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In recent years, people have raised their alertness to the hazard of air pollution. Sulfur dioxide is one of the most dangerous chemical compounds among those air pollutants. A study on removing sulfur dioxide from an air stream by adsorption using wood chips as the adsorbent is presented in this thesis. The reason for using wood as an adsorbent is that wood is a porous material and possesses a large surface of cell cavities which can hold a great amount of moisture. As sulfur dioxide gas is passed through the wood bed, it would be either condensed in the cell space of the wood by intermolecular attraction, adsorption or dissolved in the moisture held in the wood. This work was started with a review of literature. Then related references were collected and a proposal written. Douglas fir was chosen for the experiment because it is the most common kind of wood in the Pacific Northwest. After the process and proper equipment was set up, woodchips were screened and dried to prepare for further experiments. It was decided to use three different concentrations of sulfur dioxide. For each of the concentrations of sulfur dioxide, five levels of moisture (0%', 11%, 20%, 50% and saturated) were assigned to the selected woodchips. Fifteen combinations or experiments were done for the research. The results of the experiments show that dry wood (0% moisture content) had comparatively low characteristics in the adsorption of sulfur dioxide. For instance, at an influent so2 concentration of 1.12 ppm., about· 6 grams of dry woodchips adsorbed 29.37 µg. of sulfur dioxide in comparison to 2Q90.5 µg. of SO2 adsorbed in the same weight of woodchips but saturated with moisture. At an influent SO2 concentration of 1.83 ppm., the adsorption of sulfur dioxide increased from 7.73 µg. for the dry wood to 745.15µg. in the water saturated wood. For an influent SO2 concentration of 4.60ppm., dry wood adsorbed 15.26 µg. of SO2 while the moisture saturated wood adsorbed 1446.2 µg. The amount of dry woodchips used in above mentioned experiments were all about 6 grams. These data show that the moisture saturated wood adsorbed about 90 times the amount of sulfur dioxide that the dry wood adsorbed. It is clear that the wood adsorptivity increased with increasing moisture content. It was also found that wood adsorptivity and retention time were affected by the different flow rate of carrier gas. The figures show that most of the data fit a Freundlich equation. Other equations were developed to calculate the adsorptivity and retention time by obtaining the influent and effluent concentration of sulfur dioxide through the adsorbent bed.

Recent work indicates that microorganisms present in soils can remove carbon monoxide from the atmosphere and as such constitutes a major sink. B.E.T. adsorption studies were carried out on representative soils from the Willamette Valley River Basin in order to determine their adsorptive characteristics for carbon monoxide and other gases. Attempts were made to isolate, through a non-soildestructive sterilization, the adsorptive characteristics of the soil microorganisms as well as of the test soil. The carbon monoxide studies show physical adsorption equivalent to the coverage of a few per cent of the surface area at 25.0° and 76 cm-Hg. Adsorption studies also shows that the soil rather then the microorganisms adsorbs most of the carbon monoxide. On sterilized soil, chemical sorption of oxygen was present and was probably caused by the oxidation of dead or damaged soil microorganisms. Hysteresis effects were present in all adsorption studies at 25.0° and appears to be a characteristic of the constituents of the soil and represents a new and as yet unexplained phenomenon.

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M. Tech. Engineering Chemical. / Aims to investigate how the addition of impurities in a CO2 stream affects the adsorption capacity of CO2 on South African coals. To achieve this aim, the following objectives were carried out. 1. To measure the adsorption isotherms and adsorption capacities of pure CO2 and flue gas mixtures on various South African coals under in-seam conditions including pressures up to 88 bar and isothermal temperature of 35 &#x00BA%x;C; 2. To evaluate the effects of coal rank on the adsorption isotherms and adsorption capacities of pure CO2 and flue gas mixtures; 3. To do a comparative study to evaluate the effects of CO2 impurities on the adsorption capacity of pure CO2 on coal; 4. To study the degree of preferential sorption of the individual flue gas mixtures components on coal; 5. To determine the suitability of the Langmuir, Freundlich, and Temkin adsorption isotherm models in representing pure CO2 adsorption onto coal; and 6. To determine the suitability of Extended Langmuir (EL) adsorption models in representing the flue gas mixture adsorption onto coal.