Thesis (Ph. D.)--University of Washington, 2006. / Vita. Includes bibliographical references (leaves 96-100).

The electrodynamic interaction of Ganymede’s mini-magnetosphere with Jupiter’s corotating magnetospheric plasma has been shown to give rise to strong current systems closing through the moon and its ionosphere as well as through its magnetopause and magnetotail current sheet. This interaction is strongly evidenced by the presence of aurorae at Ganymede and of a bright Ganymede footprint on Jupiter’s ionosphere. This footprint is located equatorward of the main auroral emissions, at the magnetic longitude of the field line threading Ganymede. The brightness of Ganymede’s auroral footprint at Jupiter along with its latitudinal position have been shown to depend on the position of Ganymede relative to the center of the Jovian plasma sheet. Additionally, observations using the Hubble Space Telescope showed that Ganymede’s auroral footprint brightness is characterized by variations of three different timescales: 5 hours, 10-40 minutes, and ~100 seconds. The goal of the present study is to examine the relationship between the longest and the shortest timescale periodicities of Ganymede’s auroral footprint brightness and the local processes occurring at Ganymede. This is done by coupling a specifically developed brightness model to a three-dimensional multifluid model which tracks the energies and fluxes of the various sources of charged particles that precipitate into Ganymede’s ionosphere to generate the aurora. It is shown that the predicted auroral brightnesses and morphologies agree well with observations of Ganymede’s aurora from the Hubble Space Telescope. Our results also suggest the presence of short- and long-period variabilities in the auroral emissions at Ganymede due to magnetic reconnections on the magnetopause and in the magnetotail, and support the hypothesis of a correlation between the variability of Ganymede’s auroral footprint on Jupiter’s ionosphere and the variability in the brightness and morphology of the aurora at Ganymede. Finally, the modeled aurora at Ganymede reveals that the periodicities in the morphology and brightness of the auroral emissions are produced by two different dynamic reconnection mechanisms. The Jovian flow facing side aurora is generated by electrons sourced in the Jovian plasma and penetrating into Ganymede’s ionosphere through the cusps above the separatrix region. In this case, the reconnection processes responsible for the auroral emissions occur on Ganymede’s magnetopause between the Jovian magnetic field lines and the open magnetic field lines threading Ganymede’s Polar Regions. As for the magnetotail side aurora, it is generated by electrons originating from Ganymede’s magnetospheric flow. These electrons are accelerated along closed magnetic field lines created by magnetic reconnection in Ganymede’s magnetotail, and precipitate into Ganymede’s ionosphere at much lower latitudes, below the separatrix region.

This thesis studies hydrated oxygen and hydroxyl radicals as a basis for understanding the species formed in the icy surfaces of outer solar system bodies. Infrared spectroscopy is used to identify the species water-oxygen (H2O·O2) and water-hydroxyl (H2O·HO) complexes in inert gas matrices and presents a new mechanism for O2 formation in irradiated ices. The H2O·O2 Complex -- The H2O·O2 complex was identified in solid argon matrices at 11 K by measuring the infrared spectra of H2O⁄O2⁄Ar matrices. Absorption bands at 3731.6, 3638.3, 1590.2⁄1593.6 and 1551.9⁄1548.8 cm-1 were respectively assigned to asymmetric OH water stretching, symmetric OH water stretching, H2O bending, and the O2 stretching vibrations. This experimental data was in good agreement with the results of quantum mechanical calculations that predict the vibrational frequencies and intensities for H2O·O2. These calculations gave a binding energy of 0.72 kcal mol-1 for the complex. The H2O·HO Complex -- The H2O·HO complex was identified in solid argon matrices at 11 K by measuring the infrared spectra of OH⁄H2O⁄Ar matrices. The OH was formed in a Tesla coil discharge of an H2O⁄Ar gas stream. This gas stream also provided the source of H2O and Ar needed for the experiments. Three absorption bands were assigned to the OH stretch of the hydroxyl group in the complex. These three bands were caused by the occupancy of three different lattice sites. This experimental data was in good agreement with quantum mechanical calculations that predict the vibrational frequencies and intensities for H2O·HO. These calculations gave a binding energy of 5.69 kcal mol-1 for the complex. O2 Formation in Irradiated Ice -- A new mechanism for O2 formation in irradiated ice is presented. This mechanism draws on experimental evidence in the literature to explain the observations of solid O2 on or near the surface of the icy Galilean satellites, Europa and Ganymede. It is proposed that on these bodies, hydrogen peroxide, formed from the radiolysis and photolysis of the ice, is present in highly localized aggregates that hinder O2 diffusion out of the icy surface into the tenuous atmosphere. Further radiolysis and photolysis of these hydrogen peroxide aggregates can then lead to O2 formation via the formation of a short lived water-oxygen atom complex, H2O·O. The O atoms of a pair of these complexes then react rapidly to form O2