Manganese is an essential alloying element in the 2nd and 3rd generation of Advanced High Strength steels (AHSS) containing 5 to 25% manganese. A combination of excellent strength and ductility makes these grades of steel attractive for the automotive industry. To produce these steels to meet metallurgical requirements the main concern for the steelmakers is to decrease the carbon concentration as low as 0.1% while suppressing the excessive manganese losses at high temperatures. Argon Oxygen Decarburization (AOD) is a promising candidate for the refining of high manganese steels. This work has studied the kinetics of decarburization and manganese losses during the argon oxygen bubbling into a wide range of iron-manganese-carbon alloys. It was shown that decreasing the initial carbon content increased the manganese loss. In the competition between manganese and carbon for oxygen, alloys with lower initial manganese concentrations consumed a higher portion of oxygen for decarburization. This behavior was not expected by thermodynamics and the results did not support the concept of the critical carbon content either. It was demonstrated that for lower range carbon (≤0.42%) alloys, the total manganese loss can be explained by considering multiple mechanisms in parallel; oxide formation (MnO) and vapor formation (Mn (g)), and formation of Manganese mist by evaporation-condensation (Mn (l)). The evaporation-condensation mechanism was proposed with the assumption that the heat generated from MnO and CO formation increases the temperature at the surface of the bubble which facilitates the evaporation of manganese at a high vapor pressure. Consequently, manganese vapor condenses as fine droplets at the lower temperature inside the bubble. Although dilution of oxygen with argon increased the efficiency of oxygen for decarburization as expected from the mechanism of the AOD process, manganese loss did not stop completely at higher argon concentrations in the gas mixture. Therefore, the bubble and melt do not fully equilibrate with respect to Mn and C. For high carbon alloys (1%), there was excess oxygen after accounting for CO and MnO formation. According to mass balance and thermodynamic calculations, and assuming manganese loss by evaporation was negligible it was shown that oxygen was distributed amongst MnO, FeO, CO, and CO2. It was demonstrated that increasing temperature resulted in the higher manganese loss as a mist and by simple evaporation due to the increased vapor pressure and less manganese loss by oxidation. Furthermore, it was found that the rate of decarburization increased with increasing temperature due to more partitioning of oxygen to carbon than manganese. In addition, it was found that the variations of depth of lance submergence did not affect the rate of decarburization or manganese loss. This means that the reactions occur within such a short time that prolonged time after the reaction is completed does not lead to a repartitioning of the species. / Thesis / Doctor of Philosophy (PhD)

Computational Fluid Dynamics (CFD) has become one of the main instruments for the prediction of many commercial and research oriented fluid flow and heat transfer problems. While single phase flow analysis through CFD has gained grounds within the commercial industry, multiphase flow analysis is still the subject of further research and development. Heat Pipes and thermosyphones are no exception to this. However, the involvement of more than one fluid phase within these devices has made their analysis through CFD more challenging and computationally more demanding to perform. In this thesis, computational fluid dynamics is used as a modelling tool in order to predict the thermal hydraulic behaviour of multiphase environment within thermosyphones and heat pipes. Eulerian two-fluid method is used to solve the conservation equations for mass, momentum and energy, for each phase along with the inclusion of interfacial heat and mass transfer terms. Numerical predictions are obtained for the steady-state and transient operation of stationary thermosyphon, while rotating heat pipes operation is also simulated using axially and radially rotating heat pipe models. Apart from using the commercially available CFD code for the analysis of thermosyphones related simulation, numerical work is performed regarding the coupling of momentum equations based on Eulerian two-fluid modelling scheme. OPENFOAM open source code is used and modified to include the Partial Elimination Algorithm (PEA) for the coupling of interfacial exchange terms, including interfacial mass transfer term, in the momentum equations of both phases. Results obtained from above discussed studies provide good agreement with corresponding experimental and analytical observations.

Hybrid pixel detectors are widely used in many fields, including military, environment, industry and medical treatment. When integrating such a detector, a vertical connection technique called flip-chip bonding is almost the only way to realize the high-density interconnection between each pixel detector to the read-out chip. Such bonding can offer high-density I/O and a short interconnect distance, which can make the resulting device show excellent performance. Electro deposition is a promising approach to enable a low cost and high yield bump bonding process, compared with conventional sputtering or evaporation which is currently utilized for small-scale production. Due to that, Indium bumping process using electroplating is selected, as a result of which indium bump arrays with a pitch of 220 μm and a diameter of 30 μm have been fabricated using a standard silicon wafer processing. UBM (under bump metallization) for indium bumping was Ti/Ni (300 Å/ 2000 Å). It helps to increase adhesion between the wafer and the bumps and also serves as an excellent diffusion barrier both at room temperature and at 200°C. The indium is electroplated, using an indium sulfamate plating bath, and then formed into bumps through a reflow process. The reflow is made on a 200°C hot plate with a continuous flow of nitrogen over the wafer. During the reflow the indium is melted and forms into bumps due to surface tension. All the corresponding procedural processing steps and results are incorporated in this paper.

This Thesis explores physical phenomena characteristic for thin liquid films and small droplets of simple and complex liquids on solid substrates for which wettability and capillarity control their statical and dynamical properties. We start by discussing the general concepts of wettability and capillarity and introduce the common mathematical framework of the lubrication approximation for studies of thin liquid films and small contact angle drops. We demonstrate the derivation of the generic equation describing the evolution of a film of simple liquid from the Navier-Stokes equations. We show how this model can be further extended to incorporate various effects relevant to the case of complex liquids. The results described in the Thesis comprise three projects with the common main theme of the influence of wettability and capillarity on the statics and dynamics of the studied systems, namely (i) Evaporating sessile droplets fed through the solid substrate - a geometry that allows us to discuss steady states of the system and their role in the time evolution of freely evaporating droplets without influx in an isothermal case; (ii) The influence of a solute--dependent wettability on the stability, static and dynamical properties of thin films and drops of non-volatile mixtures, suspensions and solutions; (iii) A parameter-passing scheme between particle-based Molecular Dynamics simulations and the continuum lubrication model which allows us to discuss equilibrium properties of small polymeric droplets. We present the physical questions arising in the three systems and discuss approaches and results as well as possible extensions.

No description available.

No description available.

A simple water balance model was applied to a micro-catchment water harvesting system for a semi-arid area in the North-Eastern part of Jordan. Two Negarim micro-catchment water harvesting systems were built at Al-Khanasri research station. A Randomized complete block design (RCBD) in factorial combination was used with six treatments and three replicates. Each plot was divided into two parts; a runoff area, and a run-on area. Two different treatments were used for the catchment area, these were: compacted (T1) and Natural treatments (T2). Three treatments were used for the run-on area, these were: disturbed (S1), stones (S2), and crop residue mulch (S3). Soil water content was measured over a depth of 0-1 m during the seasons 96-97 in these micro-catchments. In this model; daily rainfall, runoff, and evaporation were used. Runoff was calculated by the curve number method; evaporation was calculated by the Penman equation, the Priestley and Taylor method and the Class A pan approach. The least squares method was used for optimizing model parameters. The performance of the model was assessed by different criteria, such as root mean square error, relative root mean square error, coefficient of determination and the Nash-Sutcliffe efficiency method. The performance of the micro-catchments system was also evaluated. Results showed that with limited but reliable hydrological data good agreement between predicted and observed values could be obtained. The ratio of water storage in a one meter soil depth to the rainfall falling on each catchment indicated that T1S2 and T1S3 have the highest values in size1 plots while T2S1 and T2S2 have the highest values in size 2 plots. Modelling results showed that for all the size 1 plots, the required ratio of the cultivated to catchment area, (C/CA), required to ensure sufficient harvested water, was less than the actual ratio used in the experimental design. For the size 2 plots this was only true for the T1 treatments. Consequently for the majority of plot sizes and treatments, the results showed that a smaller catchment area is capable of providing sufficient harvested water to meet crop growth requirements. The experimental ratio was based on a typical yearly design rainfall for the region having either a 50% or 67% probability of occurrence. Results also indicated that using stones and crop residue as mulch on the soil surface in the cultivated area was effective in decreasing the evaporation rate. S3 was more efficient than S2 as it stored more water due to the higher infiltration rate (12.4 cm/hr) when compared to S2 (4.1 cm/hr).

The 23Mg(pγ)24Al and 26Al(pγ)27Si astrophysical reactions are expected to be of considerable importance in the nucleosynthesis of A≥20 nuclei in classical novae. Previous studies have indicated that both reactions are dominated by resonant capture to excited states, above the proton-emission thresholds, in the proton-rich nuclei 24Al and 27Si, respectively. Consequently, by determining the nuclear properties of such resonant states it is possible to estimate the 23Mg(pγ)24Al and 26Al(pγ)27Si stellar reaction rates. In this thesis work, excited states in 24Al and 27Si were populated via the 10B(16O, 2n) and 12C(16O, n) heavy-ion fusion-evaporation reactions, respectively. The beams of 16O ions were produced by the Argonne Tandem Linear Accelerator System and prompt electromagnetic radiation was detected using the GAMMASPHERE detector array, which, in the case of the 24Al experiment, was used in coincidence with recoil selection provided by the Argonne Fragment Mass Analyzer. The two γray spectroscopy studies performed in this work allowed level structure determinations below the respective proton-emission thresholds of 24Al and 27Si nuclei, with improved precision on previous work. In addition to this, these studies also allowed a determination of the nuclear properties of proton-unbound astrophysically important γ decaying states, which, in turn, were used to re-evaluate the 23Mg(pγ)24Al and 26Al(pγ)27Si stellar reaction rates. The improved precision of the level energies and unambiguous assignments of resonant states has reduced the relative uncertainties in both the 23Mg(pγ)24Al and 26Al(pγ)27Si stellar reaction rates, constraining the production of A≥20 nuclei in classical novae.

Addition of nanopacticles in a base solvent leads to suspensions with enhanced physiochemical properties, compared to base solvent. This new type of suspensions is called nanofluids, with applications ranging from biomedicine to automotives. As a consequence extensive research is being conducted in the field, in particular, on the evaporation of these fluids as it leads to well-defined and highly ordered coffee-rings. However, the exact physics governing this phenomenon remain elusive. The goal of this experimental investigation is to elucidate how various parameters affect the progression of nanofluid coffee-stain formation. Examination of the coffee-ring structuring, produced by the free evaporation of sessile droplets containing nanoparticles, revealed an unexpected, disordered region at the exterior edge of the ring. A self-assembly mechanism with two components, particle velocity and wedge constraints, was proposed to describe the deposition of particles at contact lines of evaporating drops. Environmental pressure was used as a method to control particle crystallinity in the coffee-rings. Essentially, evaporation rate and pressure were found to be inversely proportional. Macroscopically, lowering pressure led to a transition from “stick-slip” to constant pinning. Nanoscopically, lowering pressure promoted crystallinity. Findings supported the proposed, in this thesis, particle self-assembly mechanism. Particle aspect ratio and flexibility were subsequently examined. Pinning strength was found to be a function of particle aspect ratio and rigidity, leading to constant pinning. The proposed, in this thesis, particle self-assembly mechanism was found to be applicable to a variety of aspect ratios and flexibilities. Lastly, particulate crystals grew following different pathways depending on particle flexibility.

Large areas of mesotidal estuaries become subaerial during low tide. Here we study the effect of nutrient enrichment and several meteorological and hydrodynamic parameters on the erodability of mudflat substrates when they are emergent. We tested the impact of nutrient fertilization on tidal flat sediments over a two week period in September 2011 in Plum Island Sound, Massachusetts (USA). High resolution measurements from our experiment indicate that daily nutrient enrichment at 70 μM NO3‾ using our experimental approach does not change the critical shear stress of the muddy substrate, nor affect the concentration of chlorophyll a at the surface. Sediment erodability is instead directly related to the potential evaporation rate and to the duration of the subaerial period. Chlorophyll a concentration decreases when evaporation is high, possibly due to the downward migration of diatoms. Sediment concentrations in the water column during submergence strongly depend on bottom shear stresses triggered by tidal currents. Surprisingly, they are also related to the total evaporation that occurred in the previous emergence period. We conclude that subaerial desiccation at low tide decreases the erodability of mudflat sediments. This strengthening effect is not lost during the following submerged period, thus limiting the erosive effect of tidal currents. For the first time we show that not only subaqueous but also subaerial processes control the erodability of mudflats. Global warming and other climatic variations regulating long-term evaporation rates can therefore directly affect the stability of mudflats in mesotidal environments.