The following thesis titled, Atlanta Automotive Particulate Matter Exposure and Evaluation, presents data obtained as a part of a joint project with Emory University, Rollin's School of Public Health. The Atlanta Commuters Exposure (ACE) Study uses both real-time and time-integrated sampling techniques for ambient aerosol concentrations. The ACE study is unique in that it will correlate the ambient aerosol concentrations with the concurrent health measurements. The primary objective of this thesis is to measure the concentration, size distribution and the chemical composition of PM2.5 inside the vehicle cabin for several commuters. The vehicles followed a scripted route along roadways in the Atlanta metropolitan region during periods of peak traffic volume, while the compact air sampling package of both real-time and time-integrated instruments recorded data. Real-time measurements for Particulate Matter (PM) were made using compact Optical Particle Counters (OPC), a Condensation Particle Counter, and a MicroAethalometer. The time-integrated measurements for Elemental Carbon (EC), Organic Carbon (OC), Water Soluble Organic Carbon (WSOC), particulate elemental concentrations, and speciated organics required filter collection methods. Thus a compact air-sampling package was created to combine both sets of real-time and time-integrated instruments. The following results are presented for the first four commutes. The framework for analyzing and presenting results is developed, and will be used for future commutes.

River inflow is one of the most important factors influencing the density and biomass of estuarine biotic communities. The aim of this study was to obtain an understanding of the ecosystem functioning of selected estuaries on the east coast of South Africa and to represent their dynamics through ecosystem models. The responses of water column nutrients, plankton density and biomass to inlet phase changes for 16 temporarily open/closed estuaries (TOCEs) in South Africa were first determined. This analysis demonstrated that inlet phase and the duration of mouth closure were the most important factors determining plankton density and biomass of the analysed TOCEs. Estimates of planktonic standing stocks for four of these estuaries revealed that stocks can be from 26 to 10 000 times higher during the closed compared to the open phase. Also, slightly higher variability of planktonic density and biomass was recorded during the closed phase of TOCEs. The second major thrust of this study was to analyse the variability and temporal stability of planktonic and macrobenthic invertebrate density and biomass in two KwaZulu-Natal estuaries over a dry/wet cycle. The results suggest that “stable” variability and species synchronization could be the mechanisms whereby the estuarine biota of these systems compensate for environmental changes and attain a degree of environmental homeostasis. The third major thrust involved an assessment of the spatio-temporal variations in the elemental composition and stoichiometry of suspended and sediment detritus, zooplankton and macrobenthic taxa from two estuaries over a dry/wet cycle. Significant seasonal variations in the elemental composition of detritus, zooplankton and macrobenthic species were found, with the variations in the elemental content of sediment and suspended detritus being related to the seasonal changes in river inflow, while the among-taxa variability was mainly explained by feeding mode. Finally, static seasonal carbon and nitrogen ecosystem network models were developed for the East Kleinemonde, Mlalazi and Mpenjati estuaries to investigate their nutrient dynamics and ecosystem functioning. The results indicated that the East Kleinemonde and Mpenjati estuaries were mainly dependent on primary producers during the dry season, especially the high standing stocks of phytoplankton and microphytobenthos. Similarly, the dependency on detritus was higher during the wet season due to the high riverine imports during this season. Consequently, higher detritivory was recorded in all three study systems during the wet season. Cycling of nitrogen was higher than of carbon on a seasonal basis, with higher recycling of nitrogen during the dry season implying a lower availability of this element due to reduced freshwater inflow and nutrient input during the low rainfall period. System indices indicated that the organization of these systems was higher during the dry season, while the overheads on imports and exports peaked during the wet season. The ecosystem models analysed here provide an initial insight into the overall carbon and nitrogen dynamics of estuaries on the east coast of South Africa. / M.Sc. University of KwaZulu-Natal, Durban 2013.

Published as the author's thesis (doctor, Wageningen University, 2009). / Vita. Includes bibliographical references (p. 125-138). Includes list of author's publications (p. 147-149).

Published as the author's thesis (doctor, Wageningen University, 2009). / Includes bibliographical references (p. 125-138). Includes list of author's publications (p. 147-149).

Marine renewable energy developments (MRED) will result in large quantities of infrastructure being deployed in coastal habitats, and the localised exclusion of fishing. The ecological consequences of this scale of deployment are largely unknown, particularly for benthic species. Infrastructure has the capacity to act as artificial reefs (ARs), providing novel habitat, and this may viewed as a benefit of MRED, or a means to mitigate the exclusion of fishing. At present, the functioning of AR ecosystems remains poorly understood. As a measure of ecosystem function, secondary productivity can be used to assess the implications of MRED. The lack of suitable methodology, deployable at relevant scales within time and/or cost constraints, has limited benthic secondary productivity (BSP) quantifications on ARs. Techniques to measure potential BSP and particle flux were developed and applied to the Loch Linnhe Artificial Reef (functionally similar to scour protection material). Variations in BSP and mobile epifaunal densities on, and between, structures in different environments were quantified. Reefs exposed to intermediate current had the highest potential productivity. The BSP on internal areas of structures contributed to the total productive output, but the relative contribution varied according to reef location and design. BSP was primarily determined by particle supply, but the response was not consistent among locations. Mobile epifaunal densities related to reef location, but not reef design, and were highest on reefs in the deepest water and exposed to the fastest currents. The evidence presented in this thesis highlights the need to account for the receiving environment when predicting the ecological consequences of MRED, or when modelling the productive capacity of structures. Such information can be used to suggest modifications to proposed or existing structures in order to maximise their benefit to coastal ecosystems.

Magister Scientiae - MSc (Biodiversity and Conservation Biology) / Arundo donax is an invasive species that mostly impacts on sensitive riparian ecosystems. Arundo is also invasive in South Africa, though less is known about its ecology, biology, and impacts. Since California and the Western Cape of South AFrica have similar Mediterranean-type climates, we could assume that the impacts of Arundo on ecosystems in California are likely to be similar in the Western Cape, and that control methods used could be extrapolated for use in South Africa. This thesis attempted to determine what impact Arundo has on biodiversity at the community-ecosystem level. / South Africa

Thesis (M. Dev.) -- University of Limpopo, 2016 / This mini-dissertation deals with the legal analysis of the prohibition of marine pollution. It is found that the harmful effects of marine pollution on the marine ecosystem, human health and the economy is a problem that needs to be solved immediately. International Conventions and different legislation have been drafted in order to regulate, reduce, mitigate or stop marine pollution. Despite the existence of these conventions and legislation, this problem continues unabated. Large numbers of marine species are known to be harmed and killed as a result of marine pollution. Marine pollution did not receive much attention until many species in the sea and the marine ecosystem faced adverse consequences resulting from marine pollution. Although it has become a global concern, most nations are still producing huge pollution loads. This mini-dissertation analyses the legal framework and the sources of marine pollution, the effects of marine pollution on the marine ecosystem and human health. Furthermore, it makes a comparative analysis between South Africa as developing country and Australia as a developed country in order to determine what South Africa could learn from Australia. The study makes recommendations on how marine pollution can be solved, mitigated or combatted. / National Research Foundation (NRF)

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