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The present work has been concerned with a study of the structure of germanium and silicon dichalcogenide glasses. Initially, the aim of this research was to obtain direct structural evidence of reversible photostructural changes in bulk germanium chalcogenide glasses. However, having confirmed the existence of such changes using EXAFS and neutron scattering techniques, it became obvious that a more comprehensive understanding of the as-quenched, annealed glass structure is required before a valid interpretation of the data can be made; in particular, the extent of medium-range order in these systems is of interest. Although limited to few examples at the moment, the potenital of both structural modelling and NMR studies for solving such problems has been investigated in a variety of inorganic glass systems, and these approaches can now be extended to those glasses exhibiting photostructural changes. Modelling studies of the structure of a-SiSe<SUB>2</SUB> have shown that the total correlation function T(r) is sensitive to different structural features in the generated glass structure. The present studies heavily favour a structure based on chains of edge-sharing (SiSe<SUB>4</SUB>) tetrahedra. A degree of spatial correlation is required between the chains, such as can only be obtained by short lengths of parallel chains 'pinned' by corner-sharing tetrahedra. <SUP>29</SUP>Si NMR studies of vitreous silica have shown that water, incorporated into the SiO<SUB>2</SUB> network as OH, acts as a major source of spin-lattice relaxation in this system. Numerical methods of self-calibration ('phasing') and removal of data truncation and lineshape apodization effects have been investigated, thereby enabling quantitative information concerning the Si-O-Si bond-angle distribution in silica to be obtained. Although these algorithms are presented with reference to NMR spectroscopy, their extension to other branches of spectroscopy is obvious. NMR has also been used to probe defect states in a-Se. <SUP>77</SUP>Se spin-lattice relaxation time data provide evidence of a defect state (perhaps a VAP) in equilibrium with C<SUB>1<SUP>0</SUB></SUP> centres in the glass.

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Although the oxides of the Groups VB and VIB elements (Cr, Mo, Nb, Ta, V, W) have frequently been used as nucleating agents in glass-ceramics, there has been little rigorous study of their effects. It has been suggested that they serve to reduce the interfacial tension between the subcritical nucleus and glass matrix, and thus encourage nucleus growth; this would cause an increase in nucleation rates in both homogeneously and heterogeneously-nucleating systems. There has been no attempt to demonstrate this, however. A test of the effects of these oxides on the steady-state nucleation rate and induction period in homogeneously-nucleating lithium disilicate glass was made by substituting one and two mole-percent of MoO₃, Nb₂O₅, Ta₂O₅, V₂O₅ or WO₃ for SiO₂, and heat-treating the glasses under identical conditions. The "two-step" method was used, consisting of nucleation for variable periods at 733 K and development at 843 K, followed by standard metallographic specimen preparation and inspection by optical reflection light microscopy. Crystal (i.e., nuclei) density was calculated using the stereological method of DeHoff and Rhines. It was shown that this method yielded results independent of crystal size for a given glass, and that the relationship between crystal size and shape supported the hypothesis that lithium disilicate nucleates as a rod-shaped particle, becoming more spherical as growth continues. It was found that MoO₃, Nb₂O₅, Ta₂O₅ and WO₃ substitutions reduced the nucleation rate in the experimental glasses and increased the induction period, the opposite of what was hypothesized. V₂O₅ substitutions yielded a slight nucleation-agent effect. The anti-nucleation agent behavior was associated with increased inhomogeneity in the heat-treated glass samples, resulting from varying cooling rates from the melt through the cross-section. Analysis of the equations linking nucleation rates and induction periods to glass properties suggests that the changes in both the nucleation parameters and the effect on the results of thermal inhomogeneity were primarily linked to higher viscosities in the substituted glasses.

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