A method is described which enables the user to determine the rheological parameters of a fast settling slurry using conventional viscometric measuring equipment. The effect of concentration, temperature and pH on these parameters is investigated. The results agree with those obtained by previous workers using different viscometers. However, this method allows a more detailed characterization of all the properties. A literature survey was carried out and two semi-empirical correlations were found, which allow the effect of either concentration, temperature or pH on the rheological parameters to be investigated.

No description available.

No abstract available. / Thesis (M.Sc.Eng.)-University of Durban-Westville, 2000.

A dissertation submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Master of Science, 2017 / Six different plant species that grow in a natural wetland impacted by old gold mining and other industrial activities were randomly selected with surface sediments. These included: Cyperus eragrostis (Nutgrass), Datura stramonium (Jimson weed), Melilotus alba (White sweetclover), Panicum coloratum (Blue panicgrass), Persicaria lapathifolia (Pale smartweed) and Phragmites australis (Common reed). These were used to investigate the levels of mercury in the wet and dry seasons, as well as to evaluate which of the species could be utilized for the remediation of mercury contaminated areas. The results obtained indicated that metal contamination could be determined from sediments and plant tissues. The pH values of the sediment samples were mostly neutral to slightly acidic and the redox potential was high in the wet season. On the other hand the dry season was characterised by very acidic and moderately oxidizing conditions. In summer all six plant species had higher concentration of HgT in sediments, whereas in winter the levels of HgT were elevated in the aerial tissues of the plants. The mercury accumulation patterns differed according to individual plant species and seasonality. Seasonal differences were significant but generally the MeHg concentrations in the wet season were higher in both surface sediments and plant tissues. Mercury methylation differed between species but concentration of MeHg was in general higher in plants with high concentration of mercury in sediments. The conversion of bioavailable HgT seemed more pronounced in tissues of the plants sampled in the wet season unlike those sampled in the dry season. Generally bioaccumulation factors were less than 1 in both the wet and dry seasons for all the plant species indicating that Hg was mainly retained in sediments. The translocation factor values were greater than 1 meaning metals were accumulated fundamentally in aboveground tissues for the plants D. stramonium, P. lapathifolia, P. coloratum and C. eragrostis in both the wet and dry seasons. The small bioaccumulation factors combined with translocation factor values greater than 1 were an indication that mercury present in the sediments was not the only source of mercury for the plant species growing in a contaminated environment. For P. australis the translocation of mercury was heavily influenced by seasonality, however this was not the case with M. alba. All the selected plant species demonstrated the capacity to grow in a heavily contaminated area, where P. australis and M. alba seemed to have developed an exclusion strategy to deal with toxic heavy metals therefore suitable for phytostabilisation. D. stramonium, P. lapathifolia, P. coloratum and C. eragrostis on the other hand exhibited characteristics of plants that can be successfully used for phytoextraction and phytovolatilization. / XL2018

A Thesis submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Doctor of Philosophy 2015. / Gold mining in South Africa has been the backbone of the economy for many years. With it came economic well-being, the growth and development of satellite towns, cities and metropolitan cities, e.g. Johannesburg-a place of gold. Unfortunately, it also came with adverse effects, most of which are now evident, after a century of mining, with little or no regard for pollution prevention or any form of remediation. Of interest, in this study, is the presence of tailings storage facilities (TSFs) found within the residential areas, in close proximity to commercial district and industry, having been built around them. Currently, some 270 TSFs lie dormant, pregnant with vast number of toxic heavy metals from the initially low efficient but selective gold processing techniques. This led to the deposition of the sand dumps, with high sulphur, iron, chromium, cadmium, arsenic, and mercury amongst other toxic metals. Exposure to oxygen, and water, the pyrites were oxidized and formed acid mine drainage (AMD), which resulted in the leaching out all toxic heavy metals into ground water and surface water causing serious water pollution and environmental degradation. Due to the low efficient gold processing technique, some gold amount was discarded together with the tailings materials. The reprocessing of these dumps led to the generation of dust, which is easily distributed over large areas of land. The unrehabilitated, semi-rehabilitated, and the abandoned TSFs contributed to all forms of pollution, majorly, windblown dust from unprotected tops and sides, AMD leaching toxic heavy metals. In this study, mercury, one of the most toxic elements found within the vast TSFs was determined. This was carried out as part of a larger environmental impact assessment on the effects and scale of pollution from the gold mining in the Witwatersrand. The study area consisted of the greater Johannesburg area, covering commercial business district (CBD), the industrial areas (Aeroton, City Deep, Germiston, Selby, Springs), and the residential areas (Alberton, Boksburg, Centurion, Germiston, Greenside, Sandton, Springs). Dust samples were collected from paved surfaces in the streets, and accessible buildings, were sieved into three sieved into three fractions (PM100, PM50, PM25), and most of the work focused on the smallest size fraction (PM25) in order to study impact of inhalable and respirable dust. Three sequential extraction procedures (modified BCR-the European Community Bureau of Reference, selective sequential procedure (SSE), and novel sequential extraction procedure (n-SEP)) were applied for partitioning and evaluating the mobility, availability and persistence of mercury in urban dusts. Bioavailability of mercury was assessed by leaching dust with artificial gastric and lung fluids which mimicked body conditions. Contamination levels were assessed based on the enrichment factor (EF), contamination factor (Cf) and geoaccumulation index (Igeo) were calculated to further assess the environmental risk and provide a preliminary estimate of the main sources of mercury in street dust. Non-carcinogenic effects and carcinogenic effects due to exposure to urban street dusts were assessed for both children and adults. The total mercury (HgTOT) ranged from 269 to 1350 μg kg-1. In the PM25 size fraction, mercury exhibited the following decreasing order of HgTOT: industrial area > CBD > residential area. This order shows that the HgTOT concentration in the street dust decreased with increased distance from the TSFs. The highlight was that the highest HgTOT was reported in industrial areas next to the TSFs, tailings reprocessing areas, and tailings footprints. Furthermore, in residential areas grossly affected by TSFs and tailings reprocessing, reported high HgTOT values similar to those reported for industrial samples. These results indicated that the presence of TSFs were largely responsible for the mercury found in the dust. The results from the characterization of the dust showed a large concentration of fine particulate matter, with the characteristically high quartz (74 – 98 wt. %), and minor minerals phases such as chloritoid, chlorite, K-feldspar, jarosite, mica, muscovite, pyrite, and pyrophyllite, all below 10 wt. %. These have been known to enrich trace metals, hence a high concentration of mercury. The close proximity of the tailings to the communities led to the determination of bioavailability of mercury from dust. The bioaccessible Hg extracted by lung fluid (up to 3% of HgTOT) was higher than that of gastric fluid (up to 1% of HgTOT) and was related to the mobile pool of Hg in dust. This suggests that human exposure to Hg in dust via inhalation is greater than that via the gastric tract. These values were very similar to the values obtained from water soluble phase in the sequential extraction procedure (average 1.4% of HgTOT). This indicated that these fluids were able to extract the most bioavailable fraction of Hg, which is responsible for most of the transformation reactions involving mercury. Contamination assessment factor was carried out to classify the pollution levels and indicate whether they are from natural or anthropogenic sources. Based on the EF, Cf, and Igeo, 70, 82, and 84% of the street dust samples were classified as heavily enriched, very highly contaminated, and strongly polluted by mercury, respectively, indicating that they are of anthropogenic origin. The human health risk model was useful in identifying the areas of health risks from exposure to mercury pollution. It showed that children were more vulnerable than adults when exposed to mercury in dust via ingestion. The cancer risk for exposure to As, Cd, and Cr by both children and adults was significantly high for oral ingestion of dust. Cr (VI) was the highest contributor followed by As and lastly Cd. For inhalation pathway, the possibility of developing cancer after a lifetime exposure was low and below the acceptable limits (10-6).

This report investigates the application of digital computer simulation models to the analysis and optimization of complex mine water reticulation systems- A simulation program is developed and documented, Guidelines in the construction and use of mine water models are applied in a case study of water quality and quantity aspects of Unisel Gold Mine.

Thesis (Professional Degree)--University of Missouri, School of Mines and Metallurgy, 1922. / The entire thesis text is included in file. Typescript. Illustrated by author. Title from title screen of thesis/dissertation PDF file (viewed February 23, 2010)

No description available.

Thesis (M.Eng.Sc.)--University of Western Australia, 2004.

Thesis (M. Sc.)--University of Alberta, 1997. / Submitted to the Faculty of Graduate Studies and Research in partial fulfilment of the requirements for the degree of Master of Science, Department of Earth and Atmospheric Sciences. Also available online.