This work is concerned with determining empirical parameters in stress and fiber orientation models required to accurately simulate the fiber orientation in injection molded composites. An independent approach aims to obtain the material parameters using a sliding plate rheometer to measure the rheology of fiber suspensions at increased fiber lengths subjected to transient shear flow. Fiber orientation was measured in conjunction with shear stress to determine the relationship between stress and fiber orientation. Using a compression molding sample preparation procedure, the transient shear stress response was measured for glass and carbon fiber suspensions up to a number average fiber aspect ratio (length/diameter) of 100. Increases in concentration or fiber aspect ratio caused the magnitude of the stress response to increase by as much as an order of magnitude when compared to the suspending matrix. The degree of shear thinning at low shear rates also increased with increases in aspect ratio and concentration. The compression molding sample preparation procedure provided poor control of the initial fiber orientation which led to the investigation of samples subjected to flow reversal and samples generated through injection molding. The samples prepared through injection molding provided improved repeatability in the measured shear stress response and fiber orientation evolution during the startup of flow compared to compression molded samples and samples subjected to flow reversal. From repeatable stress and orientation evolution data, models for stress and fiber orientation were assessed independently. Current theories for stress were unable to reflect the overshoot in the measured stress response and could at best capture the steady state. The transient behavior of the fiber orientation models were found to be highly dependent on the initial fiber orientation. The repeatable orientation data obtained from the injection molding sample preparation procedure provided material parameters in the strain reduction factor and reduced strain closure models. The injection molded samples provided evolution data from different initial fiber orientations to provide further scrutiny or validation of the material parameters. Orientation model parameters that provided reasonable agreement to multiple sets of fiber evolution data in simple shear flow should allow for a better assessment of the orientation models in complex flow simulations. / Ph. D.

<p>The behavior of fibers suspended in a flow between two counter-rotating discs has been studied experimentally. This is inspired by the refining process in the papermaking process where cellulose fibers are ground between discs in order to change performance in the papermaking process and/or qualities of the final paper product.</p><p>To study the fiber behavior in a counter-rotating flow, an experimental set-up with two glass discs was built. A CCD-camera was used to capture images of the fibers in the flow. Image analysis based on the concept of steerable filters extracted the position and orientation of the fibers in the plane of the discs. Experiments were performed for gaps of 0.1-0.9 fiber lengths, and for equal absolute values of the angular velocities for the upper and lower disc. The aspect ratios of the fibers were 7, 14 and 28.</p><p>Depending on the angular velocity of the discs and the gap between them, the fibers were found to organize themselves in fiber trains. A fiber train is a set of fibers positioned one after another in the tangential direction with a close to constant fiber-to-fiber distance. In the fiber trains, each individual fiber is aligned in the radial direction (i.e. normal to the main direction of the train).</p><p>The experiments show that the number of fibers in a train increases as the gap between the discs decreases. Also, the distance between the fibers in a train decreases as the length of the train increases, and the results for short trains are in accordance with previous numerical results in two dimensions.Furthermore, the results of different aspect ratios imply that there are three-dimensional fiber end-effects that are important for the forming of fiber trains.</p>

This study experimentally evaluated wheat straw slurry pipelines. Tests were conducted to determine the particle properties of the biomass mixed in water over time. The saturated particle density of 1,060kg/m3 was reached after 24 hours, while the saturated moisture contents of 78.5% and 79.5% were later reached for particle sizes of 1/8 and 3/4" respectively. A pipeline loop was redesigned to operate with 1/8, 1/4", and 3/4" straw particle slurries at up to 30% wet basis concentrations. The modifications allowed measurements of pressure loss through a length of pipe. These measurements which show the influences of drag reducing fibre suspension. Straw particles added to water lowered the pressure loss, by suppressing turbulence at lower concentrations or higher velocities. Additional straw further improved the result, until the maximum concentration was reached. High concentrations create plugs, increasing the pressure loss. Longer straw particles can further reduce losses, but have lower maximum concentrations. / Engineering Management

No description available.

The behavior of fibers suspended in a flow between two counter-rotating discs has been studied experimentally. This is inspired by the refining process in the papermaking process where cellulose fibers are ground between discs in order to change performance in the papermaking process and/or qualities of the final paper product. To study the fiber behavior in a counter-rotating flow, an experimental set-up with two glass discs was built. A CCD-camera was used to capture images of the fibers in the flow. Image analysis based on the concept of steerable filters extracted the position and orientation of the fibers in the plane of the discs. Experiments were performed for gaps of 0.1-0.9 fiber lengths, and for equal absolute values of the angular velocities for the upper and lower disc. The aspect ratios of the fibers were 7, 14 and 28. Depending on the angular velocity of the discs and the gap between them, the fibers were found to organize themselves in fiber trains. A fiber train is a set of fibers positioned one after another in the tangential direction with a close to constant fiber-to-fiber distance. In the fiber trains, each individual fiber is aligned in the radial direction (i.e. normal to the main direction of the train). The experiments show that the number of fibers in a train increases as the gap between the discs decreases. Also, the distance between the fibers in a train decreases as the length of the train increases, and the results for short trains are in accordance with previous numerical results in two dimensions.Furthermore, the results of different aspect ratios imply that there are three-dimensional fiber end-effects that are important for the forming of fiber trains.

The aim of the present work is to experimentally study the dynamics of the formation of a fiber network formed from the filtration of a fiber suspension. This is relevant for all industrial applications (e.g. papermaking, productions of composite material, etc.) where a suspension of fibers has to flow through narrow gaps, and the quality of the product depends on the distribution of mass and orientation of the fibers. To study the dynamics of network formation, we developed an experimental setup where the filtration of a fiber suspension through a semi-permeable screen can be studied. In the setup, both the fluid and the solid phase can be visualized. The focus of the present thesis is to study the fluid flow generated during the filtration. Index of refraction matching, image processing and particle image velocimetry have been used to measure the velocity field in the proximity of the resulting fiber network. Experiments with varying fiber length and filtration velocity have been performed. The disturbances generated by the screen and the forming network was found to be confined in a region (boundary region), whose extension varies with time: first, after the formation of the first fiber layers, the extent of the boundary region increases; at later times, the boundary region is thinner. The extent appears to be correlated to the gap size either of the screen (at very early times) or of the fiber network, but independent of the filtration velocity. Fluctuations on a scale larger than a fiber length are also observed during the filtration process. These fluctuations are found to be correlated to the nondimensional number Se that relates the sedimentation velocity of a fiber to the filtration velocity. The governing non-dimensional parameters are derived from the equations. The parameters are used to relate the experimental observations to the dewatering process in papermaking. / QC 20101103

With this research, we work towards the overall objective of being able to accurately simulate fiber orientation in complex flow geometries of composite fluids of industrial significance. The focus of this work is to understand the rheological behavior of these materials and its connection to fiber orientation as determined in simple shear flow. The work includes the development of a novel approach to characterizing the transient rheology; an experimental study of the relationship between the stress growth functions in startup of flow and the fiber orientation; a critical assessment of the limitations of current fiber suspension theory; and an approach to determining unambiguous model parameters by fitting. A key difference between the rheological studies performed in this work and others is the use of a cone-and-plate device combined with "donut" shaped samples (CP-D) to prevent boundary effects on the measurement. The conventional method for obtaining transient rheological data is to use parallel disk (PP) geometry set at a gap where the measurements are independent of disk spacing. However, this work suggests that the inhomogeneous velocity gradient imposed by the PP geometry induces excessive fiber-fiber contact contributing to exaggerated measurements of the stress growth functions. An experimental study of the transient rheological behavior of a 30 wt% short glass fiber-filled polybutylene terephthalate was performed using the CP-D. Stress growth measurements during startup of flow were performed in combination with direct measurement of the fiber orientation to determine the relationship between the transient rheology and the fiber microstructure. The well defined fiber orientation and rheological experiments allowed for a quantitative assessment of current fiber suspension theory. Comparison between the experimental fiber orientation and predictions based on Jeffery's equation and the Folgar-Tucker model show that the fiber orientation evolves much slower than predicted. In addition, the addition of a "slip" term improved the agreement between the predictions and experimental results. Predictions using the Lipscomb model coupled with the Folgar-Tucker model, with slip, were fit to the transient stresses to determine the feasibility of fitting unambiguous model parameters for a specific composite fluid. Model parameters determined by fitting at a shear rate of 6 s-1 allowed for reasonable predictions of the transient stresses in flow reversal experiments at all the shear rates tested. / Ph. D.

Transient viscosity growth measurements at the startup of shear flow were performed on long glass fiber-filled polypropylene. Samples were prepared with fibers pre-oriented either in 1-direction, 3-direction or random in 1-3 plane, where the 1-direction is the direction of shear motion, the 2-direction is perpendicular to the shear plane and the 3-direction is the neutral direction. A sliding plate rheometer incorporating a shear stress transducer was constructed in the lab. It was shown that this device works well for the tested materials including a Newtonian oil, a low density polyethylene (LDPE) and short glass fiber-filled polypropylene. The transient viscosity growth behavior for long glass fiber suspensions was subsequently investigated. The results suggested that both, fiber length and fiber concentration have pronounced effect on the steady state suspension viscosity. It was also observed that the transient behavior of the pre-oriented samples was highly dependent on the initial orientation state of the fibers. / Master of Science

The knowledge of the behavior of non-spherical particles suspended in turbulent flows covers a wide range of applications in engineering and science. Dispersed two-phase flows and turbulence are the most challenging subjects in engineering, and when combined it gives rise to more complexities as the result of the inherent stochastic nature of the turbulence of the carrier-phase together with the random distribution of the dispersed phase. Moreover, for anisotropic particles the coupling between the translation and rotation of particle increases the complication. Because of the practical importance of prolate particleladen turbulent flows, the plenty of numerical and experimental works have been conducted to study such suspensions. Numerical approaches have given valuable insight of turbulent suspension flows, although the computation has been only carried out at the macro scale and models, not including flow distortion around the particle, comprise the detail of the flow in the order of a particle size. In addition, the model of the forces imposed on the particle by the fluid and mass point treatment are strictly valid for infinitely small particle having size less than all scales of the fluid turbulence. Fully resolved solution at the scale of the dispersed phase in turbulent flows for high Reynolds number has been recently performed but is still a challenge. On the other hand, the presence of particle as the dispersed phase makes experimental measurements much more complicated than those with single phase as a result of particles interference. The area of considerable difficulty with this type of experiments is the measurement of the fluid-phase velocity remarkably close to the particle surface. Generally, experimental researches have been concentrated on measuring the mean velocity and Reynolds stresses of the carrier-phase, and the mean velocity, fluctuations, orientation and accumulation of the non-spherical particles. Higher-order quantities, including Lagrangian particle velocity correlations, the carrier-phase turbulence modulation, and two-particle and particlefluid velocity correlations are also of interest. It has been found that the rotational and translational movements of the fibershaped particle depend on the nature of carrier-phase field and fiber characteristics such as aspect ratio, fiber Stokes number, fiber Reynolds number, and the ratio of fiber to flow length scale. With the development of PIV (Particle Image Velocimetry) and PTV (Particle Tracking Velocimetry) techniques, it has been appeared that combined PIV/PTV will be the best available choice for the experimental study of dispersed two-phase flows. The purpose of combined PIV/PTV measurement of two-phase systems is simultaneous measurements of fluid and suspended objects, where the PIV measurement of the fluid phase are combined with PTV measurement of the dispersed phase. The objective of this doctoral thesis is to study the behavior of rod-like particles suspended in wall-bounded turbulent flow through simultaneous PIV/PTV measurements of the velocity of the flow field and particle motion. As a representative of rod-like particles, I have employed cellulose acetate fibers with the length to diameter ratio (aspect ratio) larger than one. Here, It has been considered only dilute suspensions with no flocculation; thus fiber-fiber interaction is negligible. The measurements have been conducted within the parallel planes (2D view) illuminated by laser in the streamwise direction in thin film suspension flowing on the water table setup at Linné FLOW Centre, KTH Mechanics Lab. It is shown that this setup is a well-behaved experimental model of half channel flows often used in Direct Numerical Simulation (DNS) investigations. Therefore, the experimental results are comparable to their DNS counterpart where it is convenient. A single camera PIV technique has been used to measure flowing suspension. Therefore, it has been needed to preprocess images using a spatial median filter to separate images of two phases, tracer particles as representative of fluid and fibers suspended. The well-known PIV processing algorithms have been applied to the phase of fluid. I have also introduced a novel algorithm to recognize and match fibers in consecutive images to track fibers and estimate their velocity. It is not feasible to study all relevant aspects of particle-laden turbulent flows in a single study. In this study, I present the statistics of the rotational and translational motion of fiber-like particles and the surrounding fluid velocity. To the author’s knowledge, remarkably little experimental work has been published to date on simultaneous measurement of fiber motion and turbulence field in a turbulent fiber suspension flow to reveal dynamics of fibers in this regime. Therefore, the results of this work will be profitable in better understanding of such multiphase flows. The statistical analysis of the translational motion of fibers shows that the size of fiber is a significant factor for the dynamical behavior of the fiber near the wall. It has been observed that, in the region near the wall, the probability of presence of the long fibers is high in both the high-speed and low-speed streaks of flow, and the mean velocity of fibers almost conforms to the mean velocity of flow; whereas the short fibers are mostly present in the low-speed areas, and the fiber mean velocity obey the dominant flow velocity in these areas. In the far-wall regions, the translation of fibers is practically unaffected by the aspect ratio, whereas it depends crucially on the wall-normal distance. Moreover, it was found that in the case of long fibers near the wall, the low speed fibers mostly are orientated in streamwise direction. On the other hand, there is no preferential orientation for fast long fibers. Although wall-normal velocities were not measured in this study, it is hypothesized that this behavior is a result of fibers being affected by the sweep and ejection events known to occur in wall-bounded turbulent flow. The fast fibers are in sweep environment and comes from the upper layer. The low speed fibers are into ejection areas in the vicinity of the wall, and the wall has a stabilizing effect on them. The short fibers are still oriented mostly in streamwise direction for a certain range of low velocity. Furthermore, since a considerable change of the fiber behavior is observed in a certain ratio of the fiber length to the fiber distance from the solid wall, it is supposed that this ratio is also a prominent parameter for the behavior of fiber near the wall. The results presented are in terms of viscous wall units wherever are denoted by superscript “+”.

Cellulose nanofibrils (CNF) is a renewable material with unique strength properties. A difficulty in CNF production is that CNF suspensions contain large amounts of water. If CNF suspension volume can be decreased by dewatering facilitated by centrifugation, then transportation costs and storage costs can be reduced. The aim of this thesis is to investigate the impact various parameters have on CNF centrifugation dewatering and identify optimal conditions for maximal water removal. A laboratory study was conducted using four materials; 2.0 w% enzymatically treated CNF (CNF1), 1.9 w% carboxymethylated CNF (CNF2) and two commercial samples (1.9 w% CNFA and 1.8 w% CNFB). The main method was analytical centrifugation up to 2330 g. Parameters tested were initial concentration before centrifugation, temperature, NaCl addition, pH, and applied solid compressive pressure (g-force and surface weight). In addition to centrifugation experiments the four materials were characterized with laser diffraction, UV-vis absorption, Dynamic light scattering, and dry weight measurements. Analysis of the experimental data collected show that increase in initial concentration give a higher final concentration, but less water is removed. Furthermore, temperature changes have no effect on separation of CNF and water. At an applied solid compressive pressure of 3 kPa and initial concentration at 1.5 w% the concentrations 5.5 w%, 1.5 w%, 4.0 w%, and 4.3 w% can be reach for CNF1, CNF2, CNFA, and CNFB respectively. After extrapolation of polynomial functions fitted to experimental data an applied solid compressive pressure of 22 kPa and initial concentration at 1:5 w%, the concentrations 9.1 w%, 1.5 w%, 6.9 w%, and 7.9 w% are predicted for CNF1, CNF2, CNFA, and CNFB respectively. The thickening of CNF suspensions achieved and predicted in this thesis implies possibilities for large amounts of water removal, e.g. the water content in a CNF1 suspension is reduced from 65.7 litres/kg CNF to 10.0 litres/kg CNF at the solid compressive pressure 22 kPa. The concentrations at 22 kPa are determined by extrapolation from experimental data &lt;3 kPa solid compressive pressure. The carboxymethylated CNF2 can not be dewatered unless it is diluted or if salt or pH is adjusted. This is directly correlated to the electrostatic forces in the suspension and the Debye length. Addition of salt or lowered pH also eliminate any concentration gradients in diluted and centrifuged CNF2 suspensions. / Cellulosa nanofibriller (CNF) är ett förnybart material med unika styrkeegenskaper. En svårighet med produktion av CNF är att CNF suspensioner innehåller stora mängder vatten. Om volymerna av CNF suspensioner kan minskas med avvattning genom centrifugering, då kan transport- och lagerkostnader sänkas. Målet med det här examensarbetet är att undersöka vilken inverkan olika parametrar har på CNF-avvattning genom centrifugering och identifiera optimala förhållanden för maximalt avlägsnande av vatten. En laboratoriestudie utfördes på fyra olika material. De fyra materialen är 2 w% enzymatiskt behandlad CNF (CNF1), 1.9 w% karboxymetylerad CNF (CNF2) och två kommersiella prover (1.9 w% CNFA och 1.8 w% CNFB). Den huvudsakliga metoden var analytisk centrifugering upp till maximalt 2330 g. De testade parametrarna var initial koncentration innan centrifugering, temperatur, NaCl tillsats, pH, och applicerat fast kompressionstryck (g-kraft och ytvikt). Förutom centrifugeringsexperimenten så karaktäriserades the fyra mmaterialen med laser diffraktion, UV-vis absorption, dynamisk ljusspridning och vägningar av torrhalt. Analys av den experimentella data som insamlats visar att en ökad initial koncentration ger en högre slutkoncnentration, men mindre vatten kan bortföras. Temperaturförändringar har ingen effekt på separation av CNF och vatten. Vid ett applicerat fast kompressibelt tryck på 3 kPa och en initial koncentration 1.5 w% kan koncentrationerna 5.5 w%, 1.5 w%, 4.0 w%, och 4.3 w% nås för CNF1, CNF2, CNFA, och CNFB. Efter extrapolering av polynoma funktioner passad till experimentell data förutspås att koncentrationerna 9.1 w%, 1.5 w%, 6.9 w%, och 7.9 w% kan nås för CNF1, CNF2, CNFA, and CNFB vid 22 kPa och en initial koncentration på 1.5 w%. Förtjockningen av CNF suspensioner som kan, eller förutspås kunna nås genom centrifugering i det här examensarbetet innebär att det är möjligt att avlägsna stora mängder vatten, till exempel kan vatteninnehållet i CNF1 minskas från 65.7 liter/kg CNF till 10.0 liter/kg CNF vid 22 kPa fast kompressionstryck. Koncentrationerna vid 22 kPa fast kompressionstryck är extrapolerade från exprimentell data &lt;3 kPa fast kompressionstryck. Den karboy- metylerade CNF2 kan inte avvattnas om den inte späds ut eller om salt eller pH justeras. Detta är direkt kopplat till de elektrostatiska krafterna i suspensionen och Debye längden. Tillsats av salt eller sänkt pH eliminerar också de koncentrationsgradienter som kan förekomma i utspädda centrifugerade CNF2 suspensioner.