No description available.

Fluidized bed is a suitable technology for combustion and gasification of biomass materials. Hydrodynamics occurring in the bed is crucial for the design and operation of the combustion or gasification unit. In the present study, hydrodynamic behavior of binary mixtures of biomass-silica sand in a bubbling fluidized bed was experimentally investigated. Five different biomass materials and silica sand with three different particle sizes were employed to form binary mixtures. Biomass materials were rice husk, sawdust, wheat straw, hazelnut shell and olive cake which are all potential energy sources for Turkey. Effects of mass percentage of biomass and particle size of silica sand on minimum fluidization velocity of the mixtures were determined. Comparisons between results of the present study and predictions of available correlations proposed for minimum fluidization velocity of binary mixtures were carried out. Mixing and segregation characteristics of biomass-silica sand binary mixtures were investigated for mixtures having different mass fraction of biomass and different silica sand particle sizes. Fluidization and bubbling behaviors of mentioned mixtures were observed in a 2-D fluidized bed and images taken during steady-state operation of bed were presented as visual tools to guide fluidization characteristics of the bed. Mass percentage increase of rice husk, wheat straw and sawdust resulted in increase in minimum fluidization velocity of the mixture whereas change in mass fraction of olive cake and hazelnut shell had no effect on minimum fluidization velocity. Minimum fluidization velocity increased with increase of silica sand particle size for all biomass-silica sand mixtures having same mass percentage of biomass. Vertical mixing pattern in the bed at steady state conditions were found almost same for all biomass-silica sand mixtures. Biomass acted as flotsam and accumulated mostly at the top of the bed and silica sand acted as jetsam and accumulated mostly at the bottom of the bed. 2-D bed experiments showed that mixing biomass materials with silica sand provides desired bubbling behavior in the bed.

In gas-solid fluidized beds, the generation of electrostatic charges due to continuous contacts between fluidizing particles, and the particles and the fluidization vessel wall, is unavoidable. Industrial operations, such as the production of polyethylene, are susceptible to significant operational challenges caused by electrostatics including reactor wall fouling, a problem known as “sheeting”. The formation of particle sheets can require shutdown periods for clean-up which results in significant economic losses. To gain a better understanding of the underlying mechanisms of electrostatic charging in gas-solid fluidized beds, in an attempt to eliminate or minimize this problem, a pilot-scale pressurized gas-solid fluidization system was designed and built, housing an online electrostatic charge measurement technique consisting of two Faraday cups. The system permits the study of the degree of particle wall fouling at pressures and temperatures up to 2600 kPa and 100°C, respectively, and gas velocities up to 1 m/s (covering a range including turbulent flow regime). The system also allowed, for the first time, the measurement of the fluidizing particles’ mass, net charge and size distribution in various regions of the bed, especially those related to the wall coating under the industrially relevant operating conditions of high pressures and gas velocities. Experimental trials were carried out using polyethylene resin received from commercial reactors to investigate the influence of pressure and gas velocity on the bed hydrodynamics and in turn, the degree of bed electrification. Mechanisms for particle charging, migration and adherence to the column wall were proposed. The size distribution of the gas bubbles shifted towards smaller bubbles as the operating pressure was raised. Thus, higher pressures lead to greater mixing within the bulk of the bed and resulted in a higher degree of particle wall fouling. Moreover, the extent of wall fouling increased linearly with the increase in gas velocity and as the bed transitioned to turbulent regime, due to the increase in particle-wall contacts. Bipolar charging was observed especially within the wall coating with smaller particles being negatively charged. Overall, particle-wall contacts generated negatively charged particles resulting in a net negative charge in the bed, whereas particle-particle contacts generated positively and negatively charged particles resulting in no net charge when entrainment was negligible. The formation of the wall layer and its extent was influenced by the gravitational and drag forces balancing the image force and Coulomb forces (created by the net charge of the bed and the metallic column wall as the attraction between oppositely charged particles).