The high temperature interactions of alkali metal compounds with solids present in coal conversion processes are investigated. A temperature and concentration programmed reaction method is used to investigate the mechanism by which organically bound alkali is released from carbonaceous substrates. Vaporization of the alkali is preceded by reduction of oxygen-bearing groups during which CO is generated. A residual amount of alkali remains after complete reduction. This residual level is greater for potassium, indicating that potassium has stronger interactions with graphitic substrates than sodium. Other mineral substrates were exposed to high temperature alkali chloride vapors under both nitrogen and simulated flue gas atmospheres to investigate their potential application as sorbents for the removal of alkali from coal conversion flue gases. The compounds containing alumina and silica are found to readily adsorb alkali vapors and the minerals kaolinite, bauxite and emathlite are identified as promising alkali sorbents. The fundamentals of alkali adsorption on kaolinite, bauxite and emathlite are compared and analyzed both experimentally and through theoretical modeling. The experiments were performed in a microgravimetric reactor system; the sorbents were characterized before and after alkali adsorption using scanning Auger microscopy, X-ray diffraction analysis, mercury porosimetry and atomic emission spectrophotometry. The results show that the process is not a simple physical condensation, but a complex combination of several diffusion steps and reactions. There are some common features among these sorbents in their interactions with alkali vapors: In all cases the process is diffusion influenced, the rate of adsorption decreases with time and there is a final saturation limit. However, there are differences in reaction mechanisms leading to potentially different applications for each sorbent. Bauxite and kaolinite react with NaCl and water vapor to form nephelite and carnegieite and release HCl to the gas phase. However, emathlite reacts to form albite and HCl vapor. Albite has a melting point significantly lower than nephelite and carnegieite; therefore, emathlite is more suitable for lower temperature sorption systems downstream of the combustors/gasifiers, while kaolinite and bauxite are suitable as in-situ additives.

No description available.

No description available.

CIVINS / Carbon nanotubes (CNTs) exhibit exceptional electrical, thermal, and mechanical properties that could potentially transform such diverse fields as composites, electronics, cooling, energy storage, and biological sensing. For the United States Navy, composites potentially provide a significant decrease in lifetime maintenance costs of ships by eliminating hull corrosion. A stronger composite could also improve naval ship survivability or increase combat payloads by reducing the hull weight of ships and submarines. Further, cooling requirements of ship borne electronics have grown exponentially and represent a significant weight penalty for advanced ship designs. Any improvement in thermal transport could significantly improve future naval ship designs. In order to realize these benefits, methods must be discovered to fully characterize CNT growth mechanisms, consistently produce CUTs in manufacturable quantities, and to integrate CUTs into macroscale structures which reflect the properties of individual CUTs. While growth of CNTs in laboratory scale chemical vapor deposition (CVD) tube furnaces has shown great promise, existing low cost tube furnace designs limit the researcher's ability to fully separate critical reaction parameter such as temperature and flow profiles and limit the rate of temperature change during the growth process. Conventional tube furnace designs also provide limited mechanical access to the growth Site and prevent optical monitoring of the growth site, removing the ability to observe and interact in situ during growth. This thesis presents the SabreTube, a low-cost desktop cvD apparatus that decouples temperature and flow variables, provides mechanical and optical access to the reaction site during growth, and provides modular fixturing to enable versatile experimentation with and characterization of CUT growth mechanisms. This thesis also presents the Nanosled, a device designed to translate a substrate through a CVD furnace. / Contract number: N62271-97-G-0026. / CIVINS

Abstract not available

Graduation date: 1998

Graduation date: 1995

Coal continues to be burned by direct combustion in packed or moving bed in small size domestic furnaces, medium size industrial furnaces, as well as small power stations. Recent stringent restrictions on exhaust emissions call for a better understanding of the process of combustion of coal in beds. The present study is a prelude to developing methods of analysis to obtain this improved understanding. A one-dimensional steady-state computational model for combustion of a bed of solid fuel particles with a counterflowing oxidant gas has been developed. Air, with or without preheating, is supplied at the bottom of the bed. Spherical solid fuel particles (composed of carbon and ash) are supplied at the top of the bed. Upon sufficient heating in their downward descent, the carbon in particles reacts with oxygen of the flowing gas. The governing equations of conservation of mass, energy, and species are integrated numerically to obtain the solid supply rate whose carbon content can be completely consumed by a given gas supply rate. The distributions of solid and gas temperatures, of concentrations of various gas species, of carbon content in solid, and of velocity and density of gas mixture are also calculated along the bed length. The dependence of these distributions on the solid and gas supply rates, the air supply temperature, the size of solid fuel particle, and the initial carbon content in solid is also investigated. The calculated distributions are compared with the available measurements from literature to find reasonable agreement. More gas supply is needed for complete combustion at higher solid supply rate. At a given gas supply rate, more solid fuel particles can be consumed at higher gas supply temperature, for larger particle size, and for lower initial carbon content in solid. The temperature of the bed becomes higher for higher solid supply rate, higher gas supply temperature, larger solid particle diameter, or lower initial carbon content in solid. These reasonable results lead one to encourage extension of the model presented here to more complex problems involving combustion of coals in beds including the effects of drying and pyrolysis. / Graduation date: 1994

Thesis (Ph.D.)--University of Wollongong, 2009. / Typescript. Includes bibliographical references: leaf 248-256.

Thesis (M.S.)--West Virginia University, 2001. / Title from document title page. Document formatted into pages; contains xiv, 159 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 118-122).