Submitted by Automa??o e Estat?stica (sst@bczm.ufrn.br) on 2017-02-13T19:30:58Z No. of bitstreams: 1 HugoDePaivaNunes_DISSERT.pdf: 2913431 bytes, checksum: b94ab79311730ca61ab47671efb0b8f2 (MD5) / Approved for entry into archive by Arlan Eloi Leite Silva (eloihistoriador@yahoo.com.br) on 2017-02-14T18:51:47Z (GMT) No. of bitstreams: 1 HugoDePaivaNunes_DISSERT.pdf: 2913431 bytes, checksum: b94ab79311730ca61ab47671efb0b8f2 (MD5) / Made available in DSpace on 2017-02-14T18:51:47Z (GMT). No. of bitstreams: 1 HugoDePaivaNunes_DISSERT.pdf: 2913431 bytes, checksum: b94ab79311730ca61ab47671efb0b8f2 (MD5) Previous issue date: 2016-07-29 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior (CAPES) / Devido ? grande quantidade de compostos presentes no petr?leo bruto, por exemplo, hidrocarbonetos e o di?xido de carbono, faz-se necess?rio o conhecimento das propriedades termodin?micas dessas misturas e do Equil?brio L?quido-Vapor, pois os processos industriais para obten??o de seus derivados: gasolina, diesel, nafta, querosene, entre outros, utilizam essas propriedades para determina??o das quantidades de calor e trabalho necess?rias ? realizar esses processos. Para fluidos, essas propriedades s?o frequentemente avaliadas a partir de medidas do volume molar como fun??o da temperatura e da press?o, fornecendo rela??es entre press?o, volume e temperatura (PVT), as quais podem ser expressas como equa??es de estado. Esta disserta??o consiste em elencar e avaliar a consist?ncia termodin?mica de dados experimentais de equil?brios dispon?veis na literatura, para os sistemas bin?rios (CO2 ? CH4/C2H6/C3H8/C4H10) e tern?rios (CO2/CH4/C2H6 e CO2/ CH4/C3H8) com temperaturas variando na faixa de 207 ? 419,9 K, e press?es de 0,389 ? 84,080 atm. Assim, utilizou-se a equa??o de estado c?bica de Peng-Robinson e regra de mistura de Van der Waals quadr?tica para a estima??o dos par?metros (Kij), por meio do simulador SPECS com os dados selecionados, afim de fornecer uma base para a descri??o quantitativa do comportamento de fluidos reais e correla??es generalizadas que permitam a predi??o do comportamento PVT de fluidos para os quais n?o h? disponibilidade de dados experimentais. Os erros m?dios observados para a correla??o dos sistemas bin?rios foi de at? 5%, j? para os tern?rios a predi??o apresentou erros ligeiramente maiores de at? 7%, sendo a EDEC PR eficiente nos c?lculos destes sistemas, pela modelagem simples, por?m, com descri??es quantitativa e car?ter preditivo satisfat?rio. / Due to the large amount of compounds present in the crude oil, for example, hydrocarbons and carbon dioxide, it is necessary knowledge of the thermodynamic properties of these mixtures and the vapor-liquid equilibrium, as industrial processes for obtaining their derivatives gasoline, diesel, naphtha, kerosene, among others, use these properties to determine the quantities of heat and work necessary to carry out these processes. For fluid, these properties are often evaluated from measurements of the molar volume as a function of temperature and pressure, providing relationships between pressure, volume and temperature (PVT), which can be expressed as state equations. This paper consists of listing and evaluating the thermodynamic consistency experimental data balances available in the literature for the binary systems (CO2 - CH4/C2H6/C3H8/C4H10) and ternary (CO2/CH4/C2H6 and CO2/CH4/C3H8) with temperatures in the range of 207 to 419,9 K and pressures of 0,389 up to 84,080 atm. Thus, we used the cubic equation of state Peng-Robinson and Van der Walls quadratic mixing rule for the estimation of parameters (Kij) through SPECS simulator with the data selected in order to provide a basis for the description quantitative real behavior of fluids and generalized correlations which allow the prediction of PVT behavior of fluids for which there is availability of experimental data. The average errors observed for the correlation of binary systems was up 5%, while for the ternary prediction showed slightly larger errors of up to 7%, the cubic equation PR efficient in the calculations of these systems, for the simple modeling, but with quantitative descriptions and satisfactory predictive character.