This thesis is an electro-acoustic composition done using the techniques of music concrète. Along with the music is a paper that details the historical context of the piece, specific techniques and procedures used by the composer, and a general overview of the compositional form. “Shattered Dreams” is a 12’30” stereo journey through a soundscape where the sounds of cinderblocks and shattered glass abound. All of the original source material for the music was recorded by the composer using a pair of Neumann km184 microphones. These source sounds were then manipulated using Sound Forge 6.0 and Cubase 4. The processes of manipulation were chosen with regard to the original music concrète techniques laid out by Pierre Schaeffer and Pierre Henry at the Club d’Essai studio at Radiodiffusion-Télévision Française in Paris, France. / School of Music

This Ph.D thesis describes an investigation into the operation of the Blue Circle Cauldon Works precalciner vessel. The vessel is part of the cement making plant and it serves the purpose of providing a furnace that is maintained at approximately 900C to calcine the limestone in the raw meal prior to cementation in the kiln. At Cauldon, tyre chips are used as a support fuel. It was the aim of this work to predict the likely behaviour of the gases and particles in the precalciner by using Computational Fluid Dynamics modelling. The commercial code Fluent was used. Investigation of the likely trajectories and combustion behaviour of tyre chips was particularly important. In this way it was hoped that a method of assessing the suitability of alternative waste fuels for incineration in the precalciner might be established. CFD models were constructed that simulated the precalciner with all main reactions and energy exchanges occurring. The first model predicted the behaviour of the precalciner burning coal and the full load of raw meal. Subsequent models assessed the sensitivity of the first model to changes in the boundary conditions. Further models were developed together with experimental work to assess the combustion and aerodynamic behaviour of the tyre chips. Alternative injection points for the tyre chips were investigated. This type of precalciner had not previously been modelled elsewhere. Similar models were found for the operation of the precalciner without tyre chips but the geometrical accuracy of the models was improved in this work due to improvements in commercial CFD code. No similar study of tyre chip combustion has been made elsewhere. CFD was used successfully to model a precalciner vessel with tyre chip and coal combustion and the full raw meal loading simulated. Adjustments can be made quickly to the model to assess minor geometrical alterations. Alternative fuel injection points can be quickly assessed using the model.

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The study of surface and interface structure of thin film devices is becoming increasingly important in industrial applications today. In this thesis, the technique of grazing incidence x-ray scattering (GEXS) is developed and its validity examined for many different materials. In addition, the technique of Born wave analysis introduced by Lagally has been extended, showing that in certain cases surface roughness can be obtained without full simulations of the data. GEXS measurements performed on float glass revealed that the density of the tin and air sides were 2.7 ± 1 and 2.3 ± 1 g/cc respectively across the entire ribbon. For all samples studied a surface layer on the order of a few nanometers was in evidence. When similar measurements were made on container glass it was seen to be layer free. In addition, excellent agreement was found between the roughness deduced from the simulations and the Born wave analysis. In all samples, the surface roughness deduced from the diffuse scatter was less than that from the specular, indicating that a vertical density gradient was present. When x-ray scattering measurements were performed on CVD layers deposited on glass it was noted that two sets of Yoneda wings existed in the diffuse scatter. From these it was concluded that lateral density variations existed in the SnO(_2) layer which were on the order of 0.5mm in diameter. Furthermore, excellent specular simulations were obtained. These indicated that the control of both layer thickness and interface roughness between samples was on the Angstrom level. Specular and diffuse x-ray scattering measurements were performed on Cu/Co multilayers grown on sapphire using a Nb buffer. Here the effect of anomalous dispersion was employed in order to highlight the scattering from the Cu/Co interfaces. From these data Born wave analysis was used to characterise the roughness of the samples. It was found that little change took place for anneals of 45 minutes at temperatures up to 300 C. In addition, it would appear that the measured OMR bore no relationship to the component of uncorrelated roughness within the samples. GIXS measurements perfumed on Cu/Co multilayers grown on Si, using a Cu(_3)Si buffer, revealed an asymmetry in the diffuse scatter, which was attributed to terracing within the layers. Simulations were obtained to the data using a slight modification of the fractal model for several scattering vectors with a single set of parameters. From this, a model of step bunching has been proposed which allows the diffuse scatter to be described using such a fractal surface. Diffuse x-ray scattering studies performed on Al(_2)O(_3), which had been ground in different ways, indicted that the surface density as measured from the Yoneda wings followed the bearing area as measured from optical techniques. Comparisons performed between these results and those from optical microscopy and surface acoustic wave techniques allowed a model to be proposed which was consistent with all the findings. Finally, GIXS measurements were performed on GaAs which had been subjected to various polishing techniques. Simulations revealed that a nanometer scale surface layer was present on all samples. Born wave analysis was successfully applied to the diffuse scatter and the effect of surface layers on the deduced roughness was investigated. In addition, symmetric and asymmetric triple axis diffraction studies revealed that the distribution of strains was independent of the type of polishing used whereas the tilts were not. A model has been proposed in which the surface consists of unstrained mosaic blocks separated by cracks.