The water crisis has been an increasing challenge in some places in the world. One proposed solution that has drawn lots of attention is fog harvesting. A commonly used fog collector is a vertical mesh, usually made of poly materials. Small water droplets can easily get pinned and quick evaporation is the major common challenge for vertical meshes. Coating the fog mesh with superhydrophobic chemicals is one of the solutions. However, superhydrophobicity is not durable and it may contaminate the collected water. In addition, it requires a high professional maintenance and laboratory operation standard. As a result, it is impractical to set such fog collectors in regions and countries with water crisis. Low cost, harmless, easily fabricated, higher coalesce rate and low maintenance are the five pillars for this research. This thesis topic is inspired by spider silk's ability to direct water droplets to certain locations to further enhance water collecting rate. This directional droplet movement is caused by spindle-knot and joint structure on the biomimetic silk. The spindle-knot is randomly porous, and the joint is stretched porous. In addition, the spindle-knot has a tilted angle β above the joint region. Due to these unique structures, there are three droplet movement controlling forces – surface tension force, hysteresis force, and Laplace pressure force. This thesis presents detailed equation derivations for each driving force in the introduction section. Spindle-knot is the pivot point to direct water, forming the spindle-knot structure is another focus of this thesis. Fluid coating and dip-coating with dimethylformamide (DMF), a solvent with a low evaporation rate, is the highly used methods to form the spindle-knot structures due to its simple setup and low cost. However, DMF is an extremely hazardous organic compound, and it requires high laboratory operation standards. In the second section of this thesis, DMF has been replaced with water/ethanol and photocurable materials to construct the spindle-knots. Furthermore, Additive manufacturing (3D printing method) was adopted to synthesize bionic spider web with spindle-knot structures. / Master of Science / Water shortage is one of the highest concerns all around the world and collecting fog water has drawn lots of attention recently. The focus of this thesis is to increase the fog collection rate by using less hazardous, low maintenance and low-cost methods. Commonly used fog collector is a large vertical plastic mesh. However, those large meshes suffer from water pinning and easily evaporation issues. Water repellent chemicals have been studied and used to dissolve those issues, however, the chemical coating will not last long and it will contaminate the collected water easily. Moreover, coating the water repellent chemicals requires professional operation and maintenance. To solve this issue without using chemical coating, we have learned unique water collection and directional behavior from spider silk. In a humid day, you will easily find the spider web with fully covered water droplets in an organized order. If we zoom in on single spider silk, the spider silk is composed of many puff and joint regions. Those puff regions have higher water collection ability than the joint regions, and this puff region shrinks down to form the spindle-knot shape with angle β above the joint region. This unique spindle-knot structure induces the water directional movement, and three forces- surface tension force, pinning force, and Laplace pressure force – are controlling the moving direction. Chapter 1 shows equation derivations with surface material effects, surface roughness effects and water droplet landing location effects. To form such special spindle-knot structure, commonly used formation methods are fluid coating and dip coating by using an organic polymer solvent. However, commonly used organic polymer-solvent suffer from a high level of hazardous, resulting in high laboratory requirement and operation cost. In Chapter 2 of this thesis, that commonly used organic polymer-solvent will be replaced by water/ethanol mixture and light-sensitive materials to form the spindle-knots. Furthermore, the 3D printing method is adopted to build a spider web with spindle-knot structures.

At the opposite of numerous countries in the world, despite its natural assets and its enormous surface and underground water potential, Cameroon is still trying to put down effective policies for the supply of safe drinking water for its rural population. Many initiatives to supply these communities through a national water distribution network have remained for the most dead letters or fruitless. A very high number of people still endanger their life daily by relying on archaic water supply techniques – when they are working – and by consuming unsafe water. This study therefore investigates if fog and rainwater harvesting could help in securing safe drinking water to these same rural communities, leaving the remaining demand - if any - to be provided by the existing but too often non-reliable supply system. Two pilot sites have been selected for their different climatic conditions; a village in the mountainous Western Province and another in the low-lying area of the Far-North Province of Cameroon. Average climatic data and basic topographical information from each location were used to determine the size and number of required collectors. The potential monthly water-yield at each site was then assessed using an actual climatic data series (8 years) and the theoretical performance simulated based on an increasing per capita daily consumption (10 – 40 l.d-1). An estimate of implementation cost is provided as part of the discussion on the feasibility of using both fog and rainwater harvesting as low-cost approaches to securing safe drinking water in Cameroon.

In this work, we were motivated to develop novel devices for water harvesting inspired by natural trees, and to understand their collection efficiency and working principles. We accomplished that with scale-model and large-scale fog harps, floating leaves, and synthetic trees. Fluids mechanics, physics, and thermodynamics were applied to solve the problems and rationalize the results. Redwood-inspired fog harps were designed with stainless steel vertical wires, using 3D-printing and laser-cutting techniques. Fog harps always harvested more water than any of the meshes, tested both under heavy fog and light fog conditions. The aerodynamic efficiency, deposition efficiency, and sliding efficiency were calculated to compare the fog harvesting performance. These findings provide insight into the new design of fog harvesters with high-efficiency fog harvesting performance, and future development of large fog harps, applied into regions even with light fog conditions, as an economically viable means. synthetic trees were fabricated with a nanoporous ceramic disk and silicone tubes. This tree system was tested in an environmental chamber (6 cm short trees) or a plant growth chamber (3m tall trees), both with controlled ambient humidities. The system pressure was calculated with Darcy's equation, Poiseuille equation and Laplace equation. The stable transpiration can happen to any scalable tree, which pumps water up an array of large tubes. Our synthetic trees, like natural trees, have the ability to lift water across a wide range of water temperatures and ambient humidities. They can be used as the large-scale evaporation-driven hydraulic pump, for example, pumped storage hydropower, filtration, underground water extraction. / Doctor of Philosophy / The purpose of this work is to investigate and characterize novel techniques for water harvesting that are inspired by natural trees. We are interested in two modes of water harvesting in particular: fog harps and synthetic trees. Fog harps were comprised of only vertical wires, inspired by the parallel structures of redwoods, which can capture and shed off fog droplets efficiently. Fog harps harvested more water than the traditional mesh nets, both under heavy fog and light fog conditions. Redwood-inspired fog harps have the high-efficient fog harvesting performance. They can be set up at coastal deserts to collect water from fog, where there is scarce rainfall but plenty of fog, like Chile, Peru and South Africa. Synthetic trees were designed with nanoporous disk (leaf) and tubes (xylem conduits), inspired by the transpiration process in natural trees. This transpiration-powered pump can lift water against the gravity at large scales, driven by the water evaporating from the nanopores. They can be used as the large-scale evaporation-driven hydraulic pump, for example, pumped storage hydropower, filtration, underground water extraction.

Fog harvesting is emerging as a promising means to ease the water shortage crisis in arid regions of the world with ample fog. The current state-of-the-art for fog harvesting is mesh netting, which is accessible yet struggles from a dual constraint: a course mesh lets most microscopic fog droplets pass through it, while a fine mesh clogs. In recent years, fog harps have been gaining attention as a superior alternative to meshes, bypassing these inherent constraints. In this work, we expand upon previous fog harp research with a focus on optimization. First, we analyze wire tangling in a harp due to capillary forces, resulting in a mathematical model that is able to predict when wire tangling will occur. Second, we systematically vary three key parameters of a fog harp (wire material, center-to-center wire pitch, and wire length), arriving at an optimal combination. Finally, we develop a numerical model to describe the dynamics of a fog droplet sliding down a harp wire while coalescing with others littered along it. By applying all knowledge acquired through these studies, the next generation of fog harps will push the performance ceiling of practical fog harvesters higher than ever. / Master of Science / The human population continues to grow, and with it the demand for fresh water. This need has caused many to turn to unconventional sources of water, including fog (the suspension of microscopic liquid water droplets in the air). Fog harvesters already exist in arid regions of the world as mesh nets, but suffer dual constraints from their grid-like structure: course meshes fail to capture most fog droplets passing through, while fine meshes get clogged. To bypass these inherent limits, we turn to nature for a solution. It has been observed that California redwood trees are able to effectively collect fog on their straight leaf needles, dripping droplets to the roots below. Inspired by this, we fabricate a device called a fog harp, which removes the impeding horizontal wires of meshes to effectively capture and slide droplets down its vertical wires. In this work, we expand upon previous fog harp research by investigating ways to optimize its water collection efficiency. First, we develop a mathematical model to describe the tangling of harp wires due to merging droplets on adjacent wires pulling them together. Second, we systematically vary three key parameters of the fog harp (wire material, center-to-center wire spacing, and wire length) to arrive at the optimal combination. Finally, we develop a model to describe the dynamics of droplets sliding down harp wires while merging with others littered along it. These studies will raise the performance ceiling of fog harps and push them to real-world applications.

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