An array of stratigraphic, chemical, isotopic, and mineralogical evidence indicates that an impact terminated the Cretaceous Period. The 180-km-diameter Chicxulub crater, which now lies buried on the Yucatan peninsula of Mexico, was probably formed by the impact. The impactor was probably a long-period comet. Shock devolatization of the thick carbonate/evaporite sequence impacted at Chicxulub probably led to a severe and long-lasting greenhouse warming and a prompt pulse of sulfuric acid rain. The fallout of crater ejecta formed two layers: a lower layer which varies in thickness following a power-law relation based on distance from the Chicxulub crater and an upper, globally-distributed, uniformly ∼3-mm-thick layer. The upper layer probably represents the fallout of condensates and entrained solid and liquid particles which were distributed globally by the impact fireball. The lower layer consists of brecciated rock and impact melt near the crater and largely altered tektites far from the crater. The clasts of this layer were probably ballistically transported. The Raton, New Mexico K/T boundary section preserves the fireball and ejecta layers in a coal-free nonmarine environment. Siderophile, chalcophile, and lithophile trace element anomalies occur similar to those found at marine K/T boundary localities. Soot occurs peaking in the 3-mm-thick fireball layer and the immediately overlying 3 mm of sediment, implying prompt burning of the Cretaceous forests. The Brazos River, Texas continental-shelf K/T sections preserve coarse boundary sediments which were probably produced by impact waves. Siderophile and chalcophile trace-element anomalies occur suggesting that the fireball layer and possibly part of the ejecta layer are interbedded with the coarse boundary sediments. The Beloc, Haiti deep-sea K/T sections preserve a thick ejecta sequence including altered and unaltered tektites and shocked minerals capped by the fireball layer. The thick K/T ejecta preserved at this and other nearby K/T localities require a source crater of Chicxulub's size and location. The composition of the tektites and shocked grains require an impact into recently extracted continental crust with a carbonate/evaporite component as found at the Chicxulub crater.

Ph.D., Faculty of Science, University of the Witwatersrand, 2011 / The Wahweap Formation is an ~400 m thick clastic sedimentary succession of fluvial and estuarine channel sandstones and floodbasin mudrocks that was deposited in western North America during the Late Cretaceous. It preserves important mammal, dinosaur, crocodile, turtle and invertebrate fossils that have been the subject of recent palaeontological investigations. The Wahweap Formation can be divided into lower, middle, upper, and capping sandstone members based on sand:mud ratios and degree of sandstone amalgamation. Facies analysis reveals the presence of ten facies associations grouped into channel and floodbasin deposits. Facies associations (FAs) from channels include: (1) single-story and (2) multistory lenticular sandstone bodies, (3) major tabular sandstone bodies, (4) gravel bedforms, (5) low-angle heterolithic cross-strata, and (10) lenticular mudrock, whereas floodbasin facies associations include: (6) minor tabular sandstone bodies, (7) lenticular interlaminated sandstone and mudrock, (8) inclined interbedded sandstone and mudrock, and (9) laterally extensive mudrock. The lower and middle members are dominated by floodbasin facies associations. The lower member consists dominantly of FA 8, interpreted as proximal floodbasin deposits including levees and pond margins, and is capped by a persistent horizon of FA 3, interpreted as amalgamated channel deposits. FAs 4 and 6 are also present in the lower member. The middle member consists dominantly of FA 9, interpreted as distal floodbasin deposits including swamp, oxbow-lake and waterlogged-soil horizons. FAs 1, 2, 5, 6, 7, 8, and 10 are present in the middle member as well, which together are interpreted as evidence of suspended-load channels. The upper member is sandstone-dominated and consists of FAs 1, 2, 3, 5, 7, and 8. FAs 5 and 7, which occur at the base of the upper member, are interpreted as tidally influenced channels and suggest a marine incursion during deposition of the upper member. The capping sandstone is characterized by FAs 3, 4, and 6, and is interpreted to represent a major change in depositional environment, from meandering river systems in the lower three members to a low-accommodation, braided river system. Combined results of facies and palaeosol analyses suggest that the overall climatic conditions in which the Wahweap Formation was deposited were generally wet but seasonally arid, and that iv conditions became increasingly moist from the time of lower member deposition up to the time of middle member deposition. Improved age constraints were obtained for the Wahweap Formation by radiometric dating of two devitrified ash beds (bentonites). This allowed for deposition to be bracketed between approximately 81 Ma and 76 Ma. This age bracket has two important implications: firstly, it shows that the Wahweap Formation is synchronous with fossiliferous deposits of the Judithian North American Land Mammal Age, despite subtle differences in faunal content. Secondly, it shows that the middle and upper members were deposited during the putatively eustatic Claggett transgression (T8 of Kauffman 1977) in the adjacent Western Interior Seaway. This is consistent with facies analysis which shows a marked increase in tidally-influenced sedimentary structures and trace fossils at the top of the middle and base of the upper members. Following recent alluvial sequence stratigraphic models, the middle member is interpreted as the isolated fluvial facies tract, while the upper member represents the tidally influenced and highstand facies tracts. Maximum transgression occurred during deposition of the lowest part of the upper member, synchronous with the Claggett highstand in other parts of the Western Interior Basin. The sequence boundary is placed at the base of the overlying capping sandstone member, diagnosed by a major shift in petrography and paleocurrent direction, as well as up to 4 m of fluvial incision into the underlying upper member. The capping sandstone member is interpreted as the amalgamated fluvial facies tract of an overlying sequence. Analysis of the western-most exposures of the Wahweap Formation on the Markagunt and Paunsaugunt plateaus shows facies variations in the proximal and distal parts of the central Western Interior Basin. The inconsistent thickness and variations in fluvial architecture, as well as the presence of unconformities and generally poor exposure in the west, hinder correlation attempts and also prevent the subdivision of the Wahweap Formation into members. Only the capping sandstone, which can be positively identified west of the Paunsaugunt fault, has a consistent thickness and fluvial architecture across the west-east extent of the Wahweap Formation. The capping sandstone also bears remarkable lithological similarity to the Tarantula Mesa Formation which is exposed to the east in the Henry Mountains Syncline, and it is suggested that these two units be equated under the name “Tarantula Mesa Formation”, which has precedence.

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Includes other papers published by the author. Bibliography: p. 620-629.

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Many of the world's oil fields and aquifers are found in carbonate strata. Some of these formations contain vugs or cavities several centimeters in size. Flow of fluids through such rocks depends strongly upon the spatial distribution and connectivity of the vugs. Enhanced oil recovery processes such as enriched gas drives and groundwater remediation efforts like soil venting operations depend on the amount of hydrodynamic dispersion of such rocks. Selecting a representative scale to measure permeability and dispersivity in such rocks can be crucial because the connected vug lengths can be longer than typical core diameters. Large touching vug (centimeter-scale), Cretaceous carbonate rocks from an exposed rudist (caprinid) reef buildup at the Pipe Creek Outcrop in Central Texas were studied at three different scales. Single-phase airflow and gas-tracer experiments were conducted on 2.5 in. diameter by 5 in. long cores (core-scale) and 5- to 10-ft-radius well tests (field-scale). Zhang et al. (2005) studied a 10 in. diameter by 14 in. high sample (bench-scale). Vertical permeability in the bench-scale varied from 100 darcies to 10 md and in the core-scale averaged 2.5 darcies. The field-scale permeability was estimated to be 500 md from steady state airflow and pressure transient tests. In the bench and core scales a connected path of vugs dominates flow and tracer concentration breakthrough profile. Tracer transport showed immediate breakthrough times and a long tail in the tracer concentrations characterized by multiple plateaus in concentrations. Neither flow nor tracer transport can be explained at these scales by the standard continuum equations (Darcy’s law or 1D convection dispersion equation). However, interpreting field-scale measurements with standard continuum equations suggested that a strongly connected path of vugs did not extend past a few feet. In particular, the tracer experiment in the field scale can be modeled accurately using an equivalent homogeneous porous medium with a dispersivity of 0.5 ft. In our measurements, permeability decreased with scale, while vug connectivity and multi-scale effects associated with vug connectivity decreased with increasing scale. We concluded that approximately 5 ft could be considered the representative scale for the large-touching-vug carbonate rocks at the Pipe Creek Outcrop. The major contribution of this research is the introduction of an integrated, multi-scale, experimental approach to understanding fluid flow in carbonate rocks with interconnected networks of vugs too large to be adequately characterized in core samples alone. / text