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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Geology, geochemistry and evolution of the Esfordi Phosphate - Iron Deposit, Bafq Area, Central Iran

Jami, Morteza, School of Biological, Earth & Environmental Sciences, UNSW January 2005 (has links)
Esfordi is a Kiruna-type Fe???P oxide deposit in the Bafq district of Iran. It formed within a predominantly rhyolitic volcanic sequence that formed in a continental margin tectonic regime and is of Cambrian age. The gently dipping, stratabound ore body is lenticular and displays a well-developed mineralogical zonal pattern. The Fe-oxide rich core contains a central zone of massive magnetite and a more hematitic brecciated rim. The overlying P-rich ore body contains massive and brecciated, apatite-rich variants with accessory hematite and actinolite. A zone of apatite-bearing veins and disseminations envelopes the Fe-oxide and P-rich zones and extends into overlying volcaniclastics that contain detrital magnetite ?? apatite clasts. The main ore zones are surrounded by Ca-rich alteration, dominated by actinolite, extending ~100 m into the more permeable overlying volcaniclastics. Beyond this envelope is widespread development of secondary K-feldspar. Mesoscopic and microscopic observations reveal a paragenetic sequence containing four generations of apatite. The early stage is a LREE-rich apatite 1 that occurs within the massive and brecciated magnetite core. The second generation is large and brecciated apatite 2, associated with hematite and actinolite. Both apatite 1 and 2 exhibit widespread dissolution and reprecipitation to form a LREE-poor granular apatite that is generally associated with quartz-carbonate??REE minerals. The final stage involved an overprint of LREE-poor apatite 3-carbonate-quartz-actinolite-chlorite-epidote??bastnaesite??synchesite extending into the host rocks. Fluid inclusions in apatite 1 have homogenisation temperatures of 375-425oC and indicate salinities of 14???18 wt. % NaCl. The magnetite displays low ???????O of -0.1???1.7 ???, suggesting precipitation from fluids with ???????O of 7.8???9.6 ??? at ~400oC, consistent with a magmatic source. Fluid inclusions in apatite 2 homogenise between 195???295oC with indicated salinities of 13???19 wt. % NaCl. The associated hematite displays ???????O of -0.2???2.3 ??? which would be in equilibrium with fluids having a ???????O of 10.7???13.0 ??? at ~250oC. Such enriched isotopic fluids suggest interaction of magmatic fluids with cooler saline fluids that were probably derived from the underlying carbonate-rich sequences. Fluid inclusions in apatite 3 and quartz homogenise at 145???155oC and, together with a quartz ???????O of 16.0???17.1 ???, suggests precipitation from a fluid with ???????O of -0.7???2.1 ??? that is likely to have resulted from the introduction of a cooler, less saline and isotopically depleted fluid (such as sea water). The results of this study clearly indicate a significant role for fluids in the evolution of the Esfordi deposit but do not preclude a role for immiscible Fe-oxide???P-rich melts in the initial stages of the mineralising process.
2

Geology, geochemistry and evolution of the Esfordi Phosphate - Iron Deposit, Bafq Area, Central Iran

Jami, Morteza, School of Biological, Earth & Environmental Sciences, UNSW January 2005 (has links)
Esfordi is a Kiruna-type Fe???P oxide deposit in the Bafq district of Iran. It formed within a predominantly rhyolitic volcanic sequence that formed in a continental margin tectonic regime and is of Cambrian age. The gently dipping, stratabound ore body is lenticular and displays a well-developed mineralogical zonal pattern. The Fe-oxide rich core contains a central zone of massive magnetite and a more hematitic brecciated rim. The overlying P-rich ore body contains massive and brecciated, apatite-rich variants with accessory hematite and actinolite. A zone of apatite-bearing veins and disseminations envelopes the Fe-oxide and P-rich zones and extends into overlying volcaniclastics that contain detrital magnetite ?? apatite clasts. The main ore zones are surrounded by Ca-rich alteration, dominated by actinolite, extending ~100 m into the more permeable overlying volcaniclastics. Beyond this envelope is widespread development of secondary K-feldspar. Mesoscopic and microscopic observations reveal a paragenetic sequence containing four generations of apatite. The early stage is a LREE-rich apatite 1 that occurs within the massive and brecciated magnetite core. The second generation is large and brecciated apatite 2, associated with hematite and actinolite. Both apatite 1 and 2 exhibit widespread dissolution and reprecipitation to form a LREE-poor granular apatite that is generally associated with quartz-carbonate??REE minerals. The final stage involved an overprint of LREE-poor apatite 3-carbonate-quartz-actinolite-chlorite-epidote??bastnaesite??synchesite extending into the host rocks. Fluid inclusions in apatite 1 have homogenisation temperatures of 375-425oC and indicate salinities of 14???18 wt. % NaCl. The magnetite displays low ???????O of -0.1???1.7 ???, suggesting precipitation from fluids with ???????O of 7.8???9.6 ??? at ~400oC, consistent with a magmatic source. Fluid inclusions in apatite 2 homogenise between 195???295oC with indicated salinities of 13???19 wt. % NaCl. The associated hematite displays ???????O of -0.2???2.3 ??? which would be in equilibrium with fluids having a ???????O of 10.7???13.0 ??? at ~250oC. Such enriched isotopic fluids suggest interaction of magmatic fluids with cooler saline fluids that were probably derived from the underlying carbonate-rich sequences. Fluid inclusions in apatite 3 and quartz homogenise at 145???155oC and, together with a quartz ???????O of 16.0???17.1 ???, suggests precipitation from a fluid with ???????O of -0.7???2.1 ??? that is likely to have resulted from the introduction of a cooler, less saline and isotopically depleted fluid (such as sea water). The results of this study clearly indicate a significant role for fluids in the evolution of the Esfordi deposit but do not preclude a role for immiscible Fe-oxide???P-rich melts in the initial stages of the mineralising process.

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