M.Sc. (Geology) / Please refer to full text to view abstract

The Hartbees River Thrust Belt (HRTS) is a 40-60 km wide, southwest-vergent zone of complex structure, lithostratigraphy and high-grade metamorphism in the northeastern part of the mid-Proterozoic Namaqua Tectonic Province. The HRTS comprises the boundary zone separating the Bushmanland and Gordonia Subprovinces of the Namaqua Province. A knowledge of the movement histories of major ductile shear zones within the HRTS is fundamental to understanding the tectonic development of the belt, and Namaqua tectogenesis as a whole. In spite of this, no detailed microstructural kinematic studies have been attempted and the movement histories and age relationships of these shear zones have not been described in detail. This thesis represents a detailed microstructural kinematic study of a representative suite of orientated samples of mylonitic rocks, collected from five ductile shear zones within the HRTS. These shear zones include the Neusspruit Lineament, the Kakamas shear zone (KSZ), the Hugosput shear system (HSS), the Rozynenbosch-Ganzenmond shear zone (RGSZ) and the Graafwater shear system (GSS). Accepted modern methods of microstructural kinematic analysis were applied to samples of mylonite from these shear zones, in order to determine the precise orientation of the kinematic vectors, and the sense and relative ages of movements on each of the shear zones. Shear sense criteria, including composite SoC planar fabrics and shear band foliations, asymmetrical porphyroclast systems, mica-fish, oblique grain-shape and subgrain fabrics, asymmetrical microfolds, and the displacement of fractured rigid grains, together with a well-developed mylonite elongation lineation, conclusively indicate that SSW-directed thrusting occurred along the HSS, RGSZ, GSS and possibly along the Neusspruit Lineament, while normal, top-to-NE movements occurred on the Neusspruit Lineament, KSZ and HSS. Rare transposition criteria, and textural and paragenetic contrasts between syn-kinematic fabrics, strongly suggest that the phase of normal, top-to-NE movement seen in the northeastern HRTS shear zones is younger than the more widespread top-to-SW thrusting event. On the basis of mesoscopic structural criteria, SSW-directed thrusting is correlated with the D₂ deformation event in the HRTS. The mylonite zones have been refolded by ENE-SSW trending F₃ crossfolds, whose demonstrated coaxial relationship to the mylonite elongation lineation precluded reorientation of primary kinematic vectors. In the southwestern HRTS, primary thrust vectors have been reoriented by right-lateral, strike-slip shearing adjacent to the Pofadder Lineament during D₄. Simple shear dispersion of mylonite lineations related to normal movement, suggests that they too have been modified by D₄ shearing, and this constrains the timing of extensional movements to post-D₂ and pre- or syn-D₄. Syn-kinematic mineral assemblages, rheological criteria and the annealing states of the mylonites, provide insight into the thermotectonic evolution of the shear zones. A model is proposed in which the movement histories of shear zones within the HRTS are explained in terms of a typical orogenic cycle, involving crustal thickening by thrusting during a compressional orogenic phase, followed by collapse of the thickened crust during an extensional taphrogenic phase.

Banded iron-formations (BIFs) are chemically precipitated sedimentary rocks in which Fe-rich bands or laminae alternate with Fe-poor ones. They formed within a specific time-span of the geological record. Their occurrence is restricted between 2.3 and 1.9 Ga, and characterises virtually all the major Precambrian-aged sedimentary basins of the world. The Precambrian Transvaal Basin in Griqualand West, South Africa, is noted for its well-developed BIF units. The Kuruman and Griquatown BIFs comprising the Asbesheuwels Subgroup (up to 1000m thick) are the best known and thickest of these. As far as metallogenesis is concerned, the Kuruman BIF is of major importance, for it carries the world's largest crocidolite (blue asbestos) deposits. The uppermost, youngest member of iron-formation deposition in the Griqualand West Sequence is represented by the Voëlwater BIF. The direct association between the latter and the giant Mn-deposits of the Kalahari Field, renders the Voëlwater association unusual, if not unique, in the geological record. The Voëlwater BIF represents a typical example of the so-called "Superior-type", and in the area of study it has undergone late-diagennetic to low-grade metamorphic processes. This is evident from the mineralogical composition and textural signature of the various BIF lithologies. Specifically, the minerals that make up the Voëlwater BIF are mainly chert(quartz), Fe-oxides (magnetite and hematite), Fe-silicates (greenalite, stilpnomelane, minnesotaite, riebeckite, Fe-mica), Fe-carbonates (members of the dolomite-ankerite series and siderite), calcite and pyrite. Soft-sediment deformation structures and shear-stress indicators are abundant in carbonate-rich and granular, silicate-rich BIF lithologies respectively. The bulk chemical composition of the study rocks is relatively simple and is characterised by the abundance of essentially three elements, namely Si, Fe, and Ca, which make up more than 90% of the total chemical composition of the Voëlwater BIFs. The detrital component of the study rocks is negligible. Mn-enrichments characterise all the transitional lithologies towards the interbedded Mn-orebodies, as well as the well-developed, hematitic BIF-unit between the Ongeluk lavas and the lower Mn-horizon. In terms of trace element composition, no significant enrichments or depletions, were encountered, except for some unusually high values of Sr and Ba and Co in carbonate-rich and Mn-rich lithologies respectively. Geochemical comparisons on the basis of major, trace and light rare-earth element composition verified the similarity between the Voëlwater BIF and other major Superior-type BIFs of the world (e.g. Kuruman, Griquatown, Sokoman, Biwabik, Gunflint, Mara-Mamba, Brockman, etc.). The processes that led to the formation of the Voëlwater BIFs may have been very similar to the ones described in various genetic models proposed in recent years. They would have involved a combination of: i. hydrothermal processes related to mid-ocean ridge (MOR) or hot-spot activity that acted as major iron suppliers; ii. storm-mixing in stratified oceans (bottom, anoxic, Fe⁺² reservoir-thermo- pycnocline zone-upper, mixed, SiO₂-saturated layer), largely dictated by seasonal changes and contemporaneous volcanism; iii. periodic, convection-driven upwelling mechanisms acting as major Fe-precipitators; and, iv. organic carbon productivity that was responsible for the anoxic diagenesis of the initial sediment. However, the origin of Fe and Mn for the genesis of the Voëlwater sediments was difficult to explain with typical convection-cell models in active mid-ocean ridges, in contrast to previous hypotheses. Instead, large-scale endogenous processes in the form of magma convection, underplating, differentiation and associated degassing, may have played a critical role in the supply of metals for the formation of large amounts of BIFs in the Precambrian. The present study of the Voëlwater BIF also bears strong implications regarding the metallogenesis of Mn in the Precambrian. The common association of Mn with carbonate-bearing sediments, the transitional character of the Voëlwater BIF towards carbonate lithologies (Mooidraai dolomites) and the critical timing of the deposition of the former in terms of the Precambrian atmospheric-lithospheric- hydrospheric evolution, may be important indicators for the exploration of large Mn-deposits in Precambrian sedimentary basins of the world.