In recent decades, significant requirements of changes in composition of brake friction materials in order for faster and more reliable transportation as well as their environmental friendly characterizations attracted attentions. However, the relation between performance and formulation/composition is not clear since friction processes are accompanied by many complex problems such as instability in the coefficient of friction, noise, vibration and wear. Creep-groan is a low frequency vibration which could originate in different part of the system (vehicle). The resulting resonant vibration in the passenger compartment causes discomfort and often leads to complaints of customers and related increase of warranty costs covered by manufacturers. In spite of relatively large amount of publications addressing the creep-groan phenomena, there is not an universal solution addressing the engineering aspects of brake/vehicle design. In addition, Relevance of wear occurring in brake materials increased particularly with relation to the released chemicals and corresponding health and environmental hazards. It is well known that humidity can considerably modify the adhesion of rubbing counterfaces by creating menisci and increasing the contact area. The chemistry, morphology and phase composition of the friction layers (third body) generated on the friction surfaces could play a determining role when amounts of adsorbed water on brake surfaces is concerned. The friction layer is typically a complex mix of numerous materials and, as a rule, contains the agglomerated or sintered nanoparticles. Hence, quantum effects could further modify the adsorption of water. This work addresses the impact of humidity on wear and creep groan of two commercial brake material types: the so called i) "non-asbestos organic" (NAO) and the ii) "semi-metallic" (SM) brake materials rubbed against pearlitic gray cast iron rotors typically used in the passenger vehicles. The friction and wear tests were performed with the Universal Mechanical Tester (UMT) manufactured by Bruker and the wear surfaces/mechanisms were studied by using of scanning electron microscopy, energy dispersive X-ray microanalysis, and optical topography methods. The applied wear testing conditions were designed as a series of particularly designed drag tests and were performed at several different relative humidity levels ranging between 50% and 80%. The major findings confirmed the considerable effect of humidity on wear of brake materials. Both pad types wore noticeably less at increased humidity. This was ascribed to a better capacity to form a protective friction layer. The complex wear mechanisms including abrasive, adhesive, fatigue, and corrosion wear were observed on both material types, irrespectively of humidity levels, and they dependent on the chemistry and phase composition of the friction layer. Humidity also influenced the level of friction.

Carbon fibre reinforced ceramic composites (Cf/C-SiC) have been explored as lightweight and durable disc in a friction brake. This composite was manufactured through infiltration of liquid silicon into a Cf/C perform. It has heterogeneous microstructure, composed of three key phases, silicon carbide, Cf/C, and un-reacted residual silicon. The development of the transfer layer on the friction surface of Cf/C-SiC was studied through microstructural image registration of the surface after a range of braking stops on a laboratory-scale dynamometer test rig. When an organic pad was used as the counter face brake pad, it was found that a steady transfer layer was developed in silicon regions right after initial stops; in carbon-fibre/carbon (Cf/C) regions and most of the silicon carbide region, the friction surfaces were unsteady and any possible friction transfer layers were hardly built up. Large voids and cracks/crevices likely became pools to quickly and efficiently collect the transferred materials generated by the friction, but the compacts formed inside the pools were susceptible to be stripped off by further braking operation. Three types of friction surfaces were generalized: type I, the friction transfer layer had a steady relationship with the matrix and respectable longevity; type II, the transfer layer had an unstable relationship with the matrix and poor durability; type III, the friction transfer layer had a steady relationship with the matrix but short lifetime. After testing against organic pads under the laboratory scale dynamometer testing condition, the friction surface of each key phase in Cf/C-SiC composites disc was studied by transmission electron microscopy (TEM). It was found that the transfer layer developed on Si consists of fine particles of metal silicides, silicates and minerals. The substrate damage of Si was not observed, while the precipitates having high oxygen content were found in the substrate. Formation of an interfacial bonding between transfer layer and silicon substrate is believed to be the key factor for the formation of a stable transfer layer on Si. However, the interfacial bonding between transferred materials and SiC was not detected. Kinks are common features developed on the friction surface of SiC. The interface between carbon fibre and carbon matrix was experienced mechanical damage, in form of microcracks, and the transferred material was developed in the interface. Instead of transfer layer, a thin amorphous film, produced by friction induced amorphisation of carbon fibre, was developed on top of carbon fibre.

Traumatic brain injury (TBI) is a worldwide public health problem. It is often caused by impacts to the head, which can cause translational and rotational motions. During impacts to the head, the neck serves as one of the boundary conditions for determining its kinematic response. In today’s helmet assessment standards, the dynamics of the neck are not included, and in most standards only translational accelerations are examined within a short time interval around 20- 30 ms. However, to understand the risk of brain injury, it is also important to account for the rotational motions and the influence of the neck on head kinematics.  In this thesis the influence of the neck on head kinematics was investigated by comparing 5 different finite element (FE) models of the human. By using finite element analysis, simulations of four different accident scenarios were conducted. Most models are produced for the automotive industry and are not validated in vertical impacts with forces acting on the head. The accident scenarios included vertical and horizontal impacts to the head with different striking objects. The models included two anthropomorphic test devices (ATD) and three human body models (HBM). Furthermore, an isolated head was also used. The models were equipped with an industrial safety helmet, with and without a low friction layer (LFL). Additionally, the helmet versions were used to investigate how the various FE models predict the difference in rotational kinematics.  The head kinematics showed considerable disparities between the ATDs and the HBMs. The ATDs mostly showed a stiffer, spring-like behavior with higher translational accelerations and lesser rotational motions. Furthermore, the HBMs showed responses that were assumed to have been in better proximity to biofidelic responses. The incorporation of the LFL led to a reduction in peak resultant rotational velocity (PRV) in most models and accident scenarios. Furthermore, the results were highly influenced by the choice of duration. It was seen that the differences between the models increased over time, as the boundary effects could influence the kinematics to a larger extent. Hence, the neck had more influence on head kinematics at longer time durations.  This thesis contributes to a comparison of different FE models and how various boundary conditions affect the kinematics of the head. The Hybrid III should only be used in cases involving pure flexion-extension. The attachment of the KTH neck to the Hybrid III torso led to large differences in kinematic responses to the other models, and therefore it should not be used in virtual testing. Due to the resemblance between head-only and the HBMs, as well as the short duration in bicycle helmet assessment, the use of only a headform is probably a better approximation as the ATD necks that could be used are not good representations of biofidelity. Before implementing surrogate necks in helmet assessment, more investigations on the influence of the neck on head kinematics are necessary as well as the development of neck models with high biofidelity. / Traumatiska hjärnskador är ett globalt folkhälsoproblem. Traumatiska hjärnskador orsakas ofta av slag mot huvudet, vilket kan orsaka både translations- och rotationsrörelser av hjärnan. Vid slag mot huvudet verkar halsen som ett av randvillkoren som styr kinematiken av huvudet. I dagens hjälmstandarder är halsens dynamik inte inkluderad och i majoriteten av standarder är det endast translationsaccelerationer som undersöks samt inom en kort tidsram, runt 20-30 ms. För att förstå risken för hjärnskador behöver man även beakta rotationsrörelser och då blir halsens inflytande på huvudets kinematik av vikt, liksom att utvärdera kinematiken under en längre tid.  I detta examensarbete studeras halsens inverkan på huvudets kinematik genom att jämföra fem olika finita element (FE) modeller av människan. Genom att använda finita elementmetoden, genomfördes simuleringar av 4 olika olycksscenarior. Olycksscenariorna inkluderade vertikala och horisontella islag med olika objekt. De modeller som användes var två krockdockor och tre humanmodeller samt ett isolerat huvud. De flesta modeller är framtagna för bilindustrin vilket påverkar dess användningsområde genom begränsade valideringar av vertikala slag med krafter som verkar direkt på huvudet. Alla modeller var utrustade med en industrihjälmsmodell, med respektive utan ett lågfriktionslager. Dessutom användes hjälmmodellerna till att undersöka hur de olika FE modellerna förutspådde skillnader i rotationskinematik.  Kinematiken av huvudet visade på signifikanta skillnader mellan krockdockorna och humanmodellerna. Krockdockorna hade generellt ett stelare, fjäderliknande beteende med högre translationsacceleration och mindre rotationsrörelse. Vidare hade humanmodellerna ett beteende som var mer likt den förväntade mänskliga responsen. Användandet av lågfriktionslagret ledde till reduktion i resulterande peak rotationshastighet bland de flesta modeller och olycksscenarior. Resultatet påverkades nämnvärt av valet av tidsintervall. Vid längre tidsintervall var skillnaderna i beteende större mellan modellerna. Därför hade halsen större inverkan på huvudets kinematik vid längre durationer.  Detta examensarbete bidrar till en jämförelse av olika FE modeller och förståelse för hur olika randvillkor påverkar huvudets kinematik. Hybrid III borde endast användas för horisontella islag med enbart flexion-extensions rörelser. Infästningen av KTH halsen till Hybrid III gav stora skillnader i kinematiken jämfört med de andra modellerna, och därför ska den inte användas vid virtuella tester. På grund av de likheter som sågs mellan enbart huvud och humanmodellerna samt på grund av de korta islagen vid cykelhjälmsbedömningar, är troligtvis användandet av ett isolerat huvud en bättre approximation än användandet av de tillgängliga krockdockornas halsar. Innan man använder halsmodeller vid hjälmbedömningar, krävs fler studier på halsens inverkan på kinematiken samt framtagande av halsmodeller med mer människoliknande respons.