Este trabalho tem por objetivo comparar os seguintes métodos de compressão de imagens de impressão digital: transformada discreta do cosseno (DCT), transformada de wavelets de Haar, transformada de wavelets de Daubechies e transformada de wavelets de quantização escalar (WSQ). O propósito da comparação é identificar o método que resulta numa menor perda de dados, para a maior taxa de compressão possível. São utilizadas as seguintes métricas para avaliação da qualidade da imagem para os métodos: erro quadrático médio (ERMS), a relação sinal e ruído (SNR) e a relação sinal ruído de pico (PSNR). Para as métricas utilizadas a DCT apresentou os melhores resultados, seguida pela WSQ. No entanto, o melhor tempo de compressão e a melhor qualidade das imagens recuperadas avaliadas pelo software GrFinger 4.2, foram obtidos com a técnica WSQ. / This research aims to compare the following fingerprint image compression methods: the discrete cosseno transform (DCT), Haar wavelet transform, Daubechies wavelets transform and wavelet scalar quantization (WSQ). The main interest is to find out the technique with the smallest distortion and higher compression ratio. Image quality is measured using peak signal-to-noise ratio (PSNR), signal-to-noise ratio (SNR) and root mean square (ERMS). Image quality using these metrics showed best results for the DCT followed by WSQ, although the WSQ had the best compression time and presented the best quality when evaluated by the GrFinger 4.2 software.

Este trabalho tem por objetivo comparar os seguintes métodos de compressão de imagens de impressão digital: transformada discreta do cosseno (DCT), transformada de wavelets de Haar, transformada de wavelets de Daubechies e transformada de wavelets de quantização escalar (WSQ). O propósito da comparação é identificar o método que resulta numa menor perda de dados, para a maior taxa de compressão possível. São utilizadas as seguintes métricas para avaliação da qualidade da imagem para os métodos: erro quadrático médio (ERMS), a relação sinal e ruído (SNR) e a relação sinal ruído de pico (PSNR). Para as métricas utilizadas a DCT apresentou os melhores resultados, seguida pela WSQ. No entanto, o melhor tempo de compressão e a melhor qualidade das imagens recuperadas avaliadas pelo software GrFinger 4.2, foram obtidos com a técnica WSQ. / This research aims to compare the following fingerprint image compression methods: the discrete cosseno transform (DCT), Haar wavelet transform, Daubechies wavelets transform and wavelet scalar quantization (WSQ). The main interest is to find out the technique with the smallest distortion and higher compression ratio. Image quality is measured using peak signal-to-noise ratio (PSNR), signal-to-noise ratio (SNR) and root mean square (ERMS). Image quality using these metrics showed best results for the DCT followed by WSQ, although the WSQ had the best compression time and presented the best quality when evaluated by the GrFinger 4.2 software.

Les moisissures sont des biocontaminants courants des environnements intérieurs causant la biodégradation des matériaux qu'ils colonisent et favorisant l'apparition de diverses pathologies, notamment respiratoires telles que des allergies, des infections ou des toxi-infections.En raison de ces impacts, la maîtrise de la contamination fongique constitue une préoccupation majeure pour des secteurs aussi divers que les industries agro-alimentaires, pharmaceutiques, les hôpitaux ou encore les établissements patrimoniaux. Actuellement, les techniques utilisées pour surveiller ces environnements sensibles reposent sur la mesure de particules biologiques en suspension dans l'air émises après sporulation des moisissures. Afin de prévenir les effets de la prolifération de moisissures, le Centre Scientifique et Technique du Bâtiment (CSTB) a développé un indice de contamination fongique basé sur la détection de Composés Organiques Volatils (COV) spécifiques émis dès le début de cette croissance microbienne avant même l'émission dans l'air de particules délétères (Moularat, Robine et al. 2008; Moularat, Robine et al. 2008). Cet outil, breveté en 2007 (Moularat 2007), a été employé lors de différentes campagnes de mesures dans l'habitat, les bureaux, les écoles, les crèches, les musées…(Moularat, Derbez et al. 2008; Joblin, Moularat et al. 2010; Moularat, Hulin et al. 2011; Hulin, Moularat et al. 2012). Depuis le CSTB a élaboré un prototype de balise de surveillance intégrant cet indice et constitué de capteurs gaz à base de Polymères Conducteurs Electroniques (PCE), en collaboration avec l'ESIEE Paris (l'Ecole d'Ingénieurs de la Chambre de Commerce et d'Industrie de Paris) (pour la balise) et le Laboratoire de Physico-chimie des Polymères et des Interfaces (LPPI) (pour les PCE). Ainsi des capteurs à base de polypyrrole (PPy) et de Poly-(3,4-éthylènedioxythiophène)-poly(styrènesulfonate) (PEDOT-PSS) ont permis de différencier un environnement contaminé d'un environnement sain. Si ces couches sensibles se sont montrées efficaces pour la détection par l'identification d'une empreinte globale de COV d'origine fongique, elles ne s'avèrent pas encore suffisamment sélectives pour réaliser l'identification de chaque COV, indispensable pour le calcul de l'indice.Dans le cadre de la surveillance de la qualité microbiologique de l'air des environnements intérieurs, cette thèse a pour ambition de prolonger ces travaux en étudiant les mécanismes d'interaction entre COV et PCE en vue de l'application au développement de micro-capteurs chimiques adaptés à la mesure in situ. Cette recherche implique à la fois l'optimisation de la sensibilité et de la sélectivité de ces polymères et le développement d'une matrice de capteurs.Le premier aspect de cette étude a consisté à synthétiser de nouveaux PCE, plus spécifiques sur la base de ceux identifiés comme pertinents lors de la thèse de Joblin en 2011. Ainsi, des polymères, à base de pyrrole fonctionnalisés en position 1 et 3, ont été synthétisés par voie électrochimique. Le PEDOT-PSS, polymère commercial (sous forme de suspension dans l'eau), a, quant-à-lui, été conditionné par différents traitements thermiques.Le second aspect a porté sur l'étude de l'influence de l'exposition des COV à ces PCE sur leurs propriétés physico-chimiques. Ainsi, des caractérisations morphologiques, électrochimiques, optiques ainsi que la variation des propriétés de surface ont permis de mettre en évidence des interactions faibles, en général de type van der Waals ou par liaison hydrogène, entre COV et PCE.Enfin, le dernier aspect a porté sur l'étude expérimentale de la réponse des capteurs en contact avec différents COV issus ou non du métabolisme fongique. Cette dernière étape a permis de vérifier les hypothèses de mécanismes d'interaction. Par ailleurs, la spécificité de la matrice de capteurs vis-à-vis des composés fongiques a été démontrée. Cette matrice de capteurs a également permis d'obtenir des signatures spéci / Conducting polymers can be used as active materials of sensing devices that find application in different areas, such as quality control of products in industries such as food and beverage, cosmetics and solvents, in the monitoring of air quality for environmental and safety purposes, and as an auxiliary tool in the diagnosis of diseases. In spite of this, as a general rule, the details of the prevailing interactions of the volatile compounds and the polymer are not well understood. For this reason, we have focused the work of this thesis on the characterization of the interactions between vapors of volatile organic compounds and thin films of conducting polymers. These films, that were the active components of the sensors, were prepared atop of different geometry of interdigitated electrodes via electropolymerization, where several preparation parameters (such as doping agents nature and concentrations, monomer nature, thermal annealing) were observed to assure an homogeneous growth of the polymeric film. Several characterizations such as electrochemical studies, AFM observations and UV-VIS-NIR spectra studies were used to obtain detailed information about the interaction mechanisms between VOC and conducting polymers. We have also measured the contact angle of water, formamide and diiodomethane deposited on the surface of the polymeric films to evaluate surface free energy (and its acid-base and dispersive components). The selectivity and sensitivity of the polymeric sensors when exposed to different volatile organic compounds (VOCs) have shown to be dependent not only of the properties of the analyzed VOC but also on the nature of the counter-ion used to dope the polypyrrole film. As a final conclusion, we can say that as a result of this work it becomes possible to optimize the design of an arrangement of sensors such that both a better sensitivity and a better selectivity sensitivity to a given chemical environment can be achieved.

L’objectif de l’étude est l’intégration de la méthode acoustique dans les analyses des étoffes. Par l’étude du phénomène du bruit généré par le frottement, nous avons pu concevoir et réaliser un instrument expérimental simulant le mouvement de l’avant-bras humain. Les méthodes utilisées pour l’obtention des paramètres du mouvement de l’avant-bras humain, sont des méthodes expérimentales basées sur la capture vidéo du mouvement et le traitement des séquences de ces vidéos enregistrées. Cet instrument nous a permis de tester plusieurs supports textiles destinés à l’habillement, pour extraire leur empreinte acoustique. La méthode de mesure par cet instrument consiste en l’obtention des spectres sonores obtenus par le frottement de deux échantillons de même support textile, qui seront ensuite traités et analysés pour avoir le niveau sonore et l’empreinte de la matière textile. Les résultats obtenus par cet instrument, selon des paramètres des essais fixés au préalable, montrent que le bruit généré par frottement textile /textile, devient plus intense, au fur et à mesure que la vitesse augmente (de la marche à la course) et l’intensité de ce bruit dépend aussi de la nature de la matière constituant le support textile. Ces résultats peuvent être révélateurs d’informations importantes sur les caractéristiques de tissu. Les essais de validation de cet instrument ont été faits en prenant uniquement des variations de vitesses de mouvement et de surface de frottement. Ainsi, cet instrument aide à créer un frottement similaire à la condition réelle du frottement de l’avant-bras. Dans cet esprit, on peut envisager d’utiliser cet instrument pour d’autres matériaux souples dans différentes conditions de vitesse, de surface et de pression de frottement et donc d’usage. / The objective of this study is to explore the possibilities to use acoustic method for fabric analysis. An experimental instrument was designed to study the noise generated by friction during body movement. It also allows simulating the motion of human forearm. Parameters of forearm movement were obtained by analyzing several recorded videos in sequences. Several clothing products have been tested by this instrument. The principle of this method is to obtain sound spectra created by friction between two same types of samples those have been further analyzed for the noise level and footprint of textile material. Different parameters of machine have been set before performing tests. Results depict for some fabrics that value of noise generated increases with the increase of movement speed (from walking to running). Intensity of noise mainly depends on nature of fabric’s raw material and can be influenced by speed and surface. These results indicate some very important information regarding fabric characteristics. The instrument has been validated and tested by changing two variables that are movement speed and surface friction maintaining pressure a constant. This instrument creates friction similar to real time friction produced during the movement of arm while walking or running. By using this concept, this instrument can be used for other flexible materials at different speeds, pressure and friction.

Women comprise over 57% of all U.S. mortuary school students, yet less than 20% of all funeral directors employed in this country are women. As such, women are underrepresented as funeral directors in the funeral industry. Research to date has not established clear differences between perceived gender roles and occupations in the funeral service industry. The research questions examined the perceived differences of gender role characteristics of masculine, feminine, and androgyny between the occupations of funeral service providers and nursing. Bem's gender role theory was the theoretical framework of this study. The research compared the mean scores of male and female funeral service professionals and nursing professionals as measured by the validated Bem Sex Role Inventory (BSRI). A sample consisted of 214 randomly selected male (n = 88) and female (n = 25) funeral service professionals and male (n = 37) and female (n = 64) nurse professionals. Data scores were analyzed using the factorial multivariate analysis of variance method. Results indicated nonsignificant gender role differences between male and female funeral directors. Funeral directors appear more androgynous compared to nurses. The present study contributed to the development of this important and neglected area of research by quantitatively examining the gender role perceptions of men and women in the funeral service industry for the first time. This study results highlighted the complexity in self-perceived gender role characteristics as measured by BSRI. When the funeral profession begins to dispel gender stereotypes and discrimination issues, positive social change can occur.

<p>This thesis states that cracks and scars, referred to as Secondary Creases, in fingerprint images can be used as means for aiding and complementing fingerprint recognition, especially in cases where there is not enough clear data to use traditional methods such as minutiae based or correlation techniques. A Gabor filter bank is used to extract areas with linear patterns, where after the Hough Transform is used to identify secondary creases in a r, theta space. The methods proposed for Secondary Crease extraction works well, and provides information about what areas in an image contains usable linear pattern. Methods for comparison is however not as robust, and generates False Rejection Rate at 30% and False Acceptance Rate at 20% on the proposed dataset that consists of bad quality fingerprints. In short, our methods still makes it possible to make use of fingerprint images earlier considered unusable in fingerprint recognition systems.</p>

<p>Verification of users’ identities are normally carried out via PIN-codes or ID- cards. Biometric identification, identification of unique body features, offers an alternative solution to these methods. </p><p>Fingerprint scanning is the most common biometric identification method used today. It uses a simple and quick method of identification and has therefore been favored instead of other biometric identification methods such as retina scan or signature verification. </p><p>In this report biometric security systems have been evaluated based on fingerprint scanners. The evaluation method focuses on copies of real fingers, artificial fingers, as intrusion method but it also mentions currently used algorithms for identification and strengths and weaknesses in hardware solutions used. </p><p>The artificial fingers used in the evaluation were made of gelatin, as it resembles the surface of human skin in ways of moisture, electric resistance and texture. Artificial fingers were based on ten subjects whose real fingers and artificial counterpart were tested on three different fingerprint scanners. All scanners tested accepted artificial fingers as substitutes for real fingers. Results varied between users and scanners but the artificial fingers were accepted between about one forth and half of the times. </p><p>Techniques used in image enhancement, minutiae analysis and pattern matching are analyzed. Normalization, binarization, quality markup and low pass filtering are described within image enhancement. In minutiae analysis connectivity numbers, point identification and skeletonization (thinning algorithms) are analyzed. Within pattern matching, direction field analysis and principal component analysis are described. Finally combinations of both minutiae analysis and pattern matching, hybrid models, are mentioned. </p><p>Based on experiments made and analysis of used techniques a recommendation for future use and development of fingerprint scanners is made.</p>

Women comprise over 57% of all U.S. mortuary school students, yet less than 20% of all funeral directors employed in this country are women. As such, women are underrepresented as funeral directors in the funeral industry. Research to date has not established clear differences between perceived gender roles and occupations in the funeral service industry. The research questions examined the perceived differences of gender role characteristics of masculine, feminine, and androgyny between the occupations of funeral service providers and nursing. Bem's gender role theory was the theoretical framework of this study. The research compared the mean scores of male and female funeral service professionals and nursing professionals as measured by the validated Bem Sex Role Inventory (BSRI). A sample consisted of 214 randomly selected male (n = 88) and female (n = 25) funeral service professionals and male (n = 37) and female (n = 64) nurse professionals. Data scores were analyzed using the factorial multivariate analysis of variance method. Results indicated nonsignificant gender role differences between male and female funeral directors. Funeral directors appear more androgynous compared to nurses. The present study contributed to the development of this important and neglected area of research by quantitatively examining the gender role perceptions of men and women in the funeral service industry for the first time. This study results highlighted the complexity in self-perceived gender role characteristics as measured by BSRI. When the funeral profession begins to dispel gender stereotypes and discrimination issues, positive social change can occur.

Biomass is increasingly used as a feedstock in global energy production. This may present operational challenges in energy conversion processes which are related to the inorganic content of these biomasses. As a larger variety of biomass is used the need for a basic understanding of ash transformation reactions becomes increasingly important. This is not only to reduce operational problems but also to facilitate the use of ash as a nutrient source for new biomass production. Ash transformation reactions were examined in the present work using the Lewis acid-base concept. The model presented in Paper I was further extended and discussed, including the definition of tertiary ash transformation reactions as reaction steps where negatively charged molecular ions, Lewis bases, other than hydroxides are present in the reactants. The effect of such reactions for bonding of various metal ions, Lewis acids, were discussed. It was found that the formation of various phosphates through secondary and tertiary ash transformation reactions is important for the behaviour of biomass ash in combustion. The suggested model was supported by findings in Papers II-VIII. The experimental findings in Papers II-VIII were discussed in terms of ash transformation reactions. The fuel design choices made to investigate the effect of phosphorus in particular on ash transformation reactions were high-lighted. Addition of phosphoric acid to woody-type and agricultural biomasses showed that phosphate formation has a large influence on the speciation of Si, S, and Cl. Co-combustion of a problematic agricultural residue with other biomasses showed that the relation between phosphorus, alkali and alkaline earth metal content is important. Co-combustion of biosolids with wheat straw was shown to greatly improve the combustion properties of wheat straw. It was suggested that fuel analyses should be presented using molar concentration (mole/kg) in diagrams based on ash transformation reactions and elements forming Lewis acids or bases. This may facilitate the assessment of the combustion behaviour of a fuel. Some comments were made on fuel design and additives, specifically pointing out that phosphorus content should always be carefully considered in relation to alkali and alkaline earth metals in fuels and fuel blends.

L’érosion hydrique est un processus majeur de dégradation des sols dans le monde avec des conséquences multiples : perte de terres agricoles, envasement des cours d’eau, coulées boueuses. En France, la région Hauts-de-France est la zone la plus touchée par ces pertes en terres qui peuvent dépasser les 10 t ha-1 an-1. Si les processus à l’origine de ces transferts sédimentaires ont été largement étudiés par la communauté scientifique ces dernières années, il reste néanmoins des verrous liés aux variabilités spatio-temporelles. De plus, l’efficacité des politiques récentes de lutte contre l’érosion n’est pas quantifiée. Cette étude propose une analyse de la variabilité spatio-temporelle des transferts sédimentaires selon plusieurs échelles (1-1000 km²), et une première évaluation de l’efficacité des politiques d’aménagement au sein d’un bassin du Nord de la France (la Canche ; 1274 km²). Une station de mesure haute-fréquence, a été implémentée à l’exutoire d’un sous-bassin versant de la Canche (la Pommeroye ; 0,54 km²) pour quantifier les transferts hydro-sédimentaires sur deux années hydrologiques contrastées. Selon nos résultats, les transferts varient de 29,4 à 70 t km-2 an-1. 40% du flux est exporté au cours de 3 épisodes érosifs majeurs (sur 48 enregistrés) et les paramètres forçants sont liés à la durée d’un épisode pluvieux et la quantité de précipitations. Sur ce même bassin, la prédiction spatiale à l’échelle centimétrique des transferts hydro-sédimentaires a pu être effectuée via le nouveau modèle d’érosion des sols WATERSED (BRGM) et l’efficacité d’un plan d’aménagement de lutte contre l’érosion a été quantifiée. Nos résultats permettent de valider l’opérabilité du modèle sur ce territoire. Les transferts sédimentaires à l’échelle du parcellaire agricole peuvent atteindre les 76 t km-2 pour un évènement donné et sont influencés par l’état de surface du parcellaire agricole. Une réduction significative (jusqu’à 84%) des transferts par les aménagements d’hydraulique douce est également observée. A l’échelle du bassin de la Canche, l’utilisation de traceurs chimiques et spectrocolorimétriques dans un modèle de mélange (Sed_Sat ; USGS) a permis d’évaluer d’une part les contributions des affluents de la Canche et d’autre part les contributions des sols et des berges (respectivement 30-70%). Des variations spatio-temporelles significatives ont pu être observées et les résultats tendent à montrer un potentiel impact positif des politiques récentes d’aménagement du territoire. Cette étude montre également que de nouveaux traceurs liés à la signature spécifique des particules magnétiques sont particulièrement prometteurs dans ce contexte pour tracer un signal d’érosion des sols. A terme, ces données pourraient être incluses dans des approches sediment fingerprinting. L’analyse selon plusieurs modalités spatio-temporelles et le couplage expérimentation/modélisation améliore donc notre compréhension de la dynamique des transferts sédimentaires sur le bassin versant de la Canche. Cela fournit des résultats essentiels pour orienter les futures politiques de lutte contre l’érosion des sols. / Water erosion is a serious concern in global land degradation leading to multiple consequences: loss of arable lands, siltation of streams, mudflows. In France, the Hauts-de-France region is the most affected area, and soil loss can exceed 10 t ha-1 yr-1. Although hydro-sedimentary processes have been widely studied by the scientific community, there is still a lack of knowledge in the understanding of the spatio-temporal variabilities. Additionally, the effectiveness of recent erosion control policies so far cannot be quantified. This study proposes an analysis of the spatio-temporal variability of sedimentary transfer at different scaling (1-1000 km²), and an initial assessment of the effectiveness of management policies within a northern France catchment (the Canche river, 1274 km²). A high-frequency monitoring station was implemented at the outlet of a Canche sub-catchment (the Pommeroye, 0.54 km²) to quantify the hydro-sedimentary transfer over two contrasted hydrologic years. According to our results, sediment yield varies from 29.4 to 70 t km-2 yr-1. 40% of the flux is exported during 3 major erosive events (out of 48 recorded) and the forcing parameters are related to the duration and the amount of rainfall. In this sub-catchment, the centimeter-scale spatial prediction of the hydro-sedimentary transfer was carried out using the new soil erosion model WATERSED (BRGM) and the effectiveness of an anti-erosion management plan was quantified. Our results validate the operability of the model in this context. For a given event, sediment transfer can reach 76 t km-2 yr-1 in agricultural plots and are strongly depending on the soil surface state. A significant reduction (up to 84%) of sedimentary transfer by the anti-erosion plan was also observed. At the scale of the Canche catchment, the use of chemical and spectrocolorimetric tracers in a mixing model (Sed_Sat tool; USGS) evaluated the contributions of the Canche tributaries and sediment sources contributions (i.e. channel banks and soils; 30-70% respectively). Significant spatio-temporal variations have been observed and the results show a potential positive impact of the recent management policies. This study also shows that new tracers related to the specific signature of magnetic particles are promising in the context to trace soil erosion. For further analyses, this data could be included in sediment fingerprinting approaches. Thus, this study based on several spatio-temporal modalities and the coupling of experimentation and modelling improves our understanding of the Canche hydro-sedimentary dynamics. It provides essential results to guide the future erosion control policies.