease in CO emissions found in the engine-out emissions will correlate directly with an increase in the IFCE.