The main goal of this work is to introduce new carbon structures - carbon nanotubes. The main objective of this work is to take advantage of the unique characteristic of carbon nanotubes to emit electrons at very low supply voltage.

This work deals with the theoretical foundations of electron emission into vacuum, various types of emissions, focused on the cold-emission and Schottky emission and the principle of quantum tunneling. The next part deals with the technical implementation of electron sources with a detailed study of the methodology of laboratory production of cathodes by electrochemical etching and construction of electron microscopes, using field-emission sources. This work also contains methods for measuring, processing and evaluation of electrical characteristics of emission sources.

Dizertační práce se zabývá problematikou výpočtu vlivu coulombovských interakcí částic na parametry emitovaného elektronového svazku v blízkosti Schottkyho a studené katody. Práce poskytuje základní předhled o problematice, popisuje vytvořené modely emisních zdrojů a metodu simulace Monte Carlo. Představuje novou metodu generování vstupních dat, která klade větší důraz na přesnou simulaci emisního procesu. Pozornost je zde věnována zejména vlivu interakcí na energiovou šířku, velikost virtuálního zdroje a jas katody v závislosti na velikosti poloměru hrotu a emisním proudu. Sledováním vývoje energiové šířky bylo zjištěno, že naprostá většina interakcí se odehrává v prostoru do několika mikrometrů od hrotu katody. Závislost spočtené celkové energiové šířky na úhlové intenzitě je ve shodě s dostupnými experimentálními daty. Spočtené energiové rozšíření vlivem coulombovských interakcí bylo srovnáno s hodnotami vypočtenými pomocí vzorců založených na analytických přiblíženích. Bylo zjištěno, že některé z nich přijatelně předpovídají trendy ale nemohou být použity pro kvantitativní odhad.

Soy flour (SF), a by-product of the soybean oil extraction processing, was investigated for its application in soy-polypropylene composites for interior automotive applications. The emphasis of this work was the understanding of this new type of filler material and the contribution of its major constituents to its thermal stability and impact properties. For this reason, reference materials were selected to represent the protein (soy protein isolate (SPI)) and carbohydrate (soy hulls (SH)) constituents of the soy flour. Additional materials were also investigated: the residue obtained after the protein removal from the soy flour which was called insoluble soy (IS), and the remaining liquid solution after acid precipitation of the proteins, containing mostly sugars and minerals, which was called soluble sugar extract (SSE). Two treatments, potassium permanganate and autoclave, were analyzed for their potential to modify the properties of the soy composite materials. An acid treatment with sulfuric acid conducted on soy flour was also considered. The soy materials were studied by thermogravimetric analysis (TGA) under isothermal (in air) and dynamic (in nitrogen) conditions. SPI had the highest thermal stability and SSE the lowest thermal stability for the early stage of the heating process. Those two materials had the highest amount of residual mass at the end of the dynamic TGA in nitrogen. The two treatments showed minimal effect on the isothermal thermal stability of the soy materials at 200 ??C. A minor improvement was observed for the autoclave treated soy materials. Fourier transformed infrared (FTIR) spectroscopy indicated that the chemical surface composition differed according to type of the soy materials but no difference could be observed for the treatments within one type of soy material. Contact angle analysis and surface energy estimation indicated differences of the surface hydrophobicity of the soy materials according to type of material and treatment. The initial water contact angle ranged from 57 ?? for SF to 85 ?? for SH. The rate of water absorption increased dramatically after the autoclave treatment for IS and SPI. Both materials showed the highest increase in the polar surface energy fraction. In general, the major change of the surface energy was associated with change of the polar fraction. After KMnO4 treatment, the polar surface energy of SF, IS and SPI decreased while SH showed a slight increase after KMnO4 treatment. A relationship between protein content and polar surface energy was observed and seen to be more pronounced when high protein containing soy materials were treated with KMnO4 and autoclave. Based on the polar surface energy results, the most suitable soy materials for polypropylene compounding are SPI (KMnO4), SH, and IS (KMnO4) because their polar surface energy are the lowest which should make them more compatible with non-polar polymers such as polypropylene. The soy materials were compounded as 30 wt-% material loading with an injection moulding grade polypropylene blend for different combinations of soy material treatment and coupling agents. Notched Izod impact and flexural strength as well as flexural modulus estimates indicated that the mechanical properties of the autoclaved SF decreased when compared to untreated soy flour while the potassium permanganate treated SF improved in impact and flexural properties. Combinations of the two treatments and two selected (maleic anhydride grafted polypropylene) coupling agents showed improved impact and flexural properties for the autoclaved soy flour but decreased properties for the potassium permanganate treated soy flour. Scanning electron microscopy of the fractured section, obtained after impact testing of the composite material, revealed different crack propagation mechanisms for the treated SF. Autoclaved SF had a poor interface with large gaps between the material and the polypropylene matrix. After the addition of a maleic anhydride coupling agent to the autoclaved SF and polypropylene formulation, the SF was fully embedded in the polymer matrix. Potassium permanganate treated SF showed partial bonding between the material and the polymer matrix but some of the material showed poor bonding to the matrix. The acid treated SF showed cracks through the dispersed phase and completely broken components that did not bind to the polypropylene matrix. In conclusion, the two most promising soy materials in terms of impact and flexural properties improvement of soy polypropylene composites were potassium permanganate treated SF and the autoclaved SF combined with maleic anhydride coupling agent formulation.

Electric Propulsion (EP) is widely acknowledged as a crucial technology for future space missions, offering significant propellant savings and enabling exploration of planetary missions with smaller spacecraft (s/c). For precise attitude control of these smaller spacecraft, Field Emission Electric Propulsion (FEEP) has emerged as a favorable option due to its exceptional thrust controllability. However, the successful operation of FEEP, as well as most other EP systems, relies on an electron source, typically a Hollow Cathode (HC), to neutralize the ion beam. This cathode’s behavior must be characterized through ground testing before being integrated with the thruster. Once integrated, the whole thruster undergoes further testing. While the testing phase plays an essential role in achieving mission objectives, there is a scarcity of comprehensive papers describing the design of test setups for cathodes, such as Heaterless Hollow Cathode (HHC), or EP thrusters like FEEP. The lack of detailed information makes it challenging for those not well-versed in this particular testing methodology to effectively replicate the tests. In an effort to address this issue, this thesis utilizes literature studies and thermal analyses to propose a HHC test setup by focusing on the anode configuration and the electrical interface; Subsequently, parts of this HHC test setup are reused in a conceptual vacuum chamber adaptation, facilitating testing of FEEP. Specifically, for the HHC setup, two stainless steel plate-shaped anodes are manufactured, and an accompanying electrical schematic diagram is presented to demonstrate the proper connection of power supplies and other necessary equipment. For the FEEP setup, a chevron beam target, an aluminum shield to protect the pump, and a heat-dissipating stand are introduced. These two test setups, along with the underlying motivation, can ideally simplify future cathode and thruster testing processes, especially for those having limited familiarity with this subject matter. / Elektrisk framdrivning är allmänt erkänt som en avgörande teknologi för framtida rymduppdrag eftersom elektrisk framdrivning erbjuder betydande bränslebesparingar och möjliggör utforskning av planetära uppdrag med mindre rymdfarkoster. För exakt styrning av dessa mindre rymdfarkoster har fältjonisationsframdrivning framträtt som ett fördelaktigt alternativ på grund av sin exceptionellt styrbara drivkraft. Dock är den framgångsrika driften av fältjonisationsframdrivning, liksom de flesta andra elektriska framdrivningssystem, beroende av en elektronkälla, vanligtvis en hålkatod, för att neutralisera jonstrålen. Denna katods beteende måste karakteriseras genom marktester innan den integreras med drivsystemet. Efter integrationen genomgår hela drivsystemet ytterligare tester. Trots att testfasen spelar en avgörande roll för att uppnå uppdragsmålen finns det en brist på omfattande rapporter som beskriver utformningen av testupplägg för katoder, såsom värmelösa hålkatoder, eller elektriska framdrivningssystem så som fältjonisationsframdrivning. Den bristfälliga informationen gör det svårt för dem som inte är insatta i denna specifika testmetodik att effektivt replikera testerna. I ett försök att lösa detta problem använder denna avhandling litteraturstudier och termiska analyser för att föreslå en testuppsättning för en värmelös hålkatod genom att fokusera på anodkonfigurationen och det elektriska gränssnittet; Därefter återanvänds delar av denna värmelösa hålkatods-testuppsättning i en konceptuell vakuumkammar-anpassning för att underlätta testning av fältjonisationsframdrivning. Specifikt för den värmelösa hålkatods-uppsättningen tillverkas två platta anoder av rostfritt stål, och ett tillhörande schematiskt diagram över det elektriska gränssnittet presenteras för att demonstrera korrekt anslutning av strömförsörjning och annan nödvändig utrustning. För fältjonisationsframdrivnings-uppsättningen introduceras ett chevron-mönstrat jonstråle-mål, ett aluminiumskydd för pumpen och ett värmeavledande stativ. Dessa två testuppsättningar, tillsammans med den underliggande motiveringen, kan i bästa fall förenkla framtida testprocesser för katoder och drivsystem, särskilt för dem som har begränsad kännedom om ämnet.