This paper aims on the study of developing the firmware program for the monitor chips designed inside the battery set of a Notebook power management system, with the function of monitoring safety during battery charge/discharge via the chips; meanwhile, to estimate the residual capacity of the battery. Owing to the chemistry properties of the battery, whose residual capacity will be affected by the current flow during charge/discharge, high/low of the ambient temperature, fatigue of the battery, as a result, variations of the residual capacity will be presented in non-linear. Therefore, in estimation of the battery residual capacity, using the curve learned from the practical experiment on the battery charge/discharge to be the basis for us to find out the appropriate parameters under the relevant influence factors for revision. It will be more accurate in estimation of the battery residual capacity. At the same time, the battery signal can be transmitted to the managing end of the Notebook power management system via the system management interface, which may enable the system to operate more efficiently.