The Bien Venue massive sulphide deposit is associated with a felsic volcanic succession developed in the north-eastern part of the Barberton Greenstone Belt, Eastern Transvaal. The deposit is situated 8km east-north-east of Louw's Creek between the Lily Syncline to the south and the Stentor Pluton to the north. The stratigraphy of the Onverwacht, Fig Tree and Moodies Groups in the vicinity of the deposit is poorly documented, and the exact stratigraphic position of the host felsic volcanics is not known. They are tentatively correlated with the felsic volcanics from the Theespruit Formation, Onverwacht Group. The felsic volcanics have undergone low-grade greenschist facies metamorphism and occur as quartz-sericite schists. Detailed petrography enables sub-division of the volcanic succession into distinct units. A lapilli metatuff unit hosts the base metal and precious metal mineralisation. The sulphides are best developed in the upper part of this unit, together with intercalated barite-rich horizons and cherts. A series of structural events have modified the attitude of the lithological units and disrupted the continuity of the orebody. The orebody comprises stratabound lenses of massive to semi-massive and often banded sulphides, as well as disseminated sulphide mineralisation. The dominant base metal mineralogy consists of pyrite, sphalerite, chalcopyrite, galena and tennantite. Native silver and various copper-silver sulphides are also associated with the base metal sulphides. A vertical zonation of the mineralisation exists, from pyrite-chalcopyrite-rich ore in the footwall, to pyrite - chalcopyrite-sphalerite-galena-barite-rich ore towards the hanging wall. Geochemical studies indicate that the Bien Venue lithologies are rhyolitic to rhyodacitic in composition and show a calc-alkaline affinity. The mobility of some elements at Bien Venue has been clearly demonstrated. This is believed to be associated with hydrothermal alteration that has led to SiO2 and MgO enrichment, as well as K2O depletion, in the wall rocks of the deposit. The geological setting and nature of the mineralisation at Bien Venue suggest that it is an example of a volcanogenic exhalative sulphide deposit. In terms of the classification scheme suggested by Hutchinson (1973, 1980), Bien Venue would best be described as a Primitive type deposit that contains barite. / Thesis (M.Sc.)-University of Natal, 1990

The Uitkomst Complex is a mineralized, layered basic to ultrabasic intrusion, hosted by sedimentary rocks of the lower part of the Transvaal Supergroup. It is situated on the farms Uitkomst 541JT and Slaaihoek 540JT, about 25 km north of Badplaas and 50 km east of the eastern limb of the Bushveld Complex in the Mpumalanga province of South Africa. The intrusion plunges between 8 to 10º to the northwest with an established length of 12 km and a total thickness of 850 m. It is divided into seven lithological Units (from base to top), the Basal Gabbro (BGAB), Lower Harzburgite (LHZBG), Chromitiferous Harzburgite (PCR), Main Harzburgite (MHZBG), Pyroxenite (PXT), Gabbronorite (GN) and Upper Gabbro units (UGAB). A detailed petrographic and geochemical investigation of borehole core SH176, which provided a complete intersection of the Uitkomst Complex was carried out. The study shows that the Complex may have crystallized in a dynamic magma conduit setting. The whole rock geochemical trends indicate that there is a reversed fractionation in the basal portion of the Complex and a lack of fractionation in much of the MHZBG. Trace and REE variations show a decrease in concentration with height, contrary to what is expected of a progressively differentiating magma in a close system. Further, the platinum-group element concentration of the four basal units show no depletion with increasing height, suggesting that the individual units are not related to each other by means of in situ fractionation. Instead, a model whereby the individual units crystallized from distinct pulses of magma best explains the data. By comparing Nd isotopes and ratios of highly incompatible trace elements like [Th/La]n and [Sm/Ta]n from the Uitkomst Complex and Bushveld Complex it is seen that the Uitkomst magmas are of a similar lineage as the B1 magma of the Bushveld Complex, supporting a genetic link between the two complexes. The upper portion of the Uitkomst Complex shows values more akin to B3 magmas indicating the possible presence of more than one type of magma. Based on the available S isotope and trace element data, the sulphides of the Complex appear to have formed within the Complex, probably in response to contamination of the magma with dolomite. Entrainment of sulphides from depth is considered unlikely. The relatively low Cu/Ni ratios of the sulphides in the LHZBG, PCR and MHZBG (Cu/Ni 0.03 to 0.8) may be modelled by sulphide segregation from B1 magma and not from fractionation of sulphides that were later entrained in the streaming magma. / Dissertation (MSc)--University of Pretoria, 2006. / Geography, Geoinformatics and Meteorology / Unrestricted

The Nsuze Group forms the lower, predominantly volcanic succession of the Pongola Supergroup. The 2.9Ga Nsuze Group outcrops in southeastern Mpumalanga, northern KwaZulu-Natal and Swaziland. The volcanic rocks of the Nsuze Group are basalts, basaltic andesites, andesites, dacites and rhyolites preserved as both lava and pyroclastic deposits. The oldest volcanic sequence of the Nsuze Group is the basaltic Wagondrift Formation. The younger Bivane Subgroup represents the main volcanic component of the Nsuze Group. The White River Section represents a complex volcanic history of magma storage, fractionation, and eruption, supplied by a multi-level system of magma chambers. The basaltic and basaltic andesite rocks of the White Mfolozi Inlier represent the steady and non-violent eruption of lavas from related volcanic centres. The Nsuze Group rocks have been metamorphosed by high heat flow burial metamorphism to lower greenschist facies. Geochemically, elements display well-defined fractionation trends, with evident sub-trends within each phase group of samples. These sub-trends are related to the fractionation of key minerals, in particular plagioclase. The REE patterns show that evolution of magma was largely controlled by the fractionation of plagioclase. All REE patterns show LREE enrichment relative to the HREE. The Wagondrift Formation was derived from a more depleted source than the younger Bivane Subgroup volcanic rocks and exhibits a within-plate tectonic signature. The volcanic rocks of the Bivane Subgroup in the White River Section and the White Mfolozi Inlier are geochemically similar. The volcanic rocks of the Bivane Subgroup of both the White River Section and the White Mfolozi Inlier have a subduction zone tectonic signature, in particular a Ta-Nb negative anomaly. Tectonic discrimination diagrams suggest an enriched source related to a continental-arc setting. The geochemistry suggests an eclogitic source for the Nsuze Group volcanic rocks. The formation of eclogite in the mantle requires subduction of basaltic material. Archaean models for subduction-like processes include decoupling of oceanic crust and subsequent underplating of the continental lithosphere, and low-angle subduction which minimises the effect of the mantle wedge. It is possible that a combination of these processes resulted in an enriched eclogitic source for the magmas of the Nsuze Group. / Thesis (M.Sc.)-University of Natal, Durban, 2003.