abstract: The origin of the solar system and formation of planets such as Earth are among the most fascinating, outstanding scientific problems. From theoretical models to natural observations, it is possible to infer a general way of how the solar system evolved from the gravitational collapse of the molecular cloud to accretion and differentiation of planetary-sized bodies. This dissertation attempts to place additional constraints on the source, distribution, and evolution of chemical variability in the early solar system, Mars, and Earth. A new method was developed for the measurement of titanium isotopes in calcium-aluminum-rich inclusions (CAIs) by laser ablation multi-collector inductively coupled plasma mass spectrometry. The isotopic compositions of 17 Allende CAIs define a narrow range with clearly resolved excesses in 46Ti and 50Ti and suggests that "normal" CAIs formed from a relatively uniform reservoir. Petrologic and isotopic analysis of a new FUN (Fractionated and Unknown Nuclear effects) CAI suggests that normal and FUN CAIs condensed in similar environments, but subsequently evolved under vastly different conditions. Volatiles may have influenced the formation and evolution of basaltic magmas on Mars. Light lithophile element (LLE) and fluorine (F) concentrations and isotopic compositions of pyroxene determined in situ in several Martian meteorites suggests that the primary magmatic signature of LLE and F zonation in Shergottite pyroxene has been disturbed by post-crystallization diffusive equilibration. Using relevant crystal-melt partition coefficients the F contents for Martian meteorite parental melts are ~910 and ~220 ppm. Estimates of the F content in the Shergottite and Nakhlite source regions are similar to that of mid-ocean ridge basalts (MORB) and ocean island basalts (OIB), respectively, here on Earth. Noble gas systematics of OIBs relative to MORBs, suggests OIBs preferentially sample a primordial reservoir located within Earth's mantle. Geodynamic calculations were performed to investigate the time-dependent rate of material entrained into plumes from these primordial reservoirs. These models predict melts rising to the surface will contain variable proportions of primordial material. The results demonstrate that although high 3He/4He ratios may mandate a mantle plume that samples a primordial reservoir, more MORB-like 3He/4He ratios in OIBs do not preclude a deep plume source. / Dissertation/Thesis / Doctoral Dissertation Geological Sciences 2014

A sustainable supply of fresh water for the human population is a global concern. Intriguingly, about 70% of the total fresh water consumed in the world annually is claimed by agriculture alone; this fraction is even higher in the Middle East and North Africa (MENA) region, where natural regeneration of groundwater is the slowest. Thus, there is a serious need for innovative materials and technologies to enhance the efficiency water usage in agriculture. To this end, plastic mulches have been employed across the developed world to minimize evaporative loss of water from top-soils. While plastic mulches are inexpensive, they do require specialized farm machinery for installation and long processing times. On one hand, plastic mulches have proven to increase crop yields, but on the other their non-biodegradability poses serious environmental concerns. In response, development of low-cost bio-/photo-degradable artificial mulches remains an area of intense research. In this thesis, we report on a novel superhydrophobic material exploiting inexpensive simple components to reduce the amount of water required for irrigation in agriculture by suppressing evaporative losses from the top-soil. Our material consists of ordinary beach sand coated with < 20 nm thick layer of paraffin wax. We synthesized and extensively characterized our material and applied them as mulches for tomato and barley plants at the KAUST greenhouse. We found that when a ~5 mm thick layer of superhydrophobic sand was placed onto the top-soil in pots, it dramatically suppressed evaporative losses and significantly enhanced the yields. Our preliminary field-scale experiments with tomatoes and barley crops at the Hada Al Sham site corroborate these results. Our approach might find applications in desert agriculture and other fields and alleviate water stress in the MENA region.