Thesis (M.S.)--University of North Carolina Wilmington, 2007. / Includes bibliographical references (Leaves: [131]-137)

Thesis (M.S.)--University of North Carolina Wilmington, 2009. / Title from PDF title page (January 19, 2010) Includes bibliographical references (p. 62-65)

Thesis (PhD) -- Stellenbosch Univesrsity, 1972. / The Darling batholith is characterised by large scale hybridisation, but mainly consists of the coarsely porphyritic Darling granite. This granite changes gradationally into a biotite-rich variety which occupies a roughly elliptical area with a major, northwesterly trending axis of 30 km. The biotite granite envelops a large irregular body of hybrid granodiorite. Small intrusions of younger granite occur within the batholith namely the Klipberg and Contreberg granites and possibly the biotite-rich Dassenberg granite. Dassen Island is underlain by fine-grained granite which could be related to either the younger or coarsely porphyritic granites. A prominent northwesterly trending mylonite zone can be traced through Darling to Swartberg, and ultimately to Trekoskraal in the Saldanha batholith, but is not continuous since it occasionally changes into gneissic granite and is also interrupted by the younger intrusives. Quantitative mapping included measurement of matrix grain size, average maximum phenocryst length, xenolith distribution density, quartz nodule distribution density and average size, lineation, dark mineral index and gneissosity. On Dassen Island the distribution of tourmaline nodules was , determined. The results are displayed as small scale contour maps which show strong correlation between the various parameters. The average values of matrix grain size, average phenocryst length and xenolith distribution density are respectively 2-5mm, 20-60mm and 0-1,5 per m² for the Darling granite, and 1-2 mm, 5-20 mm and 1-9 per m² for the hybrid granodiorite. It was found that the matrix grain size decreases with increase in hybridisation. The spotty distribution pattern of tourmaline nodules on Dassen Island indicates addition of boron by assimilation of metamorphites and a late stage liquid immiscibility process. The granites :.have normal mineralogy and the K-feldspar of the phenocrysts is maximum microcline (Δ = 0,9 - 1,0). The hybrid granodiorite contains much pinitised cordierite and locally garnet. The deeply pleochroic bioti te is probably of the 2M1 polytype and has a higher Fe:Mg ratio in the hybrid granodiorite than in the granite (2,8 - 3,0 vs. 2,2 - 2,3). The intimately associated chlorite seems to be of the Ia polytype. The cordierite is of the normal and low temperature type with average intensity index of 2,7 , distortion index of 0,3 and 2 a of 63°. The xenoliths are predominantly quartzitic metagraywackes, but lime-rich types holding sphene and diopside were occasionally encountered. Thirteen new chemical analyses and thirty-one previously published analyses are used to calculate average composite analyses of the various rock types. The results of calculations employing Barth standard cell values indicate that the hybrid granodiorite could have originated by reaction between granite magma and Malmesbury quartzitic metagraywacke and pe-lite with a little limestone. A "granite differentiation index" based on weight percentages of (Ti02 + MgO + FeO + Fe2O3) and (Si02 + Na2O + K2O) shows a linear relationship between the granites in probable order of age. The magmatic differentiation trend is separated from the hybridisation trend on a 6alk - 2(al - alk) - (100 - 2al) diagram. Mesonorms and their cordierite variants are used to effect comparison with the experimental granitic system of von Platen (1965). The Darling and Contreberg granites plot near the relevant cotectic surfaces. A pilot experimental study of melting behaviour indicates that the Contreberg granite is closer to a minimum melt composition than the Darling granite. Comparison of alkali values with a M Na2O - M K2O Schreinemakers diagram of Korzhinskii (1959), shows that the alkali ratio of the older analyses may be incorrect, and indicates that the dark minerals have a greater effect on plagioclase composition than the amount of K-feldspar. The classification of granites by means of Harpum diagrams is shown to have little relevance to the reconstruction of the ancient thermodynamical variants. The Darling granite is correlated with the Hoedjies Point granite of the Saldanha batholith and on geochronological evidence probably corresponds in age (500- 600 m.y.) with the Cape Peninsula granite. The younger granites of Darling are tentatively correlated with the Cape Columbine granite of the Saldanha batholith. The northeastern boundary of the Darling batholith is a major fault, the Colenso fault, which is considered to extend as far as Northwest Bay, Saldanha. It is proposed that the Darling batholith occupies a down-faulted block within a graben and that the hybrid granodiorite represents a remnant synform of the roof rocks intruded by the granite. The younger granites constitute only four percent by volume of the batholith and may represent anatectic melts from a nearby subjacent source.

Thesis (MSc)--University of Stellenbosch, 2007. / ENGLISH ABSTRACT: The aim of the study is to ascertain whether geochemical exploration techniques can be used in the search for tanzanite deposits in the Merelani area, NE Tanzania. Previous studies have successfully demonstrated a partial extraction method (in situ soil leaching) in identifying prospective ultramafic bodies at the Rockland ruby mine in the Mangare area, Kenya, thereby demonstrating the usefulness of geochemical methods in gemstone exploration. In this study, a partial extraction as well as a whole-rock geochemical method was used to determine the applicability of these methods in prospecting for tanzanite mineralisation using different sampling media, such as soil, stream sediment and calcrete. It is possible that this geochemical approach may not be as effective as physical methods such as the separation and examination of heavy mineral suites. However, its viability needs to be evaluated due to the potential efficiency and relative logistic ease of the method. In essence the scientific method employed is to compare overburden (soils, stream sediments and calcrete) chemistry with known underlying geology, the latter having been established via diamond core drilling. A positive correlation would allow the prediction of overburden covered tanzanite mineralisation. Soil samples were collected from a trench dug perpendicular to regional lithological strike over both barren and tanzanite-bearing horizons. XRF trace element data for the soils was compared to the chemistry of the underlying lithologies. ICP-AE data derived from 1 molar HCL soil leachate (12 hour leach) and soil XRF data, from the same samples, was compared, using a mass balance index, to discern any hydromorphic dispersion of selected trace elements and to evaluate the leachate as a viable alternative to XRF analysis. In general, a good correlation exists between the soil and rock trace element data profiles over the length of the section. However, Ti- and Zr-normalised mass balance calculations show some down-hill drift, but this does not disrupt the overall pattern. The ICP-AE acid leach data show that hydromorphic dispersion is low, that the trace elements of interest (V, Cr, Ni and Cu) are hosted within non-soluble phases. Consequently, the leach technique is not a viable alternative to XRF analysis of the soils. XRF analysis of the soils was shown to be potentially useful in identifying new areas of mineralisation as the soils overlying a graphitic calc-silicate schist, that always occurs adjacent to the tanzanite mineralisation in the Merelani area, was found to be easily identifiable based on anomalous concentrations of V. An exploration concession was chosen for stream sediment sampling on the basis of the presence of large streams, of a few tsavorite mines indicating high prospectivity for tanzanite, and because of a variation in geology on the property. Tanzanite and tsavorite are cogenetic in the known tanzanite deposits. In this case the aim was to investigate the possible occurrence of tanzanite-like geochemical anomolies (i.e. the anomalous V observed in the soil chemistry investigation) could be detected in the vicinity of the tsavorite mines. Tsavorite, the gem variety of grossular garnet, also contains high concentrations of V. The samples were analysed by XRF whole-rock methods for trace element content. The data shows a number of clear positive V anomalies in the study area. The data also shows that each of the existing or abandoned mines in the area is marked by a positive V anomaly. This section of the study also demonstrated a relatively low degree of stream sediment dispersion of the trace elements of interest – most likely a function of the semi-arid climate. The fine fraction (<90μm), however was shown to be mobilised to a relatively larger degree than the coarse (180μm – 300μm) and medium (90μm - 180μm) fractions. As is predictable from the leachate analysis, factor analysis of the data shows that the trace elements are dominated by heavy mineral geochemistry and that a study in heavy mineral exploration might provide a cheaper and more viable option to those explored in this study. Calcrete samples were taken from an abandoned, 10m deep mine shaft, which was sunk through the calcrete to reach the tanzanite deposit. The shaft was sampled from the bottom, closest to the tanzanite mineralisation, to the surface to investigate the association between trace element geochemistry and proximity to the deposit. There was no vertical association between the trace element geochemistry of the calcrete and proximity to the tanzanite deposit. There was also no clear indication in the geochemistry of the calcrete of the existence of the tanzanite deposit beneath it. This further indicates the immobility of the elements of interest in this environment. This study has demonstrated that properly constrained soil and stream sediment geochemical studies may be of use in tanzanite exploration. However, it must be stressed that this is only the case if the geochemical signature of the lithological package associated with the mineralisation is unique and well known. / AFRIKAANSE OPSOMMING: Die doel van hierdie studie is om te bepaal of geochemiese eksplorasie tegnieke vir die soek na tanzaniet afsettings in die Merelani area, noord-oos Tanzanië, gebruik kan word. Voorige studies het gewys dat ‘n gedeeltelike ekstraksie metode (in situ grond looging) gebruik kon word om prospektiewe ultramafiese liggame by the Rockland rubyn myn in die Mangare area, Kenia te identifiseer. Hierby is gedemonstreer dat geochemiese eksplorasie metodes suksesvol in edelsteen eksplorasie toegepas kan word. In hierdie studie is ‘n gedeeltelike ekstrasksie en heel-rots geochemiese metodes gebruik om die toepaslikheid van hierdie metodes op tanzaniet eksplorasie te toets. Verskillende geologiese materiale is gemonster, naamlik grond, stroom sedimente en kalkreet. Dit is moontlik dat hierdie geochemiese benadering nie so effektief soos fisiese metodes soos swaar mineraal skeidings mag wees nie. Dit is nogtans belangrik om die toepaslikheid van hierdie metodes op tanzanite eksplorasie te toests, as gevolg van die potensiële effektiwiteit en relatiewe logistiese gemak van die metodes. Die essensie van die wetenskaplike metodiek wat in hierdie studie gebruik is, is om die geochemie van die grond, stroom sedimente en kalkreet te vergelyk met die geochemie van die onderliggende geologie wat deur middel van diamant boorwerk vasgestel is. ‘n Positiewe korrelasie sou dan dui op ‘n bedekte tanzaniet afsetting. Grond monsters is van ‘n sloot geneem wat loodreg op die strekking van die tanzaniet gemineraliseerde en ongemineraliseerde horisonne gegrawe is. XRF spoor element data van die gronde is vergelyk met die chemie van die onderliggende gesteentes. IGP-AE data wat bekom is deur die monsters met 1 molaar HCl te loog (12 uur loging) is vergelyk met XRF data van dieselfde monsters deur middel van ‘n massa balans indeks om te bepaal of daar enige hidromorfiese dispersie van sekere spoor elemente is en om die toepaslikheid van loging as ‘n alternatief tot die heel-rots metode te bepaal. In die algemeen is daar ‘n goeie korrelasie tussen die grond en rots spoor element data profiele oor die lengte van die seksie. Alhoewel, Ti- en Zr-genormaliseerde massa balans data profiele wys dat daar ‘n mate van afwaartse beweging van grond na die voet van die heuwel is, maar dat hierdie ‘n breuk in die algemene patroon vorm nie. Die IGP-AE data dui daarop dat die hidromorfiese verspreiding van spoor elemente laag is en dat die spoor elemente wat van belang is (V, Cr, Ni en Cu) in nie-oplosbare fases gesetel is. Gevolglik is die logings metode nie ‘n toepaslike alternatief tot die heel-rots XRF metode op gronde nie. XRF analises op die gronde het gewys dat die XRF metode moontlik nuttig kan wees om nuwe areas van tanzanite mineralisasie aan te dui, omdat die gronde wat ‘n grafietiese kalk-silikaat skis oorlê, wat altyd langs die tanzaniet draende horisonne voorkom, is op grond van anomale konsentrasies van V geïdentifiseer. ‘n Eksplorasie konsessie is op die basis van die teenwoordigheid van groot strome, ‘n paar tsavoriet myne wat aanduidend is van hoë prospektiwiteit vir tanzaniet is en as gevolg van ‘n variasie in geologie in die area vir stroom sediment monstering gekies. Tanzaniet en tsavoriet is kogeneties in bekende tanzaniet afsettings. In hierdie geval was die doel om te ondersoek of tanzanietagtige anomalieë (nl. die anomale konsentrasies van V wat in die ondersoek van die grond chemie opgemerk is) in die omgewing van die tsavoriet myne geïdentifiseer kan word. Tsavoriet, die edelsteen variëteit van grossulaar granaat, bevat hoë konsentrasies V. Die monsters is deur middel van die XRF heel-rots metode vir spoor elemente geanaliseer. Die data dui op ‘n paar monsters met hoë V konsentrasies in die ondersoek area. Hierdie studie het ook gedui op ‘n lae stroom sediment verspreiding van die spoor elemente van belang, heel waarskynlik is dit ‘n funksie van die semi-ariede klimaat. Die fyn fraksie (< 90μm) blyk tot ‘n groter mate as die growwer (90μm tot 180μm en 180μm - 300μm) fraksies gemobiliseer te word. Soos voorspel kan word deur die loogings analise het faktor analise gewys dat die spoor elemente deur swaar mineraal geochemie gedomineer word en dat ‘n studie op swaar minerale moontlik ‘n goedkoper en meer toepaslike eksploraise metode is as die wat in hierdie studie ondersoek is. Kalkreet monsters is van ‘n ongebruikte, 10m diep myn skag wat deur die kalkreet gesink is om by die tanzaniet gemineraliseerde horison uit te kom geneem. Monsters is van die bodem van die skag, naaste aan die tanzaniet mineralisasie, tot die oppervlak geneem om die assosiasie tussen die spoor element geochemie en afstand van die tanzaniet mineralisasie te ondersoek. Geen vertikale assosiasie tussen spoor element geochemie en die nabyheid tot die tanzaniet afsetting kon vasgestel word nie. Daar was geen duidelike aanduiding in die geochemie van die kalkreet op die onderliggende tanzanite afsetting nie. Hierdie is ‘n verdere annduiding op die nie-mobiele toestand van spoor elemente in hierdie omgewing. Hierdie studie het suksesvol gedemonstreer dat goed gedefinieerde grond en stroom sediment geochemiese studies moontlik in geochemiese eksplorasie vir tanzaniet bruikbaar kan wees. Dit is belangrik om in gedagte te hou dat dit slegs die geval is as die geochemie van die litologiese paket wat met die mineralisasie geassosieer is uniek en goed bekend is.

Thesis (MSc)--Stellenbosch University, 2001. / ENGLISH ABSTRACT: This study was conducted to assess groundwater characteristics of geologically different fracture rock aquifers, at different depths, by means of chemical, isotope and 14C-dating results and to test for a "deeper seated aquifer", with different characteristics. Jurassic dolerite dykes and sills, Cretaceous kimberlite fissures and pipes, as well as EW trending sinusoidal megafolds, comprise the structural domains of the study area. Fluvial sandstone and mudstone of the Beaufort Group are the dominant lithology of the study area. The main water type found in the area is a water type not dominated by any anions or cations in particular. The second is a water type in which Na-S04 is dominant, followed by a Na-HC03 dominated water and to a lesser extend a Ca-S04 type water. The main cause of groundwater salinity is the infiltration of evaporated water to the subsurface, suggested by the isotopic enrichment of 0180 and 02H, indicating very slow recharge from ponded water during excessive rainfall events. There is a fair difference in isotopic values between surface measurements and measurements taken at depth, enforcing the possibility of a "second deeper seated aquifer". The water with the lower 180 values, for samples at depth suggest that this water has a source further inland, from rainfall on the range to the NE, the Hex River Mountain or Pramberge, which has greatly depleted 180 values relative to SMOW. Most of the groundwater samples taken at depth indicated a 14C~dating of century age (±200 years), although in an evolutionary sequence the water is not such an old (evolved) water type, lending support to the theory about the migration of deeper seated water and thus a "second deeper seated aquifer system". The chemical character of the groundwater is predominantly controlled by the infiltration of evaporated surface and subsurface water, the topographical nature of the catchments, geological influences (i.e. the process of dissolution, precipitation and ion exchange) and the influence of man. Variability in water quality is caused by differences in rainfall, recharge, evaporation, topography, soil type and thickness, vegetation cover and antropogenic activities. Micro-scale differences occur due to the nature of groundwater flow in Karoo rocks, namely the resulting variations within matrix and fracture components of the groundwater flux. The residence times are often different for these two main components and give rise to the differences in mineralization and solute proportion in passing groundwater. This project should be seen as a basis of continuing study to provide the concrete answers needed to manage groundwater projects in the fractured rock aquifers of the Karoo. Enslin (1950) expresses the classical hydrological conceptualisation of Karoo dolerite dykes - lithe effect of induration and crushing of the sedimentary rock is that the permeability has been increased and the contact zone has been changed into an aquifer lying between the solid dyke and the saturated, low permeability country rock". / AFRIKAANSE OPSOMMING: Hierdie studie was onderneem met die doel. om grondwater eienskappe te ondersoek in geologies verskillende gekraakte / genate aquifere en by verskillende dieptes met die hulp van chemiese, isotopiese en 14C-datering resultate, om sodoende te toets vir 'n "tweede dieper liggende aqulfeer", met verskillende eienskappe. Doleriet gange en plate (Jura), kimberliet gange en pype (Kryt), sowel as OW lopende sinusvormige mega-verskuiwings en monoklienes van die Kaapse Plooi Gordel, Vorm die strukturele omgewings in die studie gebied. Die dominante litologie in die studie gebied is fluviaal gedeponeerde sandsteen en moddersteen van die Beaufort Groep. Die opvallendste water-tipe wat in die studie gebied waargeneem word is 'n grondwater wat geen dominante katione of anione toon nie, tweedens is daar 'n Na-S04 tipe grondwater wat gevolg word deur 'n Na-HC03 tipe water en daarna 'n Ca-S04 grondwater tipe. Die hoof oorsaak van saliniteit in the grondwater is die infiltrering van verdampte water na die grondwater-tafel, deur die verryking in 01BOen 02H, wat stadige infiltrasie van water na hewige reënval episodes voorstel. Die verskil van isotoop waardes by vlak en diepper watervlakke, steun die moontlikheid van die aanwesigheid van 'n "tweede dieper liggende aquifeer". Water met die lae 1BO-waardes (met diepte) dui op 'n opvangsgebied meer na die noordoostelike binneland, soos byvoorbeeld die Hex Rivier Berge en die Pramberge. Meeste van die grondwater monsters wat geneem is by 'n redelike diepte toon 'n 14C-datering waarde van ongeveer 200 jaar, alhoewel die water uit 'n evolutionere oogpunt nie so oud is nie en sodoende ondersteuning bied aan die teorie van die beweging van dieper liggende water en die bestaan van 'n "tweede dieper liggende aquifeer". Die chemiese karakter van grondwater word hoofsaaklik beheer deur die infiltrering van verdampte oppervlak water na die grondwater-tafel, die topografiese geaardheid van die opvangsgebied, geologiese invloede (soos die prosesse van presipitering, oplossing en ioon uitruiling), sowel as die infloed van die mens. Wisselvalligheid in die kwaliteit van grondwater word veroorsaak deur verskille in reënval, infiltrasie, evaporasie, topografie, grond tipe en diepte, plantegroei en die aktiwiteite van die mens. Verskille op mikro-vlak word veroorsaak deur die aard van die grondwater vloei deur die Karoo gesteentes, volgens die verskil in hidroliese geleiding tussen vloei in die matriks en vloei in die krake / nate. Daar is ook 'n verskil in die tydsbestek wat grondwater in die twee hoofstrukturele komponente deurbring en so die verskil in mineralisasie en saliniteit in die dinamiese grondwater veroorsaak. Die projek moet gesien word as die basis vir voortdurende studie om konkrete antwoorde te verseker vir die gebruik in grondwater bestuur projekte van die gekraakte / genate rots aquifere in die Karoo. Enslin (1950) konseptualiseer Karoo doleriet gange as volg: "die effek van indringing en verbrokkeling van sedimentêre gesteentes is dat die deurlaatbaarheid verhoog word en dat die kontak sone verander is na 'n aquifeer wat lê tussen die soliede gang en die versadigde, lae deurlaatbare wand-gesteentes".

Thesis (PhD)--Stellenbosch University, 2003. / ENGLISH ABSTRACT: The Swartland region in the western Cape, South Africa, covers approximately 5000 km2 and forms part of the Pan-African Saldania Belt that represents the southernmost extremity of the Pan-African orogenic belts in southern Africa. Regional mapping of the Swartland area shows that lithologies can be classified using predominantly structural and to a lesser extent lithological criteria. This led to the proposal of a new classification, were rocks of the previous classification of the Malmesbury Group are divided into two new groups, namely the Swartland and Malmesbury groups. The Swartland group can be divided into the Berg River and Moorreesburg formations, a series of quartz-chlorite-muscovite-feldspar schists, quartz schists, graphitic schists and limestones; and the Bridgetown formation, a series of metavolcanic rocks with WPB-MORB affinities that possibly represent seafloor. Deposition of the sediments is suggested to have occurred concurrently with deformation in an accretionary prism/fore-arc and was initiated with the opening of the lapetus Ocean at ca. 600 Ma. This early deformation event, Dt (ca. 575 Ma), only affected the Swartland group and exhibits pervasive bedding transposition, thrusting and imbrication of units creating a tectonostratigraphic sequence. Where identified, kinematic indicators and fold vergence indicate a top-to-the-west transport direction during the early, low-angle Di deformation. The Malmesbury group overlies the Swartland group, being locally separated by an unconformity. The Malmesbury group is a succession of conglomerates, grits and shales (Piketberg Formation), grading into greywackes, shales, siltstones, sandstones and minor limestones of the Tygerberg and Porterville formations. Sedimentation probably commenced after ca. 575 Ma and lasted until shortly after 560 Ma. Both the Swartland and Malmesbury groups were then deformed by the deformation event, D2 (ca. 552-545 Ma), and were intruded by the 552 to 510 Ma Cape Granite Suite. The Franschhoek Formation, formally part of the Malmesbury Group is now classified, along with the inferred ca. 535-510 Ma Magrug and Populierbos Formations of the previous Klipheuwel Group. The redefined Klipheuwel group documents a change in depositional environment from the continental slope/ocean trench, marine and flyschoid deposits of the Malmesbury group to continental, fluvial half-graben and graben deposits. Exhumation, extensive erosion and the formation of a peneplain, was followed by the deposition of the Table Mountain Sandstone Group around 550-510 Ma. The Spitskop gold prospect, located 10 km south of Piketberg, represents the first identified occurrence of mesothermal gold mineralisation in the Saldania Belt. Metamorphic devolatilisation of the Swartland group during Di led to the scavenging and transportation of gold along shallow-dipping shear zones that are contained within the early, sub-horizontal So/Si tectonic fabric. Pervasive fluid movement in the Spitskop area led to elevated gold values compared to background values throughout the lithologies at Spitskop. The lack of any economic-grade gold mineralisation is probably related to the absence of suitably orientated structures, such as high-angle faults, that are commonly believed to represent the prerequisite for large fluid throughputs that could result in economic-grade gold deposits. The mineralisation at Spitskop, however, provides a genetic model for further exploration of gold in the Swartland group. / AFRIKAANSE OPSOMMING: Die Swartland streek in die Wes-Kaap, Suid-Afrika, beslaan ongeveer 5000 km2 en vorm deel van die Pan-Afrikaanse Saldania-gordel wat die mees suidelike deel van die Pan-Afrikaanse orogene gordels in suidelike Afrika verteenwoordig. Regionale kartering van die Swartland streek dui aan dat die gesteentes geklassifiseer kan word deur oorwegend strukturele, en tot 'n mindere mate litologiese kriteria te gebruik. Gevolglik word ‘n nuwe klassifikasie voorgestel, waar gesteentes volgens die vorige klassifikasie van die Malmesbury groep verdeel word in twee groepe, naamlik die Swartland en Malmesbury groepe. Die Swartland groep kan verdeel word in die Bergrivier en Moorreesburg formasies, ‘n reeks kwarts-chloriet-muskoviet-veldspaat skis, kwarts skis, grafitiese skis en kalksteen; en die Bridgetown formasie, ‘n reeks metavulkaniese gesteentes met WPB-MORB affiniteite wat moontlik oseaanvloer verteenwoordig. Daar word voorgestel dat afsetting van die sedimente gelyktydig plaasgevind het saam met vervorming in ‘n akkresionere prisma/voorboog, geinisieer deur die opening van die lapetus Oseaan (ca. 600 Ma). Hierdie vroee vervorming, Di (ca. 575 Ma), het slegs die Swartland groep geaffekteer en vertoon deurdringende verplasing van gelaagdheid, oorskuiwing en imbrikasie van eenhede en het ‘n tektonostratigrafiese opeenvolging gevorm. Waar identifiseer, dui kinematiese aanwysers en plooi kanteling op ‘n bokant-na-wes beweging gedurende die vroee, lae hoek Di vervorming. Die Malmesbury groep oordek die Swartland groep, plaaslik geskei deur ‘n diskordansie. The Malmesbury groep bestaan uit ‘n opeenvolging konglomeraat, grintsteen en skalie (Piketberg formasie), wat gradeer in grouwak, skalie, sliksteen, sandsteen en ondergeskikte kalksteen van die Tygerberg en Porterville formasies. Sedimentasie het waarskynlik begin na ca. 575 Ma en het voortgeduur tot kort na 560 Ma. Beide die Swartland en Malmesbury groepe is hierna vervorm deur D2, (ca. 552-545 Ma) en daaropvolgend ingedring deur die 552 tot 510 Ma Kaap Graniet Suite. Die Franschhoek Formasie, voorheen deel van die Malmesbury Groep, word nou geklassifiseer tesame met die afgeleide ca. 535-510 Ma Magrug en Populierbos formasies as deel van die voorheen geklassifiseerde Klipheuwel groep. Die hergedefinieerde Klipheuwel groep dui op 'n verandering in afsettingsomgewing vanaf die kontinentale glooiing/oseaantrog, mariene en flyschoiede afsettings van die Malmesbury groep na kontinentale, fluviale half-graben en graben afsettings. Herblootstelling, omvattende erosie en die vorming van ‘n skiervlakte is gevolg deur die afsetting van die Tafelberg Sandsteen Groep random 520-510 Ma. Die Spitskop goudvoorkoms, 10 km suid van Piketberg, verteenwoordig die eerste identifiseerde voorkoms van mesotermale goudmineralisasie in die Saldania Gordel. Metamorfe ontvlugtiging van die Swartland groep gedurende Dt het aanleiding gegee tot die roofuitruiling en vervoer van goud langs laaghellende skuifskeursones in die vroee, subhorisontale S0/Si tektoniese maaksel. Deurdringende vloeistofbeweging in die Spitskop omgewing het aanleiding gegee tot verhoogde goudwaardes in vergelyking met agtergrond waardes dwarsdeur die litologiee by Spitskop. Die gebrek aan ekonomiese graad goud mineralisasie is waarskynlik verwant aan die afwesigheid van geskikte georienteerde strukture, soos hoe hoek verskuiwings, wat oor die algemeen beskou word as ‘n voorvereiste vir die toevoer van groot hoeveelhede vloeistof wat kon aanleiding gegee het tot ekonomiese graad goudafsettings. Die mineralisasie by Spitskop verskaf egter 'n model vir verdere goud eksplorasie in die Swartland groep.

Thesis (DSc) -- Stellenbosch University, 1967. / INTRODUCTION: This dissertation aims to illuminate some surprises which the deceptively uncomplicated Table Mountain sandstone had long been harbouring in its kloofs and cliffs . The major contributions of this first systematic investigation of an extensive portion of the Table Mountain sandstone are the discovery of diagnostic marine fossils by means of which the first direct dating of the deposit is effected and important sedimentological conclusions drawn...

Thesis (MSc)--University of Stellenbosch, 2004. / ENGLISH ABSTRACT: The southern portions of the Early- to Mid-Archaean Barberton granitoid-greenstone terrain of South Africa consists of a high-grade metamorphic granitoid-gneiss terrain that is juxtaposed against the low-grade metamorphic supracrustal sequence of the Barberton Greenstone Belt. The boundary of the two different crustal domains corresponds to the Theespruit Formation, an amphibolite-facies, highly tectonized mélange of metabasites, felsic volcanics and rare, aluminous clastic sediments that occurs along the granitoidgreenstone margins. Amphibolite-facies lithologies in the Theespruit Formation are characterized by strongly prolate mylonitic fabrics that formed in a constrictional tectonic regime. Away from the granitoid-greenstone margin and towards the central parts of the greenstone belt, these rocks grade to, and are overprinted by, greenschist-facies S-L mylonites that formed during non-coaxial deformation. Both peak and retrograde minerals define, and are aligned parallel to, the fabrics in these rocks, indicating that shearing was initiated under peak metamorphic conditions and continued during retrogression. S-C’ fabric relationships indicate that shearing occurred in an extensional tectonic regime and that, during deformation, the gneiss terrain was uplifted relative to the greenstone belt. Peak metamorphic assemblages of grt-st-bt-chl-pl-qtz and ky-st-btms- pl-qtz in metasediments and grt-ep-hbl-pl-qtz in amphibolite constrain peak metamorphic conditions of 7.4 ± 1.0 kbar and 560 ± 20 ºC that were attained during the main accretionary episode in the Barberton terrain at 3229 ± 25 Ma. Peak assemblages in all rocks are pre-tectonic and were deformed and re-equilibrated during retrogression, resulting in these being minimum estimates of peak metamorphic conditions. Petrographic evidence and retrograde pressure-temperature estimates indicate that retrogression involved near-isothermal decompression of ca. 4 kbar prior to cooling into the greenschist-facies. The style and timing of metamorphism in the Theespruit Formation is similar to that of the granitoid-gneiss terrain, suggesting that the Theespruit Formation shares a geological history with the gneiss terrain and that it is allochtonous to the greenstone belt. The main deformational and fabric-forming event exhibited in the Theespruit Formation occurred during the exhumation of the granitoid-gneiss terrain subsequent to peak metamorphism. Consequently, the juxtaposition of this terrain againstthe greenstone belt was achieved by tectonic underplating and core complex formation at ca. 3.23 Ga. The occurrence of high-grade constrictional mylonites that are overprinted by low-grade non-coaxial mylonites as well as extension in an overall compressional tectonic regime is consistent with exhumation by extensional orogenic collapse. Burial of the high-grade terrain to depths of 25 – 30 km is only possible in a relatively cold and rigid crustal environment, while the extremely low apparent geothermal gradients of ca. 20 ºC/km preserved in this terrain suggest that burial and exhumation occurred rapidly, within a time-span of ca. 15 – 20 Ma. These parameters strongly suggest that metamorphism occurred in response to a lateral plate tectonic process that was operational in the Barberton terrain at 3230 Ma. / AFRIKAANSE OPSOMMING: Die suidelike dele van die Vroeg- tot Middel-Argaïese Barberton graniet-groensteen terrein van Suid-Afrika bestaan uit ‘n hoë-graad metamorfe graniet-gneiss terrein wat die lae-graad metamorfe groenstene van die Barberton Groensteen Gordel begrens. Die grens tussen die twee verskillende kors-domeine hang saam met die Theespruit Formasie, ‘n amfiboliet-fasies, getektoniseerde melange van metabasiete, felsiese vulkaniese gesteentes en skaars, alumineuse klastiese sedimente wat langs die graniet-groensteen kontakte voorkom. Amfiboliet-fasies gesteentes in die Theespruit Formasie word gekenmerk deur sterk prolaat milonitiese maaksels wat in ‘n vernouende tektoniese omgewing gevorm het. Hierdie rotse word weg van die graniet-groensteen kontak en na die sentrale dele van die groensteen gordel oordruk en vervang deur groenskis-fasies S-L miloniete wat tydens nie-koaksiale vervorming gevorm het. Beide piek en retrograad minerale definieer, en is georienteer parallel aan, die maaksel in die rotse, wat daarop dui dat skuifskeur onder piek metamorfe toestande begin het en volgehou het tydens retrogressie. S-C’ maaksels dui daarop dat skuifskeur in ‘n verlengende tektoniese omgewing plaasgevind het en dat die gneiss terrein opgehef is relatief tot die groensteengordel tydens vervorming. Piek metamorfe versamelings van grt-st-bt-chl-plqtz en ky-st-bt-ms-pl-qtz in metasedimente en grt-ep-hbl-pl-qtz in amfiboliet bepaal piek metamorfe toestande van 7.4 ± 1.0 kbar en 560 ± 20 ºC wat bereik is gedurende die hooffase van akkresie in die Barberton terrein teen 3229 ± 25 Ma. Die piek metamorfe versamelings in alle rotse is pre-tektonies en is vervorm en geherekwilibreer tydens retrogressie, wat maak dat die beramings minimum skattings van piek metamorfe toestande is. Petrografiese getuienis asook druk-temperatuur beramings dui daarop dat retrogressie gepaard gegaan het met byna-isotermiese drukverligting van naastenby 4 kbar voor afkoeling tot in die groenskis-fasies. Die styl en tydsberekening van metamorfose in die Theespruit Formasie is vergelykbaar met metamorfose in die granietgneiss terrein, wat daarop dui dat die Theespruit Formasie ‘n geologiese geskiedenis met die gneiss terrein deel en allochtoon is tot die groensteen gordel. Die hooffase van vervorming en maakselvorming in die Theespruit Formasie het plaasgevind gedurende die herontbloting van die graniet-gneiss terrein na piek metamorfose. Gevolglik is dieteenplasing van dié terrein teen die groensteen gordel vermag deur tektoniese onderplasing en kernkompleksvorming teen ongeveer 3.23 Ga. Die verskynsel van hoëgraadse vernoude miloniete wat oordruk word deur lae-graadse nie-koaksiale miloniete asook verlenging in ‘n algeheel saamdrukkende tektoniese omgewing dui daarop dat herontbloting plaasgevind het deur middel van verlengende orogenetiese ineenstorting. Die begrawing van die hoë-graadse terrein tot dieptes van 25 – 30 km is net moontlik in ‘n relatief koel en star kors-omgewing, terwyl die uitermate lae geotermiese gradiente van ongeveer 20 ºC/km wat in die terrein behoue gebly het daarop dui dat begrawing en herontbloting vinnig geskeid het, binne ‘n tydsverloop van ongeveer 15 – 20 Ma. Hierdie beperkings is ‘n sterk aanduiding dat metamorfose plaasgevind het as gevolg van ‘n laterale plaattektoniese proses wat werksaam was in die Barberton terrein teen 3230 Ma.

Thesis (MSc (Earth Sciences))—University of Stellenbosch, 2005. / The integration of whole-rock chemistry, heavy mineral chemistry, detrital zircon morphology and age dating has enabled high-resolution characterization of the Permian Laingsburg and Tanqua submarine fan provenance in the Karoo Basin, upper Ecca Group, South Africa. Geochemically, the Laingsburg and Tanqua sandstones are classified as greywacke and litharenite. The chemical index of alteration values for these sandstones suggest low to moderately weathered sources and a relatively cold climate. Abundant angular clastic grains and lithic fragments as well as the predominance of pristine zircons indicate a near provenance and a first cycle derivation. The investigated sandstones originated from a continental island arc and an active continental margin. The source is dominantly intermediate to felsic and includes tonalites, granodiorites, and adamellites or their volcanic equivalents.

ENGLISH ABSTRACT: The farm Geelwal Karoo is situated some 16km north of the Olifants River mouth on the West Coast of South Africa and hosts fluvial, marine and aeolian deposits of post-Gondwana age. The oldest basal fluvial succession, unconformably overlies Proterozoic and Palaeozoic basement rocks and is in turn capped by aeolianite and littoral packages representing two transgressive cycles. The fluvial channel clay succession is deposited in shallow bedrock-incised channels, has a wedge-shape and is deposited parallel to the present coastline. The flow direction is along the coast and the northwardtapering, angular, poorly sorted basal vein-quartz lag indicates a northward palaeo-flow direction. Less than 1% total heavy minerals (THM) is found in the matrix of these gravel units and the heavy mineral suite is distinguished by zircon, pseudorutile and kyanite. The channel clay unit is dominated by an upper, mediumgrained quartzose sand and kaolin clay facies, which shows advanced post-depositional weathering. The fluvial unit is correlated with the channel clay unit of Hondeklip Bay and a Cretaceous age is proposed for the initial channel incision. The two shallow marine successions have been correlated with the Late Miocene, Early Pleistocene, +30m and +50m packages respectively. These marine sediments were first described by John Pether (1994) in the Hondeklip Bay area and were named according to their transgressive maxima. They are transgressive successions arranged en echelon down the coastal bedrock gradient, from oldest and highest to youngest. The offshore environment of the +50m package consists of fine silty sand, which is moderately sorted. The mineral assemblage is dominated by quartz and the average THM is 18%. The inshore environment is distinguished by a single poorly sorted basal cobble lag which shows an overall fining upward succession. The beachface environment is composed of medium to fine-grained sand, which is moderate to well-sorted. Mineral diversity is greatest in the inshore and beachface environments and the average THM for these two units is greater than 35%. The +30m package has been extensively eroded due to its lower erosion and outcrops were sporadic along the coast. The +30m offshore sediments are recognised by fine sediments with high concentrations of glauconite and organic matter. The inshore environment is distinguished by numerous poorly sorted pebble lags with fining upward successions. Both the inshore and beachface units have higher feldspar concentrations than the corresponding +50m units. The average THM for these two units is less than 3%. The aeolianite unit, which comprises several distinct units, extends over the entire length of the study area and is characterized by calcrete and red bed horizons. Colour variations in the otherwise homogeneous unit are due to heavy mineral enrichment and/or different degrees of in situ weathering and cementation. The unit is composed exclusively of fine- to medium-grained sand and the THM concentration averages 9%. This unit is composed of more than one generation of aeolian sand and forms part of an aeolian transport corridor which transported sand from the beach to the interior. The oldest unit has been equated with the Upper Miocene Prospect Hill Formation, whereas the more recent yellow dune sand is equated with the Pleistocene Springfontyn Formation. At Geelwal Karoo, only the heavy sand placer in the +50m package was deemed to be of any economic significance. The average THM of this placer was calculated to be 40% and some 150 thousand tons of Tibearing material can be expected from this succession. This relatively small volume of heavy minerals and extensive cementation however, make this placer a less attractive prospect than the neighbouring Namakwa Sands operation. / AFRIKAANSE OPSOMMING: Die plaas Geelwal Karoo is ongeveer 16km noord van die Olifantsriviermond aan die Weskus van Suid- Afrika geleë en het voorkomste van fluviale, marine en eoliese afsettings van post-Gondwana ouderdom. Die oudste eenheid, ‘n basale fluviale eenheid, oorlê Proterosoiëse en Paleosoiëse plaaslike vloer gesteentes wat op hulle beurt weer bedek word deur eoliese en littorale eenhede verteenwoordigene ven twee transgressiewe siklusse. Die fluviale kanaalklei-opeenvolging, afgeset in vlak ingesnyde rotsbedding-kanale, is wigvormig en is afgeset parallel aan die huidige kuslyn in ‘n alluviale waaier-afsetting. Die vloeirigting was langs die kus en die noorwaards toespitsende, hoekige, swak gesorteerde basale aar-kwarts bodemgruis dui op ‘n noordwaards palaeo-vloeirigting. Minder as 1% totale swaarminerale (TSM) is gevind in die tussenmassa van hierdie gruis-eenhede en die swaarmineraal reeks word onderskei deur sirkoon, pseudo-rutiel en kianiet. Die kanaalklei eenheid word oorheers deur ‘n boonste, medium-korrelrige kwarts-bevattende sand en kaolien kleifasies was dui op gevorderde verwering na afsetting. Die fluviale eenheid word gekorreleer met die kleikanaal en ‘n Kryt-ouderdom word voorgestel vir die aanvanklike insnyding van die kanaal. Die twee vlak marine opeenvolgings word gekorreleer met die Laat Mioseen, vroeg Pleistoseen, naamlik die +30m en +50m eenhede onderskeidelik. Die aflandige omgewing van die +50m eenhied bestaan uit matiggesorteerde, fyn slikkerige sand. Die mineraalversameling word oorheers deur kwarts en die gemiddelde TSM is 18%. Die subgetysone word onderskei deur ‘n enkele swak-gesorteerde gruislaag en is oorwegende opwaarts fynerwordend. Die strandomgewing is goed verteenwordige en bestaan uit matig tot goedgesorteerde medium- tot fynkorrelrige sand. Die grootste mineraal-diversiteit kom voor in die subgety- en strandomgewings en die gemiddelde TSM vir hierdie eenhede is hoër as 35%. As gevolg van algemene erosie kom die +30m eenheid sporadies voor. Die aflandige omgeving is herken deur fyn kleierige of slikkerige sedimente met hoe konsentrasies gloukoniet en organiese materiaal. Die subgetysone omgewing is gekenmerk deur verskeie gruislae wat almal opwaarts fynwordend is. Altwee die subgety- en strandomgewings het hoer feldspar konsentrasies as die +50m eenhede. Die gemiddelde THM vir hierdie enhede is minder as 3%. Die eolitiese eenheid, bestaan uit verskeie duidelik-onderskeibare eenhede, beslaan die totale lengte van die studiegebied en word kenmerk deur uitgebreide kalkreet en rooi-laag horisonne. Kleurverskille in die andersins homogene eenheid kan verklaar word in terme van lae swaarmineraal konsentrasies en/of as gevolg wan verskillende grade van in situ verwering en sementering. Die eenheid bestaan uitsluitlik uit fyntot medium-korrelrige sand en het ‘n gemiddelde TSM konsentrasie van 9%. Die eenheid bestaan uit meer as een generasie eoliese sand en maak deel uit van ‘n eoliese vervoersisteem wat sand vanaf die strand na die binneland vervoer het. Die oudste sande in hierdie eenheid is gekorreleer met die Laat Mioseen Prospect Hill Formasie terwyl die meer onlangse geelduin sand vergelyk word met die Pleistoseen Springbokfontein Formasie. By Geelwal Karoo is slegs die +50m eenhede beskou as economies van belang. Die gemiddelde TSM van hierdie swaarmineraal-ertsligaam is bereken op 40% met ‘n verwagte 150 duisend ton Ti-draende material van die opeenvolging. Die relatiewe klein volume swaarminerale en uitgebreide sementering het tot gevolg dat dit ‘n minder aanloklike proposisie is as die aanliggende Namakwa Sands aanleg.