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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Collision Broadening of Microwave Spectral Lines of Monomeric Formaldehyde and Formic Acid

Venkatachar, Arun C. 08 1900 (has links)
Line width parameters for a number of spectral lines in the pure rotational spectrum of formaldehyde (CH20) and formic acid (HCOOH) have been measured using a sourcemodulated microwave spectrograph. All transitions studied in this investigation were of the type ΔJ=O (i.e. Q-branch transitions), with ΔK-1=0 and ΔK+1 =+l. The center frequencies of the measured lines varied from 8662.0 MHz to 48612.70 MHz. The experimentally determined collision diameters for self broadening interactions involving HCOOH and CH2 Q molecules were found to be 2 - 27 per cent less than those calculated by the Murphy-Boggs theory of collision broadening. Much better agreement between a simplified broadening scheme for symmetric top molecules and the observed foreign-gas collision diameters is obtained by using Birnbaum's theory.

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