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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Fiber adsorbents for tert-butyl mercaptan removal from pipeline grade natural gas

Chen, Grace 12 January 2015 (has links)
The purpose of this thesis study is to assess the feasibility of using a fiber sorbent module system to remove t-butyl mercaptan (TBM), a common odorant, from pipeline grade natural gas. Odorants such as mercaptans are added to natural gas for safety reasons, but their combustion products are corrosive and decrease the lifetime of the turbines in which they are combusted. Therefore, it is desirable to remove the odorants to extend this lifetime. A TBM removal system attached to a 840 MW natural gas-fueled combined cycle power plant unit such as the one at Plant McDonough-Atkinson (Smyrna, GA) must process gas at a flow rate of approximately 180,000 standard cubic feet per minute. A single 85 MW GE 7EAQ gas turbine has a flow rate of approximately 15,000 standard cubic feet per minute, and will serve as the basis for a system design and process analysis study. The concentration of odorants in natural gas is typically 10 ppm or less. For the purposes of this study, the upper limit of 10 ppm TBM will be used. Zeolite 13X was selected as the model adsorbent for this study due to its high sorption capacity for mercaptans and its ease of incorporation into both fibers and pellets. Design calculations were performed to optimize and determine the feasibility of fiber modules for TBM removal, as well as assess their advantages over conventional pellet packed beds. An understanding of how critical parameters such as heat and mass transfer resistances, pressure drop, and capital and operating costs are affected by design specifications such as sorbent and bed dimensions, allows an optimal design for the needs of the model turbine to be found. Based on these design equations, a fiber sorbent module configuration that selectively and continuously removes TBM from natural gas is developed

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