[Truncated abstract] During the last fifty years mathematical models of catchment hydrology have been widely developed and used for hydrologic forecasting, design and water resources management. Most of these models need large numbers of parameters to represent the flow generation process. The model parameters are estimated through calibration techniques and often lead to ‘unrealistic’ values due to structural error in the model formulations. This thesis presents a new strategy for developing catchment hydrology models for representing streamflow and salinity generation processes. The strategy seeks to ‘learn from data’ in order to specify a conceptual framework that is appropriate for the particular space and time scale under consideration. Initially, the conceptual framework is developed by considering large space and time scales. The space and time scales are then progressively reduced and conceptual model complexity systematically increased until ultimately, an adequate simulation of daily streamflow and salinity is achieved. This strategy leads to identification of a few key physically meaningful parameters, most of which can be estimated a priori and with minimal or no calibration. Initially, the annual streamflow data from ten experimental catchments (control and cleared for agriculture) were analysed. The streamflow increased in two phases: (i) immediately after clearing due to reduced evapotranspiration, and (ii) through an increase in stream zone saturated area. The annual evapotranspiration losses from native vegetation and pasture, the ‘excess’ water (resulting from reduced transpiration after land use change), runoff and deep storage were estimated by a simple water balance model. The model parameters are obtained a priori without calibration. The annual model was then elaborated by analysing the monthly rainfall-runoff, groundwater and soil moisture data from four experimental catchments. Ernies (control, fully forested) and Lemon (53% cleared) catchments are located in zone with a mean annual rainfall of 725 mm. Salmon (control, fully forested) and Wights (100% cleared) are located in zone with mean annual rainfall of 1125 mm. Groundwater levels rose and the stream zone saturated area increased significantly after clearing. From analysis of this data it was evident that at a monthly time step the conceptual model framework needed to include a systematic gain/loss to storage component in order to adequately describe the observed lags between peak monthly rainfall and runoff.

[Truncated abstract] The use of uncertainty analysis is gaining considerable attention in catchment hydrological modeling. In particular, the choice of an appropriate model structure, the identifiability of parameter values, and the reduction of model predictive uncertainty are deemed as essential elements of hydrological modelling. The chosen model structure must be parsimonious, and the parameters used must either be derivable from field measured data or inferred unambiguously from analysis of catchment response data. In this thesis, a long-term water balance model for the Susannah Brook catchment in Western Australia has been pursued using the ?downward approach?, which is a systematic approach to determine the model with the minimum level of complexity, with parameter values that in theory are derivable from existing physiographic data relating to the catchment. Through the analysis of the rainfall-runoff response at different timescales, and the exploration of the climate, soil and vegetation controls on the water balance response, an initial model structure was formulated, and a priori model parameter values estimated. Further investigation with the use of auxiliary data such as deuterium concentration in the stream and groundwater level data exposed inadequacies in the model structure. Two more model structures were then proposed and investigated through formulating alternative hypotheses regarding the underlying causes of observed variability, including those associated with the absence of a contribution of deep groundwater flow to the streamflow, which was indicated by deuterium concentration and internal dynamics characterized by the observed groundwater levels. ... These differences are due to differences in the time delay between rainfall and recharge between upland and riparian regions. The ages of water recharging the groundwater and discharging from the catchment were estimated by assuming a piston flow mechanism. In the deeper, upland soils, the age of recharging water was considerably larger than the unsaturated zone delay would suggest; a recharge response 16 days after an infiltration event may involve water as much as 160 days old. On the other hand, the delay and the age of recharging water were much lower in the shallow riparian zone. Where the upland zone contributes significantly to discharge, the predicted difference between the rainfall-discharge response time and the average age of discharging water can be significant.

Issues arising from climate change and long-term natural climate variability have become the focus of much recent research. In this study, we specifically explore the impacts of long-term climate variability and climate changes upon flood frequencies. The analyses of the flood frequencies are carried out in a comparative manner in catchments located in semiarid-temperate and tropical landscapes in Australia, namely Perth, Newcastle and Darwin, using a process-based derived flood frequency approach. The derived flood frequency analyses are carried out using deterministic rainfall-runoff models that capture the intrinsic water balance variability in the study catchments, and driven by temporal rainfall event sequences that are generated by a stochastic rainfall model that incorporates temporal variabilities over a multiplicity of time scales, ranging from within-event, between-event to seasonal, multi-annual and multi-decadal time scales. Six climate scenarios are considered for Newcastle, that combine the ENSO (El Niño Southern Oscillation) and IPO (Inter-decadal Pacific Oscillation) modes of variability, and six different climate scenarios are considered for Perth and Darwin that combine these different ENSO modes and step changes in climate (upwards or downwards) that occurred in 1970 in both regions, which were identified through statistical analysis. The results of the analyses showed that La Niña years cause higher annual maximum floods compared to El Niño and Neutral years in all three catchments. The impact of ENSO on annual maximum floods in the Newcastle catchment is enhanced when the IPO is negative and for Perth, the impact of ENSO weakens in the post-1970 period, while it strengthens in Darwin in the same period. In addition, the results of sensitivity and scenario analyses with the derived flood frequency model explored the change of dominant runoff generation processes contributing to floods in each of the study catchments. These analyses highlighted a switch from subsurface stormflow to saturation excess runoff with a change of return period, which was much more pronounced in Perth and Darwin, and not so in Newcastle. In Perth and Darwin this switch was caused by the interactions between the out-of-phase seasonal variabilities of rainfall and potential evaporation, whereas the seasonality was much weaker in Newcastle. On the other hand, the combination of higher rainfall intensities and shallower soil depths led to saturation excess runoff being the dominant mechanism in Newcastle across the full range of return periods. Consequently, within-storm rainfall intensity patterns were important in Newcastle in all major flood producing events (all return periods), where they were only important in Perth and Darwin for floods of high return periods, which occur during wet months in wet years, when saturation excess runoff was the dominant mechanism. Additionally, due to the possibility of a change of process from subsurface stormflow to saturation excess when conditions suited this switch, the estimates of flood frequency are highly uncertain especially at high return periods (in Darwin and Perth) and much less in Newcastle (when no process change was involved).