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Synthesis and characterization of nanostructure electrodes for lithium ion batteries. / 鋰離子電池納米電極的製備和表徵 / CUHK electronic theses & dissertations collection / Synthesis and characterization of nanostructure electrodes for lithium ion batteries. / Li li zi dian chi na mi dian ji de zhi bei he biao zhengJanuary 2013 (has links)
Liu, Hao = 鋰離子電池納米電極的製備和表徵 / 劉昊. / Thesis (Ph.D.)--Chinese University of Hong Kong, 2013. / Includes bibliographical references (leaves 99-103). / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Abstract also in Chinese. / Liu, Hao = Li li zi dian chi na mi dian ji de zhi bei he biao zheng / Liu Hao.
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Room temperature ionic liquids as electrolytes for use with the lithium metal electrodeHowlett, Patrick C. January 2004 (has links)
Abstract not available
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Synthesis and characterization of nanostructured electrode materials for rechargeable lithium ion batteriesPark, Min Sik. January 2008 (has links)
Thesis (Ph.D.)--University of Wollongong, 2008. / Typescript. Includes bibliographical references: page 205-222.
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Continuum Level Physics-based Model on Understanding and Optimizing the Lithium Transport in High-Energy-Density LIB/LMB ElectrodesHui, Zeyu January 2022 (has links)
As an efficient means of energy storage, rechargeable batteries, especially the lithium-ion batteries (LIBs) have been a vital component in solving the upcoming energy crisis and environmental problems. Recently, the development of electric vehicle market puts new requirement on the next generation LIBs, including superior energy density, safety and cycling stability, etc. Compared with experimental investigation, Physics-based models provide a surrogate method to not only tackle the underlying physics of the complex battery system, but also optimize the design of battery systems. In this thesis, I will show how I use the physics-based continuum model and cooperate with some experimental methods to understand the lithium transport phenomena inside the multiscale battery electrode systems, based on which the models are then applied to guide the experimental optimization of battery electrode design and to quantitively understand the degradation of high-performance electrodes.
The thesis is divided into three parts. First part (Chapter 2) presents a systematical model selection study on the multiscale LiNi₀.₃₃Mn₀.₃₃Co₀.₃₃O₂ (NMC₁₁₁) electrode. Discharge and voltage relaxation curves, interrogated with theory, are used to distinguish between lithium transport impedance that arise on the scale of the active crystal and on the scale of agglomerates (secondary particles) comprised of nanoscale crystals. Model-selection algorithms are applied to determine that the agglomerate scale transport is dominant in the NMC₁₁₁ electrode studied here. This study not only discovers the dominant length scale for lithium transport, but also provide a validated model (the agglomerate model) for later study.
The second part (Chapter 3 & 4) talks about understanding & optimization of ion transport in porous electrodes. In Chapter 3, multi-scale physics-based models for different active material systems, which have been parameterized and validated with discharge experiments, are optimized by varying porosity and mass loading to achieve maximum volumetric energy density. The optimization results show that with a re-scaling of the current rate, the optimal results follow a general design rule that is captured in a convenient correlation. Chapter 4 extends the model to simulate the performance of advanced electrode architectures utilizing aligned channels, by quantifying the impact of aligned channel electrode structures on cell rate capability. Then the optimization algorithm in Chapter 3 is applied to these aligned-channel electrodes.
The final part (Chapter 5) shows how I use the physics-based model to quantitatively analyze the battery degradation. The validated model is applied to cycling data to obtain parameter estimates indicative of degradation modes. It’s found that growth rates of interfacial impedance and active material loss are greater at 4.5 V, as might be expected. However, when charged to 4.5V, degradation rates are lower at a cycling C-rate of 1.0 h⁻¹ than at 0.5 h⁻¹. Once performance changes are quantified, we use further simulation to evaluate the contribution of individual degradation modes to fade of cell performance metric such as capacity, power density, and energy density.
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Density functional tight-binding and cluster expansion studies of lithiated/sodiated silicon anodes for high-energy-density batteriesPhoshoko, Katlego William January 2020 (has links)
Thesis (Ph.D. (Physics)) -- University of Limpopo, 2020 / This work presents a computational modelling workflow that uniquely combines
several techniques, proposed as a means for studying and designing high-energy-density electrodes for the next-generation of rechargeable batteries within the era of
the fourth industrial revolution (4IR).
The Self-Consistent Charge Density Functional-based Tight Binding (SCC-DFTB)
parameterisation scheme for the Li-Si and Na-Si systems is presented. By using the
Li-Si system, a procedure for developing the Slater-Koster based potentials is
shown. Using lessons learned from the Li-Si framework, the parameterisation of the
Na-Si is reported. The Li-Si SCC-DFTB parameter set has been developed to handle
environments that consist of Si-Si, Li-Si and Li-Li interactions; and the Na-Si SCC DFTB parameter set is developed for Na-Na, Na-Si, and Si-Si interactions.
Validations and applications of the developed sets are illustrated and discussed.
By calculating equilibrium lattice constants, the Li-Si set is shown to be compatible
with various phases in the crystalline Li-Si system. The results were generally within
a margin of less than 8% difference, with some values such as that of the cubic
Li22Si5 being in agreement with experiments to within 1%. The volume expansion of
Si as a function of Li insertion was successfully modelled via the Li-Si SCC-DFTB
parameter set. It was shown that Si gradually expands in volume from 53.6% for the
LiSi phase composed of 50 atm % Li, to 261.57% for Li15Si4 with 78.95 atm % Li, and
eventually shoots over 300% for the Li22Si5 phase with the expansion at 316.45%,
which agrees with experiments.
Furthermore, the ability of the Li-Si SCC-DFTB parameter set to model the
mechanical properties of Si is evaluated by calculating the mechanical properties of
pristine cubic Si. The parameter set was able to produce the mechanical properties
of Si, which agree with experiments to within 6%. The SCC-DFTB parameter set was
then used to model the volume expansion of amorphous silicon (a-Si) as a result of
lithiation within concentrations ranging from 33 – 50 atm % Li. Consistent with
experiments, the a-Si was found to marginally expand in a linear form with increase
in Li content. a-Si was observed to exhibit a lower expansion compared to c-Si.
Additionally, the structural stability of the amorphous Li-Si alloys was examined, and
observations agree with experiments.vi
The Na-Si SCC-DFTB parameter set produced equilibrium lattice parameters that
agree with experiments to within 4% for reference structures, and the transferability
was tested on three Na-Si clathrate compounds (i.e. the Pm-3n Na8Si46, the Cmcm
NaSi6 and Fd-3m Na24Si136).
By employing the approach used when lithiating Si, the sodiation of crystalline silicon
(c-Si) was modelled. It was predicted that c-Si expands by over 400% at 77 atm%
Na and shoots above 500% for concentrations exceeding 80 atm% of Na. By
comparing how c-Si expands as a result of lithiation to the expansion consequent to
sodiation for concentrations ranging from 66.6 – 81.4 atm%, c-Si is shown to be
unsuitable for Na-ion batteries. As a test, the ability of the developed Na-Si SCC DFTB parameter set to handle large and complex geometries was shown by
modelling the expansion of a-Si at 33 atm% Na. It was deduced that a-Si would be
more preferable for Na-ion batteries since at 33 atm% Na, a-Si expanded a lot less
than when c-Si was used. Using the Li-Si and the Na-Si SCC-DFTB parameter sets,
it was noted that amorphisation appears to lower the magnitude by which Si
expands, therefore agreeing with experiments in that amorphous structures are
reported to exhibit a buffering effect towards volume expansion.
The material space for the Li-Si alloy system is explored through crystal structure
predictions conducted via a machine learning powered cluster expansion (CE).
Using the FCC and BCC – based parent lattice in the grid search, 12
thermodynamically stable Li-Si alloys were predicted by the genetic algorithm. Viz.
the trigonal Li4Si (R-3m), tetragonal Li4Si (I4/m), tetragonal Li3Si (I4/mmm), cubic
Li3Si (Fm-3m), monoclinic Li2Si3 (C2/m), trigonal Li2Si (P-3m1), tetragonal LiSi
(P4/mmm), trigonal LiSi2 (P-2m1), monoclinic LiSi3 (P2/m), cubic LiSi3 (Pm-3m),
tetragonal LiSi4 (I4/m) and monoclinic LiSi4 (C2/m).
The structural stabilities of the predicted Li-Si alloys are further studied. With focus
on pressure, the thermodynamic conditions under which the Li-rich phase, Li4Si (R 3m), would be stable are tested. Li4Si (R-3m) was subjected to pressures during
geometry optimization and found to globally maintain its structural stability within the
range 0 – 25GPa. Hence, Li4Si was predicted to be a low pressure phase. In
studying the PDOS, the Li4Si (I4/m) was noted to be more stable around 40GPa and vii
45GPa, which is consistent with the prediction made from other works, wherein
intelligence-based techniques were used.
A test for exploring the Na-Si material space was done using insights acquired from
the Li-Si framework. Three thermodynamically stable Na-Si (i.e. the I4/mmm Na3Si,
P4/nmm NaSi and Immm NaSi2) were predicted. Using the Na-Si SCC-DFTB
parameter set, a correlation of the total DOS in the vicinity of the Fermi level (Ef) with
the structural stability of the three Na-Si alloys is done. NaSi (P4/nmm) was shown to
be unstable at 0GPa, NaSi2 (Immm) is found to be stable, and the Na-rich Na3Si
exhibited metastability. The stability of Na3Si was seen to improve when external
pressure ranging from 2.5 – 25GPa was applied; hence, suggesting Na3Si (I4/mmm)
to be a high-pressure phase. Furthermore, expanding on the groundwork laid from
the Li-Si and Na-Si CE, the Mg-Si system was tested to illustrate that the approach
can be used to rapidly screen for new materials. The ground-state crystal structure
search predicted 4 thermodynamically stable Mg-Si alloys. Viz. Mg3Si (Pm-3m),
MgSi (P4/mmm), MgSi2 (Immm) and MgSi3 (Pmmm).
Lastly, to highlight the power of combining various computational techniques to
advance material discovery and design, a framework linking SCC-DFTB and CE is
illustrated. Candidate electrode materials with nano-architectural features were
simulated by designing nanospheres comprised of more than 500 atoms, using the
predicted Li-Si and Na-Si crystal structures. The stability of the nanospheres was
examined using SCC-DFTB parameters developed herein. The workflow presented
in this work paves the way for rapid material discovery, which is sought for in the era
of the fourth industrial revolution. / National Cyber Infrastructure System: Center for High-Performance Computing
(NICIS-CHPC) for computing resources, the National Research Foundation (NRF)
and the University of Limpopo
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Characterization of Positive Electrodes in Sodium-Metal Chloride BatteriesZhu, Ruixing January 2016 (has links)
The high-performance sodium metal chloride battery has garnered significant interest in the past decade due to its multiple advantages such as high energy density, deep discharge cycling ability, high safety level, 100% coulombic efficiency, and a broad ambient-temperature operating range. Current development of the sodium-metal chloride batteries is focused on improving its performance and cycling life.
This work investigates micro-scale mass transfer and kinetic parameters, which is related to cell performance, for building a complete model. In a typical commercial sodium metal chloride cell, there is mass transfer and conduction throughout the thick positive electrode. The electrode materials participate in redox reactions neither homogeneously nor simultaneously. Therefore, a much thinner positive electrode is introduced in this work in order to remove added macro-scale effects in the electrode from the measurement. Therefore, the number of parameters needed to describe the data was reduced because the experimental design minimizes spatial variations within the cell.
Chapter 2 discusses the impact of iron addition to a sodium nickel-chloride cell by investigating ionic transport within the metal chloride phase. The electrochemical performance of a sodium mixed-metal (Ni, Fe) halide cell is characterized for different cathode compositions and at different rates. Charge/discharge data are characterized by a smaller nickel-voltage plateau during discharge than during charge, indicating that some of the NiCl₂ reduces at cell potentials nominally associated with the iron plateau. One means of describing the difference between charge and discharge is to consider transport processes within the mixed NiCl₂/FeCl₂ solid phase. A one-dimensional model has been used to simulate the ionic transport within the (Ni,Fe)Cl₂ phase; the transport model predicts the ratio of discharge to charge iron plateaus reasonably well for most rates and compositions.
In order to further investigate complex dynamic behavior of the open-circuit potential (OCP) and galvanic interactions in an iron-doped sodium nickel-chloride cell, a GITT (Galvanostatic Intermittent Titration Technique) method is used in Chapter 3. The response to open-circuit interrupts of porous mixed iron-nickel cathodes has been characterized as a function of state of charge (SOC) for different iron loadings and different charge and discharge rates. After discharge, OCP can evolve in time from the iron plateau to the nickel plateau, and this behavior can be explained by galvanic interactions between iron metal and Ni²⁺. Characteristic times of the OCP transients depend on SOC and can be large. When the OCP has converged on a steady state during discharge, its value may provide an estimate of the mole fraction of NiCl₂ at the interface of the triclinic (Ni,Fe)Cl₂ film that resulted from metal oxidation.
Sulfur-containing additives were shown to have dramatic impact on cell resistance and performance. In Chapter 4, the electrochemistry of iron sulfide in nickel/iron porous electrodes in molten sodium tetrachloroaluminate electrolyte was investigated. With the addition of FeS to the electrolyte, results indicate the formation of nickel sulfide species on the metal electrode and an increasing discharge capacity with increasing amount of iron sulfide. The cathode with highest sulfide content appears to be highly resistive. Galvanostatic interrupt experiments shows complex dynamic behavior of sulfide-iron-NiCl₂ galvanic interactions.
With a goal of extending knowledge of kinetic and mass transfer parameters for understanding mass transfer, Chapter 5 discusses the performance of nickel/iron cells for a broader range of temperature, composition and current. The experiments were tested at different temperatures. Also, three granule compositions with different iron levels are tested at four different current rates. The data from this study can be for use in a complete model of the sodium-nickel/iron chloride cell and in the optimization of the electrode.
In the previous chapters, a thinner positive electrode is used in order to remove the effects of macro-scale mass transfer. Chapter 6 discusses the impact of thickness of the cathode on the mass macro-scale transfer and conduction within the metal chloride and metal phase. The goal is to improve modeling of tortuosity as a function of state of charge because transport is important in real systems, and modeling ohmic resistance, for example, can be challenging.
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Degradation of graphite electrodes in acidic bromine electrolytesBistrika, Alexander A. 01 April 2015 (has links)
As the world's power needs grow, the demand for power from renewable resources, such as wind or solar is increasing. One major drawback associated with these renewable resources is that the power output is dependent on environmental factors, such as cloud cover and wind speeds. This allows the possibility of either power output exceeding or falling short of forecast levels that may lead to grid instabilities. Therefore, Large Scale Energy Storage (LSES) systems are critical to store excess power when the output exceeds demand in order to supplement output power when it falls short of demand.¹ The Zinc/Bromine Redox Flow Battery (RFB) is a promising technology because of previously reported long cycle-life (CL) capability, high efficiencies, low cost materials, and scalable operating conditions.² The excellent energy storage performance of the Zinc/Bromine system was confirmed by measuring both Faradaic and Coulombic electrochemical cell efficiency dependence on temperature of a bench scale Zinc/Bromine flow cell. At room temperature, near 75% Faradaic efficiency was measured when cycling the system between 20% and 100% State of Charge (SOC), which is in good agreement with published values,³ and was measured to be over 80% efficient when operating at an elevated temperature of 50°C.
To elucidate capital and operational costs, key system operation parameters especially focused on degradation mechanisms were investigated. Since deep discharge cycling is perceived as highly damaging to electrochemical systems, a system was cycled between 0% and 5% (SOC) 10,000 times. Performance was quantified by measuring the frequency factor (i[subscript 0]) and relative activation energy (α) for the reactions using Tafel scans. No statistically significant degradation or change to the electrodes was observed during the zero point cycling experiment. However, it was found that under conventional operation damage to the electrodes does accumulate, presumably due to the highly oxidative environment caused by the presence of high concentrations of dissolved bromine or tri-bromide. While the performance of both electrodes shows decreases in frequency factor attributed to the damage process, the bromide oxidation process seems to be more damaging (i.e., at the positive electrode during the charging process). Long term measurements show a degradation of the electrocatalytic parameters at an applied overpotential of 100 mV from ca. 40 mA/cm² to ca. 5 mA/cm² at the positive electrode and from ca. 20 mA/cm² to ca. 10 mA/cm² for the negative electrode. A degradation rate model was proposed to predict the service life expectancy of graphite electrodes in a bromine system based on processes showing a combined second order reaction rate coupled with a negative first order reaction rate. The model can be used to predict the cost of energy when operating any device using graphite electrodes, based on the operating power ratio, defined here as the quotient between operating power and system rated power. This damage could be partially reversed by exposing the electrode surfaces to concentrated potassium hydroxide dissolved in isopropanol, presumably due to exfoliation of the electrocatalytic surface leading to the exposure of a clean surface with electrocatalytic performance close to the original. Further, a chemical pretreatment for the graphite surface imparting enhanced stability in aqueous bromine systems was developed that shows negligible damage when similar amounts of current have passed through the electrode surface. After bromide oxidation equivalent to passing ca. 10 Ah/cm² the treated surface showed a change in steady state current density at an applied overpotential of 100 mV from ca. 50 mA/cm² to ca. 48 mA/cm². / Graduation date: 2013 / Access restricted to the OSU Community at author's request from April 1, 2013 - April 1, 2015
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A new chemical synthesis for vanadium sulfide as high performance cathodeWen Chao, Lee January 2014 (has links)
Indiana University-Purdue University Indianapolis (IUPUI) / Since 1990s, rechargeable Li-ion batteries have been widely used in consumer electronics such as cell phones, global positioning systems (GPS), personnel digital assistants (PDA), digital cameras, and laptop computers. Recently Li-ion batteries received considerable attention as a major power source for electric vehicles. However, significant technical challenges still exist for widely deploying Li-ion batteries in electric vehicles. For instance, the energy density of Li-ion batteries is not high enough to support a long-distance commute. The Li-ion batteries used for the Nissan Leaf and Chevy Volt only can support 50 – 100 miles per charge. The cost of Li-ion battery packs in electric vehicles is still high. The battery pack for the Chevy Volt costs about $8,000, and the larger one in the Nissan Leaf costs about $12,000. To address these problems, new Li-ion battery electrode materials with high energy density and low cost should be developed. Among Li-ion battery cathode materials, vanadium pentoxide, V2O5, is one of the earliest oxides studied as a cathode for Li-ion batteries because of its low cost, abundance, easy synthesis, and high energy density. However, its practical reversible capacity has been limited due to its irreversible structural change when Li insertion is more than x = 1.
Tremendous efforts have been made over the last twenty years to improve the phase reversibility of LixV2O5 (e.g., 0 ≤ x ≤ 2) because of vanadium pentoxides’ potential use as high capacity cathodes in Li-ion batteries. In this thesis, a new strategy was studied to develop vanadium pentoxide cathode materials with improved phase reversibility. The first study is to synthesize vanadium oxide cathodes via a new chemical route – creating a
phase transformation from the vanadium sulfide to oxide. The β-Na0.33V2O5 was prepared via a new method of chemical synthesis, involving the chemical transformation of NaVS2 via heat-treatment at 600 °C in atmospheric air. The β-Na0.33V2O5 particles were well crystalized and rod-shaped, measuring 7–15 μm long and 1–3 μm wide with the formation of the crystal defects on the surface of the particles. In contrast to previous reports contained in the literature, Na ions were extracted, without any structural collapse, from the β -Na0.33V2O5 structure and replaced with Li ions during cycling of the cell in the voltage range, 1.5 V to 4.5 V. This eventually resulted in a fully reversible Li intercalation into the LixV2O5 structure when 0.0 ≤ x ≤ 2.0.
The second study is to apply the synthesis method to LiVS2 for the synthesis of β׳-LixV2O5 for use as a high performance cathode. The synthesis method is based on the heat treatment of the pure LiVS2 in atmospheric air. By employing this method of synthesis, well-crystalized, rod-shaped β׳-LixV2O5 particles 20 – 30 μm in length and 3 – 6 μm in width were obtained. Moreover, the surface of β׳-LixV2O5 particles was found to be coated by an amorphous vanadium oxysulfide film (~20 nm in thickness). In contrast to a low temperature vanadium pentoxide phase (LixV2O5), the electrochemical intercalation of lithium into the β׳-LixV2O5 was fully reversible where 0.0 < x < 2.0, and it delivered a capacity of 310 mAh/g at a current rate of 0.07 C between 1.5 V and 4 V. Good capacity retention of more than 88% was also observed after 50 cycles even at a higher current rate of 2 C.
The third study is the investigation of NaVS2 as a cathode intercalation material for sodium ion batteries. We have shown that reversible electrochemical deintercalation of x ~ 1.0 Na per formula unit of NaxVS2, corresponding to a capacity of ~200 mAh/g, is possible. And a stable capacity of ~120 mAh/g after 30 cycles was observed.
These studies show that the new chemical synthesis route for creating a phase transformation from the vanadium sulfide to oxide by heat treatment in air is a promising method for preparing vanadium oxide cathode material with high reversibility. Although this sample shows a relatively low voltage range compared with other cathodes such as LiCoO2 (3.8 V) and LiFePO4 (3.4 V), the large capacity of this sample is quite attractive in terms of increasing energy density in Li-ion batteries. Also, NaVS2 could be a promising cathode material for sodium ion batteries.
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