An organic Schottky barrier cell, consisting of a thin layer of the organic semiconductor, GaPc-Cl, in contact with gold on one side and an electrolyte containing a redox couple on the other, was developed as a solar energy conversion device. Schottky barriers were formed at both interfaces. Film morphology, as determined by the sublimation rate, was the major determinant of the photoelectrochemical behavior. An optimum film consisted of a single layer of crystallites about 1.0 micron in thickness, tightly packed together to give a non-porous film. Thinner films did not develop the full theoretical photopotential, and pores acted as recombination sites, decreasing the efficiency. Both negative and positive photopotentials could be developed, depending on the redox couple used. The photopotential, was found to be proportional to the differences between the Fermi level of the Au and the formal potential of the redox couple. Hydrogen evolution was possible with up to 0.1% solar efficiency on a platinized version of the optimum electrode. Results from photocurrent action spectra and pulsed laser photocoulostatics, showed the potential drop across the film was not linear, but formed a potential well about 0.1 eV deep, which captured charge carriers and decreased the efficiency. From scanning electron microscope studies, phthalocyanines, such as AlPc-Cl, GaPc-Cl, and InPc-Cl, with bulky anions were found to form block-like crystal structures favorable for use in Schottky barrier cells. Phthalocyanines with transition metals in the +2 oxidation state, such as FePc and MgPc, were found to form long needles, which were not favorable for use in Schottky barrier cells.

The aim of this study was to investigate the electrochemical and electrocatalytic properties of a selection of glassy alloys for the hydrogen evolution reaction in base. The glassy alloy compositions tested included the known alloys Fe67Co18B14Si1, Co66Fe4Si16B12Mo2, Fe40Ni40B20 and Fe40Ni40P14B6 and an entirely new alloy Zr74Ti19Cu2Fe5. The electrochemical techniques employed were cyclic voltammetry and slow sweep polarisation. Electrochemical techniques were used in conjunction with the surface analysis techniques of scanning electron microscopy (SEM) and energy dispersive x-ray spectrometry (EDS) to gain insight into the morphology and chemical compositions of the electrode surfaces after various treatments. The aims included: 1) To obtain an understanding of the field of electrochemistry of glassy alloys. 2) To develop systems, techniques and procedures to enable the testing of a new alloy to be performed with confidence. 3) To this end, techniques were firstly developed and then compared with published data on the known alloys. Once the handling techniques were satisfactory the new and previously untested Zr74Ti19Cu2Fe5 glassy alloy was characterised, in particular its catalytic properties and its corrosion resistant properties were investigated. The physical properties of the Zr74Ti19Cu2Fe5 alloy are under investigation by another group in the School of Physics. My findings are presented here. The corrosion resistance of the alloys was determined in their as-polished state and after surface pretreatment from slow sweep anodic polarisation studies and cyclic voltammetry. Glassy Fe67Co18Bl4Si1 and Co66Fe4Si16B12Mo2 displayed the poorest corrosion resistance of the alloy compositions tested. The anodic polarisation curve of the Zr74Ti19Cu2Fe5 alloy produced no active region and displayed potentially excellent anticorrosive properties in the basic media which was attributed to highly passivating Zr oxide and Ti oxide surface films. The electrocatalytic activity of the glassy alloys for hydrogen evolution was evaluated in 1MKOH. Cathodic polarisation curves were used to construct Tafel plots from which the kinetic Tafel parameters, i0 and b, were calculated. The least corrosion resistant glassy alloy compositions, Fe67Co18B14Sil and Co66Fe4Si16B12Mo2, displayed the highest catalytic activity for hydrogen evolution in the as-polished state. The most corrosion resistant alloy, Zr74Ti19Cu2Fe5, showed the poorest catalytic activity for the reaction in the as-polished state and only a slight improvement was obtained by increasing the electrolyte temperature in comparison to the other alloys tested. This was again attributed to passivating Zr oxide and Ti oxide surface layers that inhibited the HER. It was found that the Zr-based alloy displayed no substantial advantages over the other glassy alloys or more expensive noble metal surfaces in basic media, unless pre-treated as described in this thesis. The influence of ex situ chemical pretreatment on the electrocataytic activity of the glassy alloys for the HER was determined using pure HF and HF/HNo3 mixtures. Acid pretreatment of glassy C066Fe4SiI6B12M02 and Fe40Ni40Pl4B6 with IM HF/lM HN03 (10 minutes) and Zr74Til9Cu2Fe5 with 1M HF (10 seconds) resulted in a significant improvement in the activity of the alloys in comparison to their as-polished state. SEM/EDS analysis indicated that preferential dissolution of a P-enriched surface region on the Fe40Ni40P14B6 electrode created a porous structure with a greatly enlarged surface area at which the HER could occur. In comparison, the P-free, Fe40Ni40B20, composition displayed a much lower improvement in activity after acid pretreatment with only slight surface roughening observed. The Zr component of glassy Zr74Ti19Cu2Fes was selectively leached by acid pretreatment to produce a porous surface, however, the corrosion resistance of the alloy was also reduced, as indicated from anodic polarisation curve that showed an active and passive region of greater current density than the as-polished electrode. Hence the beneficial effect of acid pretreatment in activating the alloy surface for the HER was countered by a reduction in the general corrosion resistance of the alloy. In view of the dramatic effect on the HER shown by prior ex situ (acidic) oxidation of the glassy alloy surface, the influence of in situ (anodic) oxidation in the basic medium was investigated for comparison. For all the glassy alloy compositions tested, anodic activation was found to be less effective than acidic activation. Anodic pretreatment of glassy Zr74Ti19Cu2Fe5 (3000µA.cm-2) resulted in the greatest improvement in activity in comparison to the as-polished state out of the alloy compositions tested. In addition, the corrosion resistance of the alloy was not reduced by anodic pretreatment and consequently formed a less destructive activation procedure than acidic pretreatment. In this regard, anodic pretreatment would produce a more durable electrocatalyst and is the preferred technique for activating the glassy alloy surfaces for the HER. Initial characterisation of the surface deposits formed by anodic oxidation, using SEM and EDS techniques, indicates that the composition of these deposits and the mechanism by which anodic activation activates the glassy alloy surfaces requires further investigation. / Thesis (M.Sc.)-University of Natal, Durban, 1999.

No description available.

表面等離子體基元共振是自由電子在納米尺寸的集體共振效應，該效應會產生一系列新奇的性質。貴金屬納米結構由於可以產生表面等離子體基元共振而受到各個領域廣泛的關注。在共振激發的情況下，貴金屬納米結構具有極大的散射和吸收截面積以及極強的進場放大效應。這些奇特的性質可以應用於傳感、成像、光學調製、光熱療、光催化和太陽能電池等領域。金和銀納米結構由於其表面等離子體基元共振波長處在可見和近紅外波段而受到廣泛研究。然而，在某些應用中純金或純銀納米結構不能起到很好的作用。例如，金和銀對很多化學反應的催化活性很弱或者沒有催化活性。如果把金和銀與其他金屬複合在一起就可以同時獲得表面等離子基元共振和其他效應。在我的博士研究期間，我製備了Au/Ag 和Au/Pd 複合雙金屬納米結構和研究了該複合結構的表面等離子體基元共振的性質和在氫氣傳感和光催化中的應用。 / 由於在金屬納米結構的製備中晶種起著至關重要的作用，所以我首先研究了晶種的晶體結構和形狀對雙金屬納米結構合成的影響。我研究了銀和鈀分別在相同條件下在單晶金納米棒、多晶金納米棒和納米雙錐種子上的生長過程。研究發現當晶種是單晶金納米棒時，銀和鈀的生長形成長方體雙金屬納米結構。然而，當晶種是多晶的金納米棒和納米雙錐時，銀和鈀的生長生成納米棒雙金屬結構。銀和鈀在多晶金納米棒上的生長由兩端開始，而在多晶金納米雙錐上的生長由臺階面開始。這表明在雙金屬納米結構的生長過程中納米晶種的晶體結構對最終納米結構的形貌具有決定性的作用，而納米晶種的形狀對生長動力學有明顯的影響。 / 在Au/Ag納米晶製備過程中，我發現Au/Ag納米晶具有四個表面等離子體基元共振峰。於是我對這四個共振峰的演變和共振模式進行了實驗和理論研究。電動力學模擬表明能量最低的共振峰是縱向的電偶極共振，能量次低的共振峰是沿橫向的電偶極共振，兩個高能量的共振峰是沿著橫向的電八極共振。遲滯效應和兩個垂直橫向激發的干涉是導致形成兩個電八極共振的關鍵因素。研究發現隨著銀殼厚度的增加，縱向電偶極共振峰藍移，橫向電偶極共振峰先藍移后稍微紅移，兩個電八極共振沒有明顯的峰位移動。四個表面等離子體基元共振的強度都隨著銀殼厚度的增加而增強。 / 鈀被廣泛地應用於氫氣傳感和催化反應中。於是我研究了Au/Pd 雙金屬納米結構的氫氣傳感和光催化性能。在氫氣傳感研究中，我製備了兩種不同結構的Au/Pd 納米結構。一種具有連續的鈀殼層，另一種鈀殼層不連續。對於具有連續鈀殼層的納米結構，氫氣的傳感性能隨著鈀殼層厚度的增加而增加。實驗發現當納米結構暴露在4%的氫氣中時表面等離子體基元共振峰移動高達56 nm。不連續鈀殼層的納米結構的氫氣傳感性能不如連續鈀層的納米結構。我進一步對Au/Pd 雙金屬納米結構的光催化性能進行了研究。所選取的催化反應是Suzuki 偶聯反應。研究結果表明Au/Pd 納米結構可以有效地捕獲光能來促進化學反應。由於Au/Pd 納米結構使表面等離子體基元共振功能和催化功能緊密集成在一個納米結構中，因此表面等離子基元共振部份所捕獲的光能可以有效地傳遞到催化功能部份而實現光催化。研究發現熱電子效應和光熱轉化效應同時加速化學反應。其中光熱轉化在我的實驗中體現為非局部加熱效應，熱電子對化學反應的促進作用依賴于環境溫度。因此，光熱轉化效應可以促進熱電子轉移效應。 / 本論文的研究結果有助於人們瞭解具有表面等離子體基元共振性質的雙金屬納米機構的設計和應用。對Au/Ag雙金屬納米結構表面等離子體基元共振性質的研究不僅加深了人們對雙金屬表面等離子體基元共振的瞭解而且對利用不同共振模式實現特定功能有著指導意義。對Au/Pd雙金屬納米結構在氫氣傳感和催化反應應用中的研究明確表面雙金屬表面等離子體納米結構可以實現單一組成不具備的功能，這在一定程度上有助於擴展表面等離子基元共振在生命科學、能源和環境領域的應用。 / Noble metal nanocrystals have attracted great interest from a wide range of research fields because of their intriguing properties endowed by their localized surface plasmon resonances, which are the collective oscillations of free electrons. Under resonant excitation, metal nanostructures exhibit very large scattering and absorption cross sections and large near-field enhancement. These extraordinary properties can be used in different applications, such as plasmonic sensing and imaging, plasmon-controlled optics, photothermal therapy, photocatalysis, solar cells, and so on. Gold and Silver nanocrystals have plasmon resonances in the visible and near-infrared regions. However, gold and silver are not suitable for some applications. For example, they are generally inactive for catalyzing chemical reactions. The integration of plasmonic metals with other metals can offer superior or new physical/chemical properties. In this thesis, I prepared Au/Ag and Au/Pd bimetallic nanostructures and studied their lasmonic properties and applications in hydrogen sensing and photocatalysis. / Seeds have a crucial importance in the synthesis of bimetallic nanostructures. I therefore first studied the roles of the crystalline structure and shape of seeds on the overgrowth of bimetallic nanostructures. The overgrowth of silver and palladium on single crystalline Au nanorods, multicrystalline Au nanorods, and nanobipyramids were studied under the same conditions for each metal. The growths of silver and palladium on single crystalline Au nanorods gave cuboidal nanostructures, while rod-shaped nanostructures were obtained from the growths of silver and palladium on multicrystalline Au nanorods and nanobipyramids. Moreover, the growths of silver and palladium on multicrystalline Au nanobipyramids started at the stepped side facets, while the growths started at the twin boundaries on multicrystalline Au nanorods. These results unambiguously indicate that the crystalline structure of seeds plays a significant role on the final morphologies of multimetallic nanostructures, while the seed shape has a prominent effect on the growth kinetics. / Four plasmon resonance bands were observed in Au/Ag bimetallic nanocrystals. I then studied the evolution and nature of the four plasmon bands during the silver coating on Au nanorods both experimentally and theoretically. Electrodynamic simulations revealed that the lowest-energy peak belongs to the longitudinal dipolar plasmon mode, the second-lowest-energy peak is the transverse dipolar plasmon mode, and the two highest-energy peaks can be attributed to octupolar plasmon modes. The retardation effect and the interference between two perpendicularly polarized excitations along the edge directions are important for the formation of the distinct highest-energy and second-highest-energy octupolar plasmon modes, respectively. As the Ag shell thickness is increased, the longitudinal plasmon mode blue-shifts, the transverse plasmon mode first blue-shifts and then red-shifts slightly, and the two octupolar plasmon modes stay at nearly constant wavelengths. The extinction intensities of all the four plasmon bands increase with the increase of the overall particle size. / Palladium is widely used in hydrogen sensing and catalysis. I therefore studied the applications of Au/Pd bimetallic nanostructures in hydrogen sensing and photocatalysis. Two types of Au/Pd bimetallic nanostructures, nanostructures with continuous and discontinuous Pd shells, were employed to study their hydrogen sensing performances. For the nanostructures with continuous Pd shell, the hydrogen sensing performances were improved with the increase in the Pd shell thickness. A plasmon shift of 56 nm was observed when the hydrogen concentration was 4%. The nanostructures with discontinuous Pd shell exhibited smaller plasmon shifts compared with those with continuous Pd shell. For the photocatalytic application of Au/Pd bimetallic nanostructures, I studied their photocatalytic performance for Suzuki coupling reactions. The results indicate that plasmonic Au/Pd bimetallic nanostructures can efficiently harvest light energy for chemical reactions. The intimate integration of plasmonic and catalytic components in one nanostructure enables the light energy absorbed by the plasmonic component to be directly transferred to the catalytic component. Both hot electron transfer and photothermal heating contribute to the plasmon-enhanced chemical reactions. The photothermal effect is a nonlocal heating and the contribution of the hot electron transfer effect is dependent on the environmental temperature. Therefore, the photothermal heating effect can promote the hot electron transfer effect. / I believe that my research work will be very helpful for the design and application of plasmonic bimetallic nanostructures. My study on the plasmonic properties of Au/Ag bimetallic nanocrystals has deepened the understanding of the plasmons of Au/Ag nanorods and will be helpful for utilizing the different modes to achieve specific functions. The hydrogen sensing and photocatalysis of Au/Pd bimetallic nanostructures have shown that the integration of functional components with plasmonic nanostructures can achieve unconventional properties, which will flourish the applications of plasmons in life sciences, energy, and environmental areas. / Detailed summary in vernacular field only. / Detailed summary in vernacular field only. / Detailed summary in vernacular field only. / Detailed summary in vernacular field only. / Detailed summary in vernacular field only. / Jiang, Ruibin = 雙金屬納米結構表面等離子體基元共振的研究及其在氫氣傳感和化學反應中的應用 / 江瑞斌. / Thesis (Ph.D.)--Chinese University of Hong Kong, 2013. / Includes bibliographical references. / Abstracts also in Chinese. / Jiang, Ruibin = Shuang jin shu na mi jie gou biao mian deng li zi ti ji yuan gong zhen de yan jiu ji qi zai qing qi chuan gan he hua xue fan ying zhong de ying yong / Jiang Ruibin. / Abstract --- p.I / Acknowledgements --- p.VI / Table of Contents --- p.VIII / List of Figures --- p.X / List of Tables --- p.XIII / Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- Localized surface plasmon resonances --- p.1 / Chapter 1.2 --- Applications of localized surface plasmon resonances --- p.3 / Chapter 1.3 --- Overview of this thesis --- p.13 / Chapter 2 --- Theory, Simulation, and Experimental Methods for the Investigation of LSPRs --- p.20 / Chapter 2.1 --- Theoretical methods --- p.20 / Chapter 2.2 --- Simulation methods --- p.30 / Chapter 2.3 --- Experimental methods --- p.35 / Chapter 3 --- Preparation of Metal Nanostructures --- p.43 / Chapter 3.1 --- Preparation methods for Au nanocrystals --- p.43 / Chapter 3.2 --- Seed-mediated growth method --- p.46 / Chapter 3.3 --- Metal nanostructure preparations --- p.54 / Chapter 4 --- Crystalline Structure-Determined Growth of Bimetallic Nanocrystals --- p.62 / Chapter 4.1 --- Au nanocrystal seed preparation --- p.64 / Chapter 4.2 --- Au/Ag bimetallic nanocrystals --- p.66 / Chapter 4.3 --- Au/Pd bimetallic nanocrystals --- p.71 / Chapter 4.4 --- Summary --- p.77 / Chapter 5 --- Plasmons of Au/Ag Core/Shell Bimetallic Nanocrystals --- p.83 / Chapter 5.1 --- Variations of plasmons with Ag shell thickness --- p.86 / Chapter 5.2 --- Nature of the different plasmon modes --- p.94 / Chapter 5.3 --- Summary --- p.99 / Chapter 6 --- Au/Pd Bimetallic Nanostructures for Hydrogen Sensing --- p.105 / Chapter 6.1 --- Au nanorods with continuous Pd shell for hydrogen sensing --- p.107 / Chapter 6.2 --- Au nanorods with discontinuous Pd shell for hydrogen sensing --- p.114 / Chapter 6.3 --- Theoretical simulations --- p.117 / Chapter 6.4 --- Summary --- p.119 / Chapter 7 --- Plasmon-Enhanced Chemical Reactions --- p.124 / Chapter 7.1 --- Mechanisms of plasmon enhancement in chemical reactions --- p.125 / Chapter 7.2 --- Plasmon-enhanced Suzuki coupling reactions --- p.129 / Chapter 7.3 --- Summary --- p.149 / Chapter 8 --- Conclusions --- p.156 / Curriculum Vita --- p.160

各種納米結構的光學反應，已成為一被相當關注的課題，在物理理論和應用技術的層面上被廣泛研究。在本文中，我們利用格林函數方法(GFF)，研究了新月形圓柱体和兩接近中的圓柱体的靜電共振。格林函數方法裏涉及一表面積分方程式，我們求該方程的解便可以得出各不同形狀的納米結構的電勢。格林函數方法是一容易使用、高效率的方法，並且在研究納米結構的光學行為的問題上得出準確結果。 / 在論文的第一部分，我們計算了新月形圓柱体和兩接近中的圓柱体的杆光譜，從而研究該兩個結構的靜電共振。然而，當這兩個結構中有接觸點時，系統中便有一奇點，因此我們不能直接使用格林函數方法研究這情況。為了解決這問題，我們首先使用了變換光學的方法，求得該結構的雙極因子，再從中得到其有效介電常數的譜密度。為了比較非接觸情況中離散的杆光譜和接觸情況中的連續杆光譜，我們進一步定義了一累積分佈函數，它是其譜密度的累積分佈函數。我們從而發現當系統由非接觸的情況漸近接觸時，其離散的杆光譜便趨向其相應的連續杆光譜。 / 在論文的第二部分，我們直接研究了新月形圓柱体和兩接近中的圓柱体的勢分佈和電埸分佈。我們發現在新月形圓柱体和兩接近中的圓柱体的系統中，能量會分別將集中於其金屬間隔和空氣間隔附近的區域。當我們適當地選擇系統的參數時，其共振及能量更能進一步增強。我們亦確認了使用格林函數方法和使用保角變換方法兩者得出的結果的是吻合的。我們的研究結果可以幫助設計電漿子捕光裝置。 / The optical responses of various nanostructures have attracted a considerable attention and they have been extensively studied from the theoretical and technological points of view. In this thesis, we have studied the electrostatic resonance of crescent-shaped cylinder and two approaching cylinders by the Green function formalism (GFF). In the GFF, a surface integral equation is formulated for the scalar potential for an arbitrary number of nanostructures of various shapes. GFF is easy to apply and gives accurate results for the optical behaviors of these nanostructures. / In the first part of the thesis, we have studied the electrostatic resonance of crescent-shaped cylinder and two approaching cylinders by calculating the pole spectrum. However, in the touching case, there is a singular point and thus the GFF cannot be applied directly. To circumvent this problem, the spectral density is found from the polarizability of the nanostructure, which can be obtained analytically by the transformation optics approach. To compare the discrete pole spectrum of the non-touching cases with the continuous spectrum of the touching case, we have used the cumulative distribution function of the spectral density. We are then able to show that the discrete pole spectrum approaches to the continuous pole spectrum as the system approaches from non-touching cases to the touching case. / In the second part of the thesis, the electrostatic resonance is investigated by directly finding the local field distributions of crescent and two approaching cylinders under a uniform applied electric field. It is shown that there is an energy concentration within the metal narrow gap and the air narrow gap in the cases of crescent and two approaching cylinders respectively. It is also found that when parameters are carefully chosen, the nanoconcentration of energy will be greatly enhanced. The numerical GFF results are confirmed with the analytic results by conformal transformation. The results are useful in designing plasmonic light-harvesting devices. / Detailed summary in vernacular field only. / Detailed summary in vernacular field only. / Detailed summary in vernacular field only. / Yung, Sai Kit = 電漿子納米結構中的能量集中 : 格林函數方法 / 翁世杰. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2012. / Includes bibliographical references (leaves 71-74). / Abstracts also in Chinese. / Yung, Sai Kit = Dian jiang zi na mi jie gou zhong de neng liang ji zhong : Gelin han shu fang fa / Weng Shijie. / Abstract --- p.i / 摘要 --- p.iii / Acknowledgements --- p.iv / Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- Optical responses in plasmonic systems --- p.1 / Chapter 1.2 --- Objective of the thesis --- p.5 / Chapter 2 --- Review on Green function formalism --- p.7 / Chapter 2.1 --- Integral equation formalism --- p.7 / Chapter 2.2 --- Periodic corrugated interfaces --- p.11 / Chapter 2.3 --- Solution by mode expansion --- p.16 / Chapter 2.4 --- Numerical solution --- p.18 / Chapter 3 --- Pole spectrums of crescent-shaped cylinder and approaching cylinders --- p.21 / Chapter 3.1 --- Review of Green function formalism on the spectral representation of the effective dielectric constant --- p.22 / Chapter 3.2 --- Numerical results --- p.29 / Chapter 3.2.1 --- Spectral representation of the effective dielectric constant of crescent-shaped cylinders --- p.29 / Chapter 3.2.2 --- Spectral representation of the effective dielectric constant of approaching cylinders --- p.37 / Chapter 4 --- Energy concentration of crescent and approaching cylinders --- p.44 / Chapter 4.1 --- Energy concentration of crescent-shaped cylinder --- p.45 / Chapter 4.2 --- Energy concentration of approaching cylinders --- p.53 / Chapter 5 --- Conclusion --- p.58 / Chapter 5.1 --- Suggestion of future works --- p.60 / Chapter A --- Conformal transformation --- p.61 / Chapter A.1 --- Conformal transformation on crescent-shaped cylinder: nontouching case --- p.61 / Chapter A.2 --- Conformal transformation on approaching crescent-shaped cylinders --- p.66 / Bibliography --- p.71

by Wah-chung Wong. / Thesis (M.Ph.)--Chinese University of Hong Kong, 1987. / Bibliography: leaves 155-162.

by Chan Hing Nam = 壓力對La₀.₆₇Ca₀.₃₃MnO₃薄膜的導電能的效應 / 陳慶楠. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2001. / Includes bibliographical references. / Text in English; abstracts in English and Chinese. / by Chan Hing Nam = Ya li dui La₀.₆₇Ca₀.₃₃MnO₃ bo mo de dao dian neng de xiao ying / Chen Qingnan. / Acknowledgements --- p.i / Abstract --- p.ii / 論文摘要 --- p.iii / Table of contents --- p.iv / Chapter Chapter 1 --- Introduction / Chapter 1.1 --- Introduction to colossal magnetoresistance --- p.1-1 / Chapter 1.2 --- Effects of chemical pressure and strain on LCMO thin films --- p.1-7 / Chapter 1.3 --- Review of pressure effects on bulk LCMO --- p.1-11 / Chapter Chapter 2 --- Instrumentation and Characterization / Chapter 2.1 --- Preparation of LCMO thin films --- p.2-1 / Chapter 2.2 --- X-ray diffraction (XRD) --- p.2-3 / Chapter 2.3 --- Self-clamping pressure cell --- p.2-5 / Chapter 2.3.1 --- Electrical feedthroughs --- p.2-5 / Chapter 2.3.2 --- Teflon cell --- p.2-8 / Chapter 2.3.3 --- Pressure variations in the pressure-transmitting medium --- p.2-9 / Chapter Chapter 3 --- Pressure effect on LCMO thin films grown on different substrates / Chapter 3.1 --- Annealing effect --- p.3-1 / Chapter 3.2 --- Thickness effect --- p.3-4 / Chapter 3.3 --- Lattice effect and pressure effect --- p.3-5 / Chapter 3.4 --- Crystallinity effect --- p.3-13 / Chapter Chapter 4 --- Activation energy of small polaron in LCMO thin films / Chapter 4.1 --- Motivation --- p.4-1 / Chapter 4.2 --- Basic theory --- p.4-2 / Chapter 4.3 --- Activation energy --- p.4-4 / Chapter Chapter 5 --- Conclusion --- p.5-1

by Sin Lai Yi, Mandy. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2002. / Includes bibliographical references (leaves 120-121). / Text in English; abstracts in English and Chinese. / by Sin Lai Yi, Mandy. / Abstract --- p.ii / 論文摘要 --- p.iii / Acknowledgements --- p.iv / Table of Contents --- p.v / List of Figures --- p.ix / List of Tables --- p.xiii / Chapter Chapter 1 --- Introduction / Chapter 1.1 --- Adhesion --- p.1 / Chapter 1.2 --- Adhesion issues in PLEDs --- p.1 / Chapter 1.3 --- Literature review of the adhesion measurement techniques --- p.4 / Chapter 1.3.1 --- Methods involving detachment normal to the interface --- p.4 / Chapter 1.3.1.1 --- Direct pull-off method --- p.5 / Chapter 1.3.2 --- Methods based upon the application of lateral stresses for detachment --- p.7 / Chapter 1.3.2.1 --- Scotch tape method --- p.7 / Chapter 1.3.2.2 --- Peel test --- p.8 / Chapter 1.4 --- Motivations and aims of studies --- p.11 / Chapter 1.5 --- Outline of the thesis --- p.12 / Chapter Chapter 2 --- Experimental and Instrumentation / Chapter 2.1 --- Sample preparation --- p.13 / Chapter 2.2 --- Instrumentation --- p.13 / Chapter 2.1.1 --- Modified Scotch tape method --- p.13 / Chapter 2.2.2 --- Atomic force microscope --- p.23 / Chapter 2.2.3 --- X-ray photoelectron spectroscopy --- p.26 / Chapter 2.2.4 --- Radio-frequency (RF) plasma etching system --- p.27 / Chapter Chapter 3 --- Verification of the modified Scotch tape method / Chapter 3.1 --- Introduction --- p.31 / Chapter 3.2 --- Verification Test One ´ؤ Measurement against different adhesive tapes --- p.31 / Chapter 3.3 --- Verification Test Two ´ؤ Measurement with different crosshead speeds --- p.40 / Chapter 3.4 --- Verification Test Three ´ؤ Measurement of adhesive tapes with different sizes --- p.46 / Chapter 3.5 --- Summary --- p.51 / Chapter Chapter 4 --- Adhesion of gold films coated on the plasma treated ITO / Chapter 4.1 --- Introduction --- p.53 / Chapter 4.2 --- Characteristics of RF plasma etching --- p.53 / Chapter 4.2.1 --- Test One ´ؤ Study the relationship between sputtering time and sputtering depth --- p.54 / Chapter 4.2.2 --- Test Two - Study the relationship beteen self-bias voltage and sputtering depth --- p.54 / Chapter 4.3 --- Modification of the surface morphology of the Ar plasma treated ITO --- p.57 / Chapter 4.4 --- Quantitative adhesion measurement of gold films on plasma treated ITO --- p.62 / Chapter 4.5 --- Summary --- p.68 / Chapter Chapter 5 --- Adhesion of PFO on ITO with self-assembled monolayers as interfacial layers / Chapter 5.1 --- Introduction --- p.69 / Chapter 5.2 --- Reactions between SAMs and ITO --- p.71 / Chapter 5.3 --- Sample preparation --- p.73 / Chapter 5.4 --- Tests of alkylsilane --- p.74 / Chapter 5.4.1 --- Determination of the point of film detachment --- p.74 / Chapter 5.4.2 --- Adhesion test of PFO/alkylsilane/ITO --- p.79 / Chapter 5.4.3 --- Adhesion test of PF0/alkylsilane/Si02 --- p.91 / Chapter 5.5 --- Tests of phenylsilane --- p.104 / Chapter 5.6 --- Summary --- p.114 / Chapter Chapter 6 --- Conclusions and further studies / Chapter 6.1 --- Conclusions --- p.116 / Chapter 6.2 --- Further studies --- p.118 / References --- p.120

Ng Ka Shun = La₀.₄Ca₀.₆MnO₃/La₀.₈Ca₀.₂MnO₃多層薄膜之龐磁阻 / 吳家信. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2006. / Includes bibliographical references. / Text in English; abstracts in English and Chinese. / Ng Ka Shun = La₀.₄Ca₀.₆MnO₃/La₀.₈Ca₀.₂MnO₃ duo ceng bo mo zhi pang ci zu / Wu Jiaxin. / Acknowledgements --- p.i / Abstract --- p.ii / 論文摘要 --- p.iii / Table of Contents --- p.iv / List of Figures --- p.vi / List of Tables --- p.viii / Chapter Chapter 1 --- Introduction / Chapter 1.1 --- Review of magnetresistance --- p.1-1 / Chapter 1.2 --- Colossal magnetoresistance (CMR) --- p.1-4 / Chapter 1.3 --- Possible mechanism of CMR --- p.1-7 / Chapter 1.3.1 --- Double exchange --- p.1-7 / Chapter 1.3.2 --- Phase separation and percolation theory --- p.1-9 / Chapter 1.3.3 --- Current carrier density collapse --- p.1-12 / Chapter 1.4 --- Our motivation --- p.1-14 / Chapter 1.5 --- Brief review of several manganite multilayer systems --- p.1-15 / Chapter 1.6 --- Scope of this thesis work --- p.1-16 / References --- p.1-17 / Chapter Chapter 2 --- Instrumentation / Chapter 2.1 --- Thin film deposition --- p.2-1 / Chapter 2.1.1 --- Facing target sputtering (FTS) --- p.2-1 / Chapter 2.1.2 --- Connection of heating wires and thermocouple --- p.2-5 / Chapter 2.1.3 --- Vacuum system --- p.2-7 / Chapter 2.2 --- Annealing system --- p.2-9 / Chapter 2.3 --- Characterization --- p.2-11 / Chapter 2.3.1 --- X-ray diffraction (XRD) --- p.2-11 / Chapter 2.3.2 --- Resistance measurement --- p.2-13 / Chapter 2.3.3 --- Thickness estimation --- p.2-15 / References --- p.2-15 / Chapter Chapter 3 --- Growth and characterization of LCMO single layer thin film --- p.3-1 / Chapter 3.1 --- Fabrication and characterization of LCMO targets --- p.3-1 / Chapter 3.2 --- Preparation of LCMO thin film --- p.3-5 / Chapter 3.2.1 --- Deposition conditions --- p.3-5 / Chapter 3.2.2 --- Depostion procedure --- p.3-8 / Chapter 3.2.3 --- Characterization of single layer film --- p.3-9 / References --- p.3-12 / Chapter Chapter 4 --- La0.4Ca0.6MnO3 / La0.8Ca0.2MnO3 multilayers / Chapter 4.1 --- Sample preparation --- p.4-1 / Chapter 4.2 --- Results and discussion --- p.4-4 / Chapter 4.2.1 --- Structural characterization --- p.4-4 / Chapter 4.2.2 --- Transport properties --- p.4-10 / Chapter 4.3 --- Oxygen post-annealing of multilayer thin films --- p.4-13 / Chapter 4.3.1 --- Introduction --- p.4-13 / Chapter 4.3.2 --- Oxygen post-annealing conditions --- p.4-14 / Chapter 4.3.3 --- Results and discussion --- p.4-16 / Chapter 4.4 --- Conclusion --- p.4-26 / References --- p.4-27 / Chapter Chapter 5 --- Conclusion

Yam Chi Tong = 懸浮顆粒之介電反應 / 任智堂. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2005. / Includes bibliographical references (leaves 76-79). / Text in English; abstracts in English and Chinese. / Yam Chi Tong = xuan fu ke li zhi jie dian fan ying / Ren Zhitang. / Chapter 1 --- Introduction --- p.1 / Chapter 2 --- Spectral Representation of a Pair of Polydisperse Cylinders --- p.3 / Chapter 2.1 --- Introduction --- p.3 / Chapter 2.2 --- Multiple Image Method --- p.4 / Chapter 2.2.1 --- Polydispersity in Size --- p.6 / Chapter 2.2.2 --- Polydispersity in Permittivity --- p.7 / Chapter 2.3 --- Spectral Representation --- p.9 / Chapter 2.3.1 --- Polydisperse Size Cylinders --- p.10 / Chapter 2.3.2 --- Polydisperse Permittivity Cylinders --- p.12 / Chapter 2.4 --- Numerical Results --- p.13 / Chapter 2.4.1 --- Polydispersity in Size --- p.14 / Chapter 2.4.2 --- Polydispersity in Permittivity --- p.17 / Chapter 2.5 --- Conclusion --- p.22 / Chapter 3 --- Dielectric Behaviors of Polydisperse Colloidal Suspensions --- p.24 / Chapter 3.1 --- Introduction --- p.24 / Chapter 3.2 --- Dielectric Dispersion Spectral Representation --- p.26 / Chapter 3.3 --- Polydisperse Colloidal Suspensions --- p.28 / Chapter 3.4 --- Numerical Results --- p.30 / Chapter 3.4.1 --- Monodisperse Limit --- p.31 / Chapter 3.4.2 --- Influence of the Medium Conductivities --- p.32 / Chapter 3.4.3 --- Effect of Conductivity Contrasts --- p.34 / Chapter 3.4.4 --- Effect of Varying the Volume Fractions --- p.37 / Chapter 3.5 --- Conclusion --- p.41 / Chapter 4 --- Dielectric Behaviors of Shelled Cell Suspensions --- p.43 / Chapter 4.1 --- Introduction --- p.43 / Chapter 4.2 --- Shelled Spherical Particle Model --- p.46 / Chapter 4.2.1 --- Intrinsic Dispersions --- p.47 / Chapter 4.3 --- Numerical Results --- p.49 / Chapter 4.3.1 --- One Type of Shelled Cells --- p.51 / Chapter 4.3.2 --- Mixture of Two Types of Shelled Cells --- p.60 / Chapter 4.4 --- Conclusion --- p.62 / Chapter 5 --- Dielectric Behaviors of Compositionally Graded Films --- p.64 / Chapter 5.1 --- Introduction --- p.64 / Chapter 5.2 --- Discrete Layer Model --- p.65 / Chapter 5.2.1 --- Linear Profiles --- p.67 / Chapter 5.2.2 --- Gaussian Profiles --- p.67 / Chapter 5.3 --- Continuously Graded Model --- p.68 / Chapter 5.3.1 --- Linear Profiles --- p.68 / Chapter 5.3.2 --- Gaussian Profiles --- p.69 / Chapter 5.4 --- Conclusion --- p.72 / Chapter 6 --- Summary --- p.74 / Bibliography --- p.76 / Chapter A --- The Maxwell-Garnett Approximation --- p.80 / Chapter B --- The Bergman-Milton Spectral Representation --- p.82