Cette thèse est consacrée à l'étude mathématique des propriétés de stabilité de systèmes quantiques infinis, décrits par des modèles non linéaires. Dans les chapitres 1 et 2, on étudie l'instabilité du vide relativiste menant au phénomène de création de paires électron-positron. Dans le chapitre 3, on considère la dynamique de ce même vide relativiste couplé à un champ scalaire. Les chapitres 4 et 5 sont consacrés au caractère dispersif de la dynamique non linéaire de Hartree pour des perturbations de la mer de Fermi, et en particulier à sa stabilité orbitale et asymptotique. Enfin, le chapitre 6 introduit une notion générale d'entropie relative entre deux états comportant une infinité de particules. / This thesis is devoted to the mathematical study of stability properties of infinite quantum systems described by nonlinear models. In chapters 1 and 2, we study the instability of the relativistic vacuum leading to the phenomenon of electron-positron pair production. In chapter 3, we consider the dynamics of this same relativistic vacuum coupled to a scalar field. Chapters 4 and 5 are devoted to the dispersive behaviour of the nonlinear Hartree dynamics for perturbations of the Fermi sea, and in particular to its orbital and asymptotic stability. Finally, chapter 6 introduces a general notion of relative entropy between states having infinitely many particles.

This thesis is devoted to the rare decay π0 → e+ e− . We firstly introduce all theoretical knowledge necessary for the description of the vertices used in this work. Subsequently, we introduce three two-loop chiral Feynman diagrams, which are of order O(α2 p4 ). These diagrams are firstly decomposed to Master integrals by Laporta algorithm. After that, we calculate each Master integral individually by the differential equation technique. We also focus on the renormalization of the process. Since we are working with the effective field theory, finite corrections χ from counterterm diagrams naturally appear. With use of the calculations listed in this thesis, the determination of the parameter χR could be further improved taking into account the whole two-loop correction. 1