International Telemetering Conference Proceedings / October 17-20, 1988 / Riviera Hotel, Las Vegas, Nevada / In this paper, the group synchronization code (length n = 60 bit) of the TIROS Satellite was analysed. It seems to us the code isn't optimization. A series of optimum group sync codes (n = 60) have been searched out with error tolerance E = 1, 2, 3, 4, 5, 6 and 10, 12. Their error sync probabilities are less than the error sync probability of the TIROS code (from two times to two order of magnitudes about). These optimum or qansi-optimum codes will be presented for application in the second generation of the Meteorological Satellites of China.