Philosophiae Doctor - PhD / The increasing population in search for better social and economic development in coastal areas puts groundwater resources under pressure because of the high fresh water demand for domestic and agriculture use. Seawater intrusion is widely recognised as major concern in coastal aquifers across the globe and is influenced by multiple factors, being climate variation which is projected to adjust recharge of groundwater because of decreased precipitation patterns and to increase sea level variations and over-abstraction due to high freshwater demand as a result of increased population and agricultural practices, thereby inducing salinization in groundwater. The coastal aquifer in Heuningnes Catchment is not exempted from these issues and salinization is a major concern in the area affecting groundwater quality. In Heuningnes Catchment and South Africa in general there is limited knowledge on the application of integrated approach for assessing groundwater quality especially salinization mechanism in coastal aquifers. The main goal of this research is to test and demonstrate the viability of using joint interpretation approach of geophysics, geochemical and geological information to investigate groundwater quality in coastal aquifers thus improving on the understanding of using such approach. This work offers the initial thorough assessment of groundwater quality and understanding of the salinity sources and hydro-geochemical processes governing the chemical composition of groundwater in the region. Thus provide advice on the fitness of this water for consumption and irrigation purposes. Thirty-two groundwater samples were collected and analysed for (Mg2+), (Ca2+), (Na+), (K+), (Cl-), (SO42), (HCO3-), (pH, TDS and EC). To estimate fitness of groundwater quality for consumption purposes WHO (2011) and SANS241 guideline were used and for irrigation utilization the water quality indices (EC), (Na+%), (SAR), (RSC), (KR) and (MR) were used. Statistics approaches were employed to ascertain the primary geochemical processes governing the chemical composition of groundwater in the research region. Lastly, the spatial distribution maps were created by means of ArcGIS. Electrical resistivity method was used to map the extent of saline distribution within the subsurface. The findings of this study revealed that groundwater in the region is alkaline type and TDS, EC, Na+, Cl- exceeded WHO and SANS241 guidelines for consumption water. The geophysical investigation revealed that the sandy clay/clayey sand, fine sand and fractured sandstone units make up the coastal aquifer systems within the area. Further, revealed that these aquifers were saturated with fresh, saline or brackish water depending on the subsurface layer. The presence of saline and brackish was confirmed by the chemical results which indicated a Na+-Cl- type as a dominant water type. Also classifying groundwater based on EC and TDS supports these findings. The foremost hydro-geochemical processes that controls the salinity and quality of groundwater in the study region as indicated by Gibbs plot are water-rock interaction followed by evaporation process. Furthermore, analysis of hydrochemical data also proposes that weathering of silicate minerals, ion-exchange and dissolution of carbonate minerals amended ion concentration in groundwater thus influencing salinisation in certain parts of the study region. Also assessment of ionic-ratios displays influences of marine sprays as well as seawater, on the chemical structure of groundwater within the Heuningnes Catchment aquifer. Valuation of groundwater quality and its fitness for ingestion and irrigation purposes, the results indicated that shallow groundwater in the area is not suitable for any use; however, groundwater from deeper boreholes was found fresh and appropriate for irrigation and household purposes. Findings of this study indicated that salinity is the major groundwater quality issue for this area and that monitoring of groundwater quality in Heuningnes Catchment is limited. The absence of consistent monitoring program on groundwater quality makes it difficult to ascertain long term trends on groundwater quality parameters. Therefore, this study emphasizes the need for regular groundwater quality monitoring to assess the trends of these parameters in order to make an informed decision as to what can be done for mitigation purposes.

Gold exploration in the laterite terrains of the Siguiri basin (Guinea-West Africa) is discussed in this thesis. It seeks to propose and develop effective and reliable geochemical exploration techniques applied in such laterite terrains. The study is also intended to investigate and provide some geological clues as to why, in some target areas, the reconnaissance test drilling across the geochemical anomalies couldn’t intersect economic gold mineralisation. Targets were generated based on soil geochemical results, some of which were drilled without delivering economic discoveries even on areas with strong and consistent geochemical signatures. To find the failure and define the appropriate methods to be used is the core of the thesis. More importantly, the geological observation is aimed at sourcing and establishing the nature and validity of geochemical anomalies within the license area and their relationship with the underlying lithologies and structural networks. The geological field work conducted during this study is mostly based on regolith and surface geological mapping. The thick laterite cover, deep weathering, bedrock geology, gold geochemistry (the gold geochemical anomalous results are defined according to historical data before 2007), soil formations and variations in climate conditions are emphasized to illustrate the importance of mineral element mobility and dispersion in the weathering profiles. The knowledge and experience in regolith geochemistry and regolith mapping provide the advantage to exploration geologists. The depletion of ore resources and reserves in Siguiri and the continuous decline of the gold price in comparison to the complexity of exploring for gold are demanding more scientific-related thoughts and techniques to be integrated in the available geological, geochemical and geophysical information so as to reduce costs. The integration of good exploration strategy and technique may result in the possibility of making viable discoveries in this highly competitive geological environment where the mineral resources become depleted every day.

This master's thesis deals with the natural environment of two selected deserted medieval localities - Jevany-Dubina (Prague-East District) and Hol (Capital City of Prague). This work consists of two relatively independent parts. The first theoretical part describes chemical processes occurring in forest soils, and anthropogenic impact on soil. The second part is the actual research associated mainly with the study of agricultural land use and the variability of the natural environment influenced by man. The research of the Jevany-Dubina site consisted of an additional geodetic survey, a description of all relics, a surface collection and a geophysical survey. Selected procedures partially helped to interpret the parts of the settlement and its function. We conclude that a farmstead with guardians was most probable. The main part of the thesis is devoted to a geochemical research in the intravilan and extravilan of the deserted medieval village Hol. The greatest attention was paid to the interpretation of phosphorus (P) distribution in soil. Another of the issues dealt with in this thesis was the extent to which residents fertilized their fields and gardens around the village. Higher values of anthropogenic P in soil have been documented only in the intravilan of the village. Farther away from the...

The principal goal of this thesis was to provide relevant information on the spatiotemporal dynamics of erosion-sedimentation and weathering processes in the last climatic cycle and to interpret the obtained data in the context of European paleoenvironmental development. Representative sequences of loess, paleosols and lacustrine sediments from the area of the Bohemian Massif, the Carpathian Foredeep, the the Vienna Basin and the northern edge of the Panno-nian Basin were investigated using a wide range of instru-mental tools and paleontological methods. A uniform analytical approach applied to these sedimentary facies has provided ample new information about the paleoclimatolog-ical and paleoenvironmental development of East-Central Europe - an important region in the transition zone from oceanic to continental macro-climatic settings. The individu-al studies included in this PhD thesis cover the complete period of the Upper Pleistocene (MIS 5-2; ~130-12.7 ky BP) and are presented as separate chapters in the order of the superposition of strata. Chapters III/1-3 deal with the results of research into six loess/paleosol sequences (LPSs) situated in the Central Bohemian Massif, throughout the Moravian Valleys, and at the northwest and north edge of the Pannonian Basin. A detailed paleoenvironmental...