Waters of various salinities were secured from the Umpqua estuary, the Umpqua River, and the open ocean near the mouth of the estuary. The rate of oxidation of sulfides in these various waters was investigated to assess the potential longevity of free sulfides in estuarine waters. The rate of disappearance of sulfides showed no simple relationship with salinity. Estuarine water exhibited the fastest rate of oxidation with decreasing rates observed in river water and open ocean water. The effects of aged water samples on the oxidation rate of sulfides were investigated. The results indicated that fresher samples exhibit a faster oxidation rate than aged samples in estuarine, open ocean, and river water. / Graduation date: 1973

The funnel-shaped Mgeni Estuary, at the mouth of the fourth largest river along the KwaZulu- Natal coast, discharges into the Indian Ocean in the northern suburbs of Durban. This system is under considerable anthropogenic stress associated with modern development and industrialisation, both adjacent to the estuary and in the catchment area. The construction of Inanda Dam in 1989, immediately upstream of the estuary, is considered to have had an irreversible impact on the system and the estuary and is addressed in this study. A thorough analysis of available maps, aerial photographs and oblique images from 1860 to 2006, provided a record of the changes in the estuary morphology. The Pre-Inanda Dam period is characterised by the repeated re-establishment of a large central bar after major floods as evident prior to the 1987 flood. The post 1989 Inanda-Dam period, however, is characterised by the deposition of a series of side-attached bars and the development of extensive mudflats. Sediment distribution results show a definite decrease in grain size compared to the predominant gravel fraction in 1986 towards an estuary dominated by medium to fine sand-sized sediment. A reduction in sediment grain size is also complemented by an increase in carbonate concentration throughout the estuary. This indicates an increase in marine incursion with decreased fluvial flow suggesting a shift from a river dominated estuary to a marine dominated system since the completion of Inanda Dam. Linked to the finer grained sediment is a higher increased organic and heavy metal concentration. An analysis of the enrichment factor for 9 metals shows that the Mgeni Estuary is significantly contaminated, especially at the head of the estuary. This situation is exacerbated by decreased fluvial flow rates, an increase in the frequency of mouth closures and the reduction in flooding events effectively preventing the removal of contaminants out of the estuary. / Thesis (M.Sc.)-University of KwaZulu-Natal, Westville, 2009.

Abstract not available. / Thesis (M.Sc.)-University of KwaZulu-Natal, Westville, 2005.

South African estuaries have high biodiversity value and provide many benefits to society, including food, real estate, a place for recreation and economic enterprise. However, they are facing growing human pressures such as urban encroachment, development in river catchments and interference in hydrological cycles. This dissertation provides an exploratory study of the environmental history of the Mgeni River Estuary, KwaZulu-Natal in an attempt to improve the understanding of the forces that drive environmental change. Through the application of the techniques and methodologies of environmental history, it explores the dynamics, characteristics and impacts of human interaction with the Mgeni River Estuary over time. It focuses on the emergence of a capitalist! industrial society in the twentieth century as this period has been characterised by the most significant environmental alteration and degradation. With the aid of the techniques and methodologies employed, the study highlights a complexity of natural and human events that have altered the estuary over time. Comparative analysis of aerial photographs between 1937 and 1996 reveals that physical changes to the estuary were linked to prevalent social and economic activities. The study describes cultural beliefs, modes of resource use and the political economy as significant and interwoven factors that facilitate environmentally intrusive activities. The study has provided insights into the complexity of factors that influence the rate and extent of change of an estuarine system. It concludes that to improve the understanding of the causes of environmental change, it is necessary to look further than the physical impacts on the environment to the attitudes and beliefs that underlie them. While the solutions to the problems facing the Mgeni River Estuary are not easily at hand, such analysis should assist policy makers and managers in finding a way to initiate more sustainable estuarine development in the future. / Thesis (M.Sc.)-University of Natal, Pietermaritzburg, 2000.