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The thermodynamic and structural effects of highly anisotropic, short-ranged attraction are investigated for single- and four-site interaction models using Wertheim's multi-density graph theory of chemical association. Both models consist of associating hard spheres, where the saturable attraction sites are described by conical wells centered in the hard core and evaluated in the "sticky-spot" limit. The resulting fluids then mimic many of the directional and steric-constrained properties of hydrogen-bonded fluids. The single-site model is used to explore the effects of dimerization upon the well-known properties of a planar liquid-vapor interface. Apart from hard sphere repulsion and sticky-spot attraction, a van der Waals-like dispersion interaction is incorporated to generate the critical point. Association is treated within Wertheim's thermodynamic perturbation theory, along with classical density functional methods to determine the interfacial density profile. The direct correlation functions which carry all bonding information are derived by means of the associative Ornstein-Zernike equations with a Percus-Yevick-like closure relation. The primary effects of dimerization are manifest in system thermodynamics. Critical temperatures and densities are shifted from their non-associating values and small, non-monotonic shifts in the correlation length and surface tension are also observed. While these effects are accompanied by interface compositional changes, any influence upon the density profile seems to be subsumed by use of the proper T/T[subscript c]. The four-site, network-forming model is investigated as a prototype for the thermodynamics and structural properties of water. Bonding interactions occur between "hydrogen" and electron "lone pair" sites described in the sticky-spot limit. System properties are derived under the ideal network approximation using the same methods as for the one-site model and are found to qualitatively reproduce some thermodynamic and connectivity features characteristic of real water. Partial densities are calculated self-consistently within the theory, and most thermodynamic quantities can be written in terms of the average number of hydrogen bonds per molecule. An analytical structure factor is also derived for this model. / Graduation date: 2003

Graduation date: 1999

Graduation date: 1994

Thesis (M. Phil.)--University of Hong Kong, 2006. / Title proper from title frame. Also available in printed format.

Thesis (M.S.)--West Virginia University, 2007. / Title from document title page. Document formatted into pages; contains viii, 58 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 51-52).

Single-dielectric-barrier-discharge (SDBD) plasma actuators have shown much promise as an actuator for active flow control. Proper design and optimization of plasma actuators requires a model capable of accurately predicting the induced flow for a range of geometrical and excitation parameters. A number of models have been proposed in the literature, but have primarily been developed in isolation on independent geometries, frequencies and voltages. This study presents a comparison of four popular plasma actuator models over a range of actuation parameters for three different actuator geometries typical of actuators used in the literature. The results show that the hybrid model of Lemire & Vo (2011) is the only model capable of predicting the appropriate trends of the induced velocity for different geometries. Additionally, several modifications of this model have been integrated into a new proposed model for the plasma actuator, introducing a number of improvements.

Single-dielectric-barrier-discharge (SDBD) plasma actuators have shown much promise as an actuator for active flow control. Proper design and optimization of plasma actuators requires a model capable of accurately predicting the induced flow for a range of geometrical and excitation parameters. A number of models have been proposed in the literature, but have primarily been developed in isolation on independent geometries, frequencies and voltages. This study presents a comparison of four popular plasma actuator models over a range of actuation parameters for three different actuator geometries typical of actuators used in the literature. The results show that the hybrid model of Lemire & Vo (2011) is the only model capable of predicting the appropriate trends of the induced velocity for different geometries. Additionally, several modifications of this model have been integrated into a new proposed model for the plasma actuator, introducing a number of improvements.

In this thesis work the feasibility of using open source OpenFOAM software as a solver part for Computation Fluid Dynamics in Volvo Technology is studied. Since the structure of the case in OpenFOAM is rather complex, one of the main purposes of this thesis work was also to make the process of using OpenFOAM as user-friendly as possible. The general conclusion that can be drawn from this work is that a very streamlined workflow can be, and has been, designed and created.

Thesis (Ph. D.)--University of Missouri-Columbia, 2000. / Typescript. Vita. Includes bibliographical references. Also available on the Internet.