Thesis (Sc.D.)--Massachusetts Institute of Technology, Dept. of Nuclear Engineering, 1980. / MICROFICHE COPY AVAILABLE IN ARCHIVES AND SCIENCE. / Bibliography: leaves 289-295. / by Bahman Atefi. / Sc.D.

Thesis (Nucl.E.)--Massachusetts Institute of Technology, Dept. of Nuclear Engineering, 1979. / MICROFICHE COPY AVAILABLE IN ARCHIVES AND SCIENCE. / Includes bibliographical references. / by John A. Bernard, Jr. / Nucl.E.

M. Tech. (Department of Chemistry, Faculty of Applied And Computer Sciences), Vaal University of Technology. / Biodiesel has an ability to solve the problem associated with the use of fossil fuels as a source of energy. The aim of this study was to produce biodiesel from waste cooking oil (WCO) by transesterification, catalysed with potassium hydroxide (KOH) supported on attapulgite (ATP) clay as the heterogeneous catalyst. WCO was used on the basis that it is one of the cheapest feedstocks for biodiesel production, is readily available and can minimise environmental impact. ATP clay was first crushed and sieved to particle sizes of ≤ 90 μm and subsequently treated with hydrochloric acid (HCl) to remove impurities. The KOH supported ATP catalyst was prepared through ion exchange method by soaking ATP into KOH solution, dried in an oven and later calcined at 400 ℃ in a furnace. The prepared catalyst and ATP clay were characterised using Hammett indicator to determine the basic strength of the catalyst. XRF and EDX were used to determine the elemental composition of the catalyst whilst XRD was used to determine the crystallinity of the ATP after modification. The functional groups of ATP were determined by FTIR. BET was utilised to determine the changes on the surface area, pore volume and pore diameter of ATP and on the other hand, SEM was used to determine the morphological changes on the surface of ATP. The XRD, FTIR, BET AND SEM-EDX showed that addition of potassium caused changes on the surface of the ATP. The optimal conditions for the transesterification reaction of waste cooking oil with methanol were found to be oil-to-methanol molar ratio of 1:15, 3wt% catalyst amount, 65 ℃, 3 h of a reaction time, at 200 rpm stirring rate and 94 % biodiesel yield was obtained. After the catalyst was reuse three consecutive times, the decrease in biodiesel yield was observed (Figure 17) after each cycle. However, the 5MKOH/ATP catalyst is heterogeneous and can be used to transesterify WCO with good yield.

Thesis submitted in 50 % completion of the degree of Master of Management in the field of Public and Development Management at the University of the Witwatersrand, Johannesburg. 20 June 2016 / In response to the ever increasing problems associated with climate change, and greenhouse gas emissions, many countries in the world are developing and adopting climate change resilient policies that support green economy. Green economy sector in South Africa has not as yet received much expected attention as a key sector to address economic and environmental problems. The use and the production of renewable fuels, such as biodiesel are known to have significant economic and environmental benefits. However, progress in the production of biodiesel is hampered by limits imposed by government on the use of fresh vegetable extracted oils for production of biodiesel, mainly due to challenges on food security; and the impact this will have on food prices. In recent years recycling has become an important tool to address waste problems; pollution control; and socio-economic problems such as joblessness, poverty and social inequity. Used cooking oil has always been considered waste and an environmental burden. Therefore through technology advancement of recycling, wastes such as used cooking oil have become useful resources for biodiesel production. This research is about the challenges in recycling used cooking oil to produce biodiesel. The study recommended that in order to address challenges facing sustainability of our environment, and high unemployment rate; small recycling industries such as those operating in Polokwane will need government support such as biodiesel sector policies and regulations, to encourage investment in the biodiesel value chains in a way that will lead to the achievement of green economy goals. / MT2016

In the time line of world industrial age, the most important era begins in the late 18th century when the use of fossil fuels was growing intensively. This approach has continued and developed up to the 20th century. Besides, this trend has had side effects like polluting environment. Air pollution is one of the critical issues nowadays that stems from using hydrocarbon fuels. One type of the problematic compounds in polluting air is nitrogen oxides that can be produced in combustion process from engines and industrial plants. Different solutions have been suggested to remove air polluting compounds. One method for removing nitrogen oxides is using the mechanism of Selective Catalytic Reduction in silencer of engines. This method has become practical in trucks’ engines. Therefore, research on SCR chemistry is important for improving the usage of this method in removing nitrogen oxides. SCR has its own problems when used in trucks. One of the problems is formation of white clumps on pipe wall of silencers using SCR which can cause back pressure in the engines and costs a lot to remove them from engines.  This report evaluates the effect of alternative fuels on SCR chemistry .Different parameters affecting deposit formation are studied and evaluated. Ethanol is one of the controversial fuels used in engines and acetic acid is one its byproducts. Also, urea and its by products are important materials in SCR chemistry, too. Consequently, the first part of the report studies the influence of acetic acid and Ferrite steel, one of the usual steels in silencers of engines, on urea, biuret and cyanuric acid decomposition. The instruments used in the first part include TGA-DSC (Thermo Gravimetric Analysis-Differential Scanning Calorimetric) which is connected to FTIR (Fourier Transform Infrared Spectroscopy).In the second part of the report, the effect of diesel exhaust and ethanol exhaust on cyanuric acid evaporation rate is evaluated. Cyanuric acid is the main compound forming deposit in silencers. The instrument used in the second part is TGA. The third part consists surveying effect of Adblue, aqueous solution of urea, and additivised Adblue, surfactant added Adblue to improve its efficiency, in a patented rig that is scaled down of a silencer of truck. The most important result for the first part includes the effect of Ferrite steel treated with acetic acid that accelerated the decomposition of cyanuric acid. This result can be investigated more in order to be used in silencers to accelerate the decomposition rate of clumps formed. In the second part, it is found out that cyanuric acid evaporates faster under ethanol exhaust than diesel exhaust. The third part’s results shows that in the current assembly of pipes in the rig, Additivised Adblue loses its improved efficiency which is an interesting result for engine welding in order to avoid this type of connection in engines.

This project sets out a theory of how performance can contribute to the spread of ecological values as we, as a species, confront the challenges of the Anthropocene. In response to the theory that the roots of the contemporary ecological crisis lie in the agricultural revolution, the project examines an archive of performances that engage questions of agriculture, land use, and anthropogenic climate change. Chapter 1 looks at mainstream, Western dramas that depict ecodystopian futures; chapter 2 looks at teatros in the Chicano movements and their anti-agribusiness actos; chapter 3 looks at rural, community responsive theater on public lands threatened by fossil fuel development; and chapter 4 looks at anti-pipeline ritual performance in the Niobrara River Valley. These objects of analysis are united in their activist drive to dislodge the values that undergird industrial agriculture and replace them with ecological values. The project argues that an understanding of performance as “performance-assemblage” can help to explain its power to bring about this transvaluation by drawing on the posthuman characteristics of assemblages to “deterritorialize” and “reterritorialize”—that is, to shift elements from one assemblage to another, and to alter the meaning of those elements and assemblages in the process.

No description available.

Philosophiae Doctor - PhD / Fossil fuels are part of fuels that are formed from natural processes and they are called non-renewable sources of energy. These include natural gas, coal and oil. They have been used for decades to produce energy globally. However, there are some factors that related with the use of fossil fuels which results in an increase in the requirement of large amounts of energy. In addition, the use of fossil fuels as energy source has a negative impact on the environment and they cannot be reused. It is expected that at some point they will run out. Thus, a need for a renewable, clean and plentiful source of energy is urgent. Solar energy is one of the energy sources that may overcome fossil fuel drawbacks.

No description available.

There is an increasing need for renewable energy sources to replace fossils fuels which accumulate harmful byproducts in the environment. Biodiesel emits less gaseous pollutants than diesel. There are various sources for biodiesel but they are unable to meet the existing demands for fuel. Microalgae are a promising source for biodiesel because of its relatively faster growth rate, availability, and lipid content. Microalgae (JC and BT) growing in local water bodies were collected, selected on section media containing antibiotics, and used for characterizations. Experiments were conducted to study and evaluate the optimum growing conditions. Results show that both JC and BT attain maximum growth with shaking and additional aeration compared to control microalgae Dunaliella salina, Nannochlorposis oculata which do not require additional aeration for optimal growth. Lipid extraction results suggest that JC (9.7%) and BT (4.1%) have slightly higher lipid content compared to control algae e.g. Chlamydomonas reinhardtii (3.1%).