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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Adi??o de geomanta e tecido n?o tecido de polipropileno em cimentos geopolim?ricos de pega r?pida

Freitas, S?nia Maria Bel?sio de Andrade 05 June 2008 (has links)
Made available in DSpace on 2014-12-17T14:57:40Z (GMT). No. of bitstreams: 1 SaniaMBAF.pdf: 3070934 bytes, checksum: 722dda15cd04d9eb4986b09211186f20 (MD5) Previous issue date: 2008-06-05 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / Geopolymers are cementing materials that depict a number of advantages compared to Portland cement. Contrary to the latter, geopolymers are synthesized at room temperature, thus significantly reducing the emission of CO2 to the atmosphere. Moreover, the composition and synthesis reactions can be tailored to adjust the setting time of the material as well as its compressive mechanical strength. It is then possible to produce geopolymeric cements with short setting times and high compressive strength, although relatively brittle. The objective of the present study was to produce and characterize composite materials by reinforcing fastsetting geopolymeric matrixes with polypropylene geosynthetics (geomats and geotextiles) in an attempt to improve the toughness and tensile strength of the cementing material. Geosynthetics have been increasingly used to reinforce engineering structures, providing higher strength and better toughness. In particular, polypropylene nonwoven and geomats depict other attractive properties such as low density, durability, impact absorption and resistance to abrasion. Fast-setting geopolymers were then synthesized and reinforced with polypropylene nonwoven and geomats. The mechanical strength of the materials, reinforced or not, was characterized. The results showed that relatively short setting times and adequate flowing behavior were achieved by adjusting the composition of the geopolymer. In addition, it is possible to improve the fracture resistance of geopolymeric cements by adding polypropylene geosynthetics. The best results were achieved by reinforcing geopolymer with polypropylene TNT / Geopol?meros s?o materiais cimentantes que apresentam uma s?rie de vantagens quando comparados ao cimento Portland. Ao contr?rio deste, a s?ntese de geopol?meros ? feita em temperaturas pr?ximas da ambiente, reduzindo significativamente a emiss?o de CO2 para a atmosfera. Al?m disso, tanto a composi??o quanto ?s condi??es das rea??es de s?ntese podem ser ajustadas para que os materiais resultantes tenham o tempo de pega e as propriedades mec?nicas desejadas. Desta forma, ? poss?vel produzir geopol?meros de pega r?pida e com resist?ncias mec?nicas relativamente altas, embora seu comportamento seja intrinsecamente fr?gil. Nesse contexto, o objetivo do presente trabalho foi estudar a produ??o e as propriedades de comp?sitos produzidos a partir do refor?o de matrizes geopolim?ricas com polipropileno, a fim de reduzir o car?ter fr?gil dos materiais. Para esta finalidade foram empregados geosint?ticos (geot?xteis e geomanta) de polipropileno. Esses materiais t?m sido amplamente utilizados com refor?o estrutural, proporcionando maiores resist?ncias ? tra??o e tenacidade. Em particular, tecidos n?o tecidos e geomantas de polipropileno apresentam outras propriedades atraentes como baixa densidade, durabilidade, absor??o ao impacto e resist?ncia ? abras?o. Geopol?meros de pega r?pida foram sintetizados e refor?ados com tecido n?o tecido e geomanta de polipropileno. A resist?ncia mec?nica dos geopol?meros, com e sem refor?o, foi avaliada. Os resultados mostraram que o ajuste na formula??o do geopol?mero permitiu produzir pastas com tempos de pega relativamente curtos e ao mesmo tempo, mant?-las com a fluidez necess?ria para o recebimento do refor?o. Comprovou-se que a presen?a de geosint?ticos aumentou a energia de fratura do geopol?mero, sendo que os melhores resultados foram alcan?ados com refor?o de TNT

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