published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy

M.Sc. (Geology) / Please refer to full text to view abstract

A Dissertation Submitted to the Faculty of Science University of the Witwatersrand, Johannesburg for the Degree of Master of Science. / Beatrix Mine is located 35 km south of the city of Welkom in the Welkom Goldfield and as such forms the most southerly of the Witwatersrand-type gold mines. The Beatrix Reef overlies an angular unconformity at the base of the Turffontein Subgroup, Central Rand Group Significant, southerly truncation of over 600m of the Johannesburg Subgroup, and the lower formations of the Turffontein Subgroup, occur at this unconformity in the Beatrix area.. characteristics of the Beatrix Reef conglomerates such as the morphology, sorting and packing of clasts, and the arrangement. of the sediments in various sedimentary structures and facies/ sequences, suggest deposition within a braided fluvial environment on a coarse-grained braid-delta. Sedimentation occurred after the fluvial degradation of previously deposited units, and culminated in a marine/ lacustrine transgression. Low aggradation rates led to significant reworking and concentration of placer materials in a depositional model probably typical of ventral Rand Group placer formation. Heavy minerals (and gold) are concentrated in response to hydraulic conditions and show a close association with large and small scale sedimentary features. Transport directions deduced from the sedimentary structures suggest a north to south dispersal of sediment down the braid plain. Sedimentary structures in the finer rained units at the base of the Eldorado Formation are indicative of tidal influences and document the marine transgression as the culmination of the degradational events. The lithologys sedimentary structures and facies sequences of the coarser grained units of the Eldorado Formation well as the overall coarsening upward of these lithologies indicate sedimentation in a braided , fluvial system, on an alluvial fan prograding across the preyiously deposited units" Sedimentary ~tructures and lithologic variations confirm a continued north to south dispersal pattern. In the area south of the Sand over the period of fluvial degradation and transgression after the formation of the Beatrix: Reef was followed by more rapidly aggreding fluvial progradation due to a major change in base level in response to compressional tectonics and uplift along the Western Margin Structure. Only in post-Central Rand Group times did relaxation and extensional tectonics result in the outpourings of the Ventersdorp .supergroup lavas and the cessation of active Witwatersrand Supergroup sedimentation. / Andrew Chakane 2018

[Formulae and special characters can only be approximated here. Please see the pdf version of the abstract for an accurate reproduction.] The formation of world-class Archean orogenic gold deposits in the Eastern Goldfields Province of Western Australia was the result of a critical combination of physical and chemical processes that modified a single and widespread ore-fluid along fluid pathways and at the sites of gold deposition. Increased gold endowment in these deposits is associated with efficient regional-scale fluid focusing mechanisms and the influence of multiple ore-depositional processes at the deposit-scale. Measurement of the complexity of geologic features, as displayed in high-quality geologic maps of uniform data density, can be used to highlight areas that influence regional-scale hydrothermal fluid flow. Useful measurements of geological complexity include fractal dimensions of map patterns, density and orientation of faults and lithologic contacts, and proportions of rock types. Fractal dimensions of map patterns of lithologic contacts and faults highlight complexity gradients. Steep complexity gradients, between domains of high and low fractal dimensions within a greenstone belt, correspond to district-scale regions that have the potential to focus the flow of large volumes of hydrothermal fluid, which is critical for the formation of significant orogenic gold mineralization. Steep complexity gradients commonly occur in greenstone belts where thick sedimentary units overly more complex patterns of lithologic contacts, associated with mafic intrusive and mafic volcanic units. The sedimentary units in these areas potentially acted as seals to the hydrothermal Mineral Systems, which resulted in fluid-pressure gradients and increased fluid flow. The largest gold deposits in the Kalgoorlie Terrane and the Laverton Tectonic Zone occur at steep complexity gradients adjacent to thick sedimentary units, indicating the significance of these structural settings to gold endowment. Complexity gradients, as displayed in surface map patterns, are an indication of three-dimensional connectivity along fluid pathways, between fluid source areas and deposit locations. Systematic changes in the orientation of crustal-scale shear zones are also significant and measurable map features. The largest gold deposits along the Bardoc Tectonic Zone and Boulder-Lefroy Shear Zone, in the Eastern Goldfields Province, occur where there are counter-clockwise changes in shear zone orientation, compared to the average orientation of the shear zone along its entire length. Sinistral movement along these shear zones resulted in the formation of district-scale dilational jogs and focused hydrothermal fluid-flow at the Golden Mile, New Celebration and Victory-Defiance deposits. Faults and lithologic contacts are the dominant fluid pathways in orogenic gold Mineral Systems, and measurements of the density of faults and contacts are also a method of quantifying the complexity of geologic map patterns on high-quality maps. Significantly higher densities of pathways in areas surrounding larger gold deposits are measurable within 20- and 5-kilometer search radii around them. Large variations in the sulfur isotopic composition of ore-related pyrites in orogenic gold deposits in the Eastern Goldfields Province are the result of different golddepositional mechanisms and the in-situ oxidation of a primary ore fluid in specific structural settings. Phase separation and wall-rock carbonation are potentially the most common mechanisms of ore-fluid oxidation and gold precipitation. The influence of multiple gold-depositional mechanisms increases the potential for significant ore-fluid oxidation, and more importantly, provides an effective means of increasing gold endowment. This explains the occurrence of negative δ34S values in ore-related pyrites in some world-class orogenic gold deposits. Sulfur isotopic compositions alone cannot uniquely define potential gold endowment. However, in combination with structural, hydrothermal alteration and fluid inclusion studies that also seek to identify multiple ore-forming processes, they can be a useful indicator. The structural setting of a deposit is also a potentially important factor controlling ore-fluid oxidation and the distribution of δ34S values in ore-related pyrites. At Victory-Defiance, the occurrence of negative δ34S(py) values in gently-dipping dilational structures, compared to more positive δ34S(py) values in steeply-dipping compressional structures, is potentially associated with different gold-depositional mechanisms that developed as a result of fluid-pressure fluctuations during different stages of the fault-valve cycle. During the pre-failure stage, when fluids are discharging from faults, fluid-rock interaction is the dominant gold-depositional mechanism. Phase separation and back-mixing of modified ore-fluid components are dominant during and immediately after faulting. Under appropriate conditions, any, or all, of these three mechanisms can oxidize orogenic gold fluids and cause gold deposition. The influence of multiple gold-depositional mechanisms during fault-valve cycles at dilational jogs, where fluid pressure fluctuations are interpreted to be most severe, can potentially explain both the large gold endowment of the giant to world-class Golden Mile, New Celebration and Victory-Defiance deposits along the Boulder-Lefroy Shear Zone, and the presence of gold-related pyrites with negative δ34S values in these deposits. This study highlights the interplay that exists between physical and chemical processes in orogenic gold Mineral Systems, during the transport of ore fluids in pathways from original fluid reservoirs to deposit sites. Potentially, a single and widespread orogenic ore-fluid could become oxidized, and lead to the formation of ore-related sulfides with variable sulfur isotopic compositions, depending on the nature and orientation of major fluid pathways, the nature of wall-rocks through which it circulates, and the precise ore-depositional processes that develop during fault-valve cycles.

Over the last two decades, gold occurrences in the Palaeoproterozoic Pine Creek Orogen (PCO) have been cited as type-examples of high-temperature contact-metamorphic or thermal-aureole deposits associated with granitoid magmatism. Furthermore, spatial relationships between these gold occurrences and the granitoids have led to inclusion of these deposits in the intrusion-related gold deposit group. Research on the characteristics, distribution and timing of these gold deposits tests these classifications and supports an alternative interpretation. The deposits display many similarities to well-described ‘turbidite-hosted’ orogenic gold deposits described from several Palaeozoic orogens. As in most ‘turbidite-hosted’ orogenic deposits, the gold mineralisation is dominantly epigenetic, sediment-hosted (typically greywacke and siltstone) and fold-controlled. Most gold is hosted by concordant or discordant veins, with limited alteration halos in host rocks, except where they occur in silicate-facies BIF or other Fe-rich rocks. The domal culminations of major doubly-plunging anticlines, and/or fold-limb thrust-faults, are important structural controls at the camp- and deposit-scales. Many deposits are sited in parts of the lithostratigraphy where there is significant competency and/or chemical contrast between units or sequences. In particular, the complex interdigitated stratigraphy of euxinic and transitional high-energy sedimentary rocks of the c.1900-1880Ma South Alligator Group is important for the localisation of gold deposits. The distribution of deposits is influenced further by the location and shape of granitoids and their associated contact-metamorphic aureole. Approximately 90% of gold deposits lie within the ∼2.5km wide contact-aureole, and most of these are concentrated in, and just beyond, the biotite-albite-epidote zone (0.5-1.0km from granitoid), with few deposits located in the inner hornblende-hornfels zone. At the deposit scale, gold is commonly associated with arsenopyrite-loellengite and pyrite, native-Bi and Bi-bearing minerals, and is confined to a variety of extensional quartz-sulphide ± carbonate veins. Such veins formed typically at 180-320°?C and ∼1kbar from low- to moderate salinity, two-phase aqueous fluids. Isotopic studies of the deposits are equivocal in terms of the source of hydrothermal fluid. Most δD and δ18O values fall within the range defined for contact-metamorphic and magmatic fluids, and sulphur isotopes indicate that the fluids are within the range of most regional sources. Significantly, lead isotope ratios show that the goldbearing fluid does not have a felsic magmatic-source signature, but instead suggest a homogenous regional-scale lead source. Excluding a few outliers, the relative uniformity of deposit characteristics, including host rocks, structural style, alteration, sulphide paragenesis and fluid P-T-X conditions, suggests that most deposits represent a continuum of broadly coeval mineralisation that formed under similar geological conditions

No description available.

The Kalahari Goldridge mine is located within the Archaean Kraaipan Greenstone Belt about 60 km SW of Mafikeng in the Northwestern Province, South Africa. Several gold deposits are located within approximately north - south-striking banded iron-formation (BIF). Current opencast mining operations are focused on the largest of these (D Zone). The orebody is stratabound and hosted primarily in the BIF, which consists of alternating chert and magnetite-chloritestilpnomelane-sulphide-carbonate bands ranging from mm to cm scale. The ore body varies in thickness from 15 to 45 m along a strike length of about 1.5 km. The BlF is sandwiched between a sericite-carbonate-chlorite schist at the immediate footwall and carbonaceous meta-pelites in the hanging-wall. Further west in the footwall, the schists are underlain by mafic meta-volcanic amphibolite. Overlying the hanging-wall carbonaceous metapeiites are schist units and meta-greywackes that become increasingly conglomeratic up the stratigraphy. Stilpnomelane-, chlorite- and minnesotaite-bearing assemblages in the BlFs indicate metamorphic temperatures of 300 - 450°C and pressures of less than 5 kbars. The BIF generally strikes approximately 3400 and dips from 60 to 75°E. Brittle-ductile deformation is evidenced by small-scale isoclinal folds, brecciation, extension fractures and boudinaging of cherty BIF units. Fold axial planes are sub-parallel to the foliation orientation with sub-vertical plunges parallel to prominent rodding and mineral lineation in the footwall. Gold mineralization at the Kalahari Goldridge deposit is associated with two generations of subhorizontal quartz-carbonate veins dips approximately 20 to 40°W. The first generation consists of ladder vein sets (Group lIA) preferentially developed in Fe-rich meso bands, whilst the second generation consists of large quartz-carbonate veins (Group lIB), which crosscut the entire ore body extending into the footwall and hanging-wall in places. Major structures that control the ore body are related to meso-scale isoclinal folds with fold axes subparallel to mineral elongation lineations, which plunge approximately 067°E. These linear structures form orthogonal orientation with the plane of the mineralized shallowdipping veins indicating stretching and development of fluid - focusing conduits. A second-order controlling feature corresponds to the intersection of the mineralized veins and foliation planes of host rock, plunging approximately 008°N and trending 341°. G0ld is closely associated with sulphides, mainly pyrite and pyrrhotite and to a lesser extent with bismuth tellurides, and carbonate gangue. The ore fluid responsible for the gold deposition is in the C-O-H system with increased CH₄ contents attributed to localized hydrolysis reaction between interbedded carbonaceous sediment and ore fluid. The fluid is characterized by significant C0₂ contents and low salinities below 7.0 wt % NaCl equivalent (averages of 3.5 and 3.0 wt % NaCl equivalent for the first and second episodes of the mineralization respectively) . Calculated values of f0₂. ranging from 10⁻²⁹·⁹⁸ to 10⁻³²·⁹⁶ bars, bracket the C0₂-CH₄ and pyrite-pyrrhotite-magnetite buffer boundaries and reveal the reducing nature of the ore fluid at deposition. Calculated total sulphur content in the ore fluid (mΣs), ranges from 0.011 to 0.018M and is consistent with the range (10⁻³·⁵ to 10⁻¹M) reported for subamphibolite facies ore fluids. The close association of sulphides with the Au and nature of the fluid also give credence that the Au was carried in solution by the Au(HS)₂ - complex. Extensive epigenetic replacement of magnetite and chlorite in BIF and other meta-pelitic sediments in the deposit by sulphides and carbonates, both on meso scopic and microscopic scales gives evidence of an interaction by a CO₂- and H₂S-bearing fluid with the Fe-rich host rocks in the deposit. This facilitated Au precipitation due to changes in the physico-chemical conditions of the ore fluid such as a decrease in the mΣs and pH leading to the destabilization of the reduced sulphur complexes. Local gradients in f0₂ may account for gold precipitation in places within carbonaceous sediments. The fineness of the gold grams (1000*Au/(Au + Ag) ranges from 823 to 921. This compares favourably with the fineness reported for some Archaean BIFhosced deposits (851 - 970). Mass balance transfer calculations indicate that major chemical changes associated with the hydrothermal alteration of BIF include enrichment of Au, Ag, Bi, Te, volatiles (S and CO₂), MgO, Ba, K and Rb but significant depletion of SiO₂ and minor losses of Fe₂O₃. In addition, anomalous enrichment of Sc (average, 1247%) suggests its possible use as an exploration tool in the ferruginous sediments in the Kraaipan greenstone terrane. Evidence from light stable isotopes and fluid inclusions suggests that the mineralized veins crystallized from a single homogeneous fluid source during the two episodes of mineralization under the similar physicochemical conditions. Deposition occurred at temperatures rangmg from 350 to 400°C and fluid pressures ranging from 0.7 to 2.0kbars. Stable isotope constraints indicate the following range for the hydrothermal fluid; θ¹⁸H₂O = 6.65 to 10.48%0, 8¹³CΣc = -6.0 to -8.0 %0 and 8³⁴SΣs = + 1.69 to + 4.0%0 . These data do not offer conclusive evidence for the source of fluid associated with the mineralization at the Kalahari Goldridge deposit as they overlap the range prescribed for fluid derived from devolatization of deep-seated volcano-sedimentary piles near the brittle-ductile transition in greenstone belts during prograde metamorphism, and magmatic hydrothermal fluids. / KMBT_363 / Adobe Acrobat 9.54 Paper Capture Plug-in

[Truncated abstract] The Tintina Gold Province (TGP) comprises numerous (<15) gold belts and districts throughout interior Alaska and Yukon that are associated with Cretaceous plutonic rocks. With a gold endowment of ∼70Moz, most districts are defined by their placer gold contributions, which comprise greater than 30 Moz, but four districts have experience significant increases in gold exploration with notable discoveries at Fort Knox (5.4 Moz), Donlin Creek (12.3 Moz), Pogo (5.8 Moz), True North (0.79 Moz), and Brewery Creek (0.85 Moz). All significant TGP gold deposits are spatially and temporally related to reduced (ilmenite-series) and radiogenic Cretaceous intrusive rocks that intrude (meta-) sedimentary strata. The similar characteristics that these deposits share are the foundation for the development of a reduced intrusion-related gold deposit model. Associated gold deposits have a wide variety of geological and geochemical features and are categorized as intrusion-centered (includes intrusion-hosted, skarns and replacements), shear-related, and epizonal. The TGP is characterized by vast, remote under-explored areas, unglaciated regions with variable oxidation depths and discontinuous permafrost, which, in combination with a still-evolving geological model, create significant exploration challenges. Twenty-five Early and mid-Cretaceous (145-90 Ma) plutonic suites and belts are defined across Alaska and Yukon on the basis of lithological, geochemical, isotopic, and geochronometric similarities. These features, when combined with aeromagnetic characteristics, magnetic susceptibility measurements, and whole-rock ferric:ferrous ratios define the distribution of magnetite- and ilmenite-series plutonic belts. Magnetite-series plutonic belts are dominantly associated with the older parts of the plutonic episode and comprise subduction-generated metaluminous plutons that are distributed preferentially in the more seaward localities dominated by primitive tectonic elements. Ilmenite-series plutonic belts comprise slightly-younger, slightly-peraluminous plutons in more landward localities in pericratonic to continental margin settings. They were likely initiated in response to crustal thickening following terrane collision. The youngest plutonic belt forms a small, but significant, magnetite-series belt in the farthest inboard position, associated with alkalic plutons that were emplaced during weak extension. Intrusion-related metallogenic provinces with distinctive metal associations are distributed, largely in accord with classical redox-sensitive granite-series. Copper, Au and Fe mineralisation are associated with magnetite-series plutons and tungsten mineralisation associated with ilmenite-series plutons. However, there are some notable deviations from expected associations, as intrusion-related Ag-Pb-Zn deposits are few, and significant tin mineralisation is rare. Most significantly, many gold deposits and occurrences are associated with ilmenite-series plutons which form the basis for the reduced intrusion-related gold deposit model

A review of Archean granite-greenstone terranes, orogenic gold deposits, the Slave Province and modern exploration tools, techniques and methods was conducted to identify prospective areas in the Yellowknife domain for hosting orogenic gold deposits and illustrate the best exploration methods for delineating this deposit type. This study identifies Archean granite-greenstone terranes as economically important hosts to quartz-carbonate vein-hosted orogenic gold deposits. These deposits occur at convergent plate margins, but can also be related to local extensional tectonics within a convergent setting. Heat generated from tectonic processes can trigger hydrothermal fluid movement along first-order faults and shear zones. Precipitation of gold-bearing quartz-carbonate veins from the hydrothermal fluids occurs in second- and third-order faults and shear zones related to the first-order structures. This study also identifies the Archean Slave Province in northern Canada as a well-endowed craton with numerous orogenic gold deposits, diamondiferous kimberlites, VMS deposits and several other mineralization styles. In particular, three greenstone belts (Yellowknife, Cameron River and Beaulieu River) associated with likely first-order structures are comprised of prospective rocks for hosting orogenic gold and VMS mineralization. The Yellowknife greenstone belt hosts the past-producing and former world-class Con and Giant orogenic gold deposits, but has been little explored with modern exploration techniques. The Cameron River and Beaulieu River greenstone belts host numerous base and precious metal VMS and BIF-hosted orogenic gold prospects and deposits, indicating mineralization is present. There is considerable potential for significant discoveries to be made using modern exploration techniques in the greenstone belts; however, exploration in the region has been hindered over the past decade by ongoing political negotiations. Once the political negotiations are finalized, application of modern exploration methods and techniques in the prospective greenstone belts should be carried out. Regional scale methodologies should be applied to generate targets using predictive modelling, implicit 3D modelling, 3D geochemistry and exploration targeting so decisions defining a businesses strategy for ground acquisition of high priority targets are made using quantitative analysis. Once ground is acquired, field-based exploration for orogenic gold and VMS deposits should include geological mapping with a focus on structural geology, geochemical sampling and airborne magnetic, radiometric and EM geophysical surveys. Prior to reconnaissance drilling, integration of all data layers and interpretation within a common 3D earth model should be conducted. Following successful reconnaissance drilling, definition drilling along strike and down dip of intersected mineralization, combined with borehole geophysics, should be carried out to delineate the extent of mineralization.

The Koulekoun Gold project is the most important prospect of Avocet Mining plc. It is one of the projects within the TriK-block in Guinea (West Africa) for which an exploration permit has been granted. The Koulekoun deposit is located within the Siguiri basin of Birimian age in the Eastern Guinea region; where most Guinea’s gold mines are situated. The present study involves the investigation of structural elements (S₀, S₁, S₂, intrusive contacts, faults and veins) from selected drill cores from drill sections that intersect the Koulekoun orebody in four parts of the deposit; characterizes the principal orientations of measured structures and determines their relationships using stereonet; in order to predict important intersections to focus on in exploration programs within the TriK-block and suggests a possible structural model of the Koulekoun deposit. Raw data used for the present research was collected from half-core samples due to the absence of surface outcrop from which direct measurements could have been made. Measured data were interpreted using stereographic projection. Often no preferred orientations of structural elements exist in the area, suggesting a complex structural situation, particularly with regard to hydrothermal vein attitudes. Thus, it has been illustrated from structural data analysis and S₀ data 3d interpolation of the four sub-structural domains (North-East, North-West, Central and South) that NE-SW structures (S₂, intrusive contact, fault and vein) have controlled the occurrency of gold mineralization in the Koulekoun deposit area. Geometrical relationships between structure main cluster orientation from stereonet analysis show the majority of S₀ moderately E-dipping; intrusive contacts dip at moderate angle to the SE in all zones, except in the North-East zone where they are sub-vertical and SE-dipping. Fault planes show variable orientation of NE-SW, NW-SE and E-W, and steeply SE-dipping. Vein planes correspond to fault systems and show high variability in their orientation with numerous orders of vein direction in each domain. The cross-cutting relationships suggest two principal generations of faults: the NE-SW fault (F1) and the NW-SE fault (F2). These two fault systems and their associated vein intersection areas preferably define the ore shoot zones within the Koulekoun deposit. The proposed structural model of the Koulekoun deposit suggests the intersection and interference of major NW-SE and minor NE-SW structures. The interference of folds formed basin-dome structures with oval shape geometries striking NW-SE and that dominantly occur in North-East, North-West and Central zones. The South Zone is characterized by NE-SW gently plunging and moderately inclined folds with NW-SE striking axial surface. Gold mineralization occurs at the edges of basin-dome structures in North-East, North-West and Central zones. Mineralized porphyry intrusions are likely located within the axial surface of the South zone folds and extend toward the Central zone. The proposed model is compliant with the earlier model of the Koulekoun deposit presented by Tenova (2013); Fahey et al. (2013) describing the Koulekoun deposit as an auriferous NE-SW trending fault zone, intersecting a major NW-striking and steeply E-dipping porphyry units. The model also fits within the regional structural context suggested by Lahondere et al. (1999a) related to the E-W vein structures attributed to NW-SE fractures and to the conjugated fault of NE-SW direction. Comparatively to the three industrial gold deposits (Siguiri, Lero, Kiniero) being currently mined in the Siguiri Basin, and defined as mesothermal vein and lode mineralization hosted in Birimian meta-sedimentary rocks (Lalande, 2005), the Koulekoun gold deposit appears to be a porphyry hosted orogenic disseminated style mineralization system (Fahey et al., 2013). Although, similarities between the Koulekoun gold deposit and these three industrial deposits (Siguiri, Lero, Kiniero) constitute of the intensive extends of the weathering profile and at some stages, by the existence of numerous ring-shaped and curved lineaments enhanced by drag folding (Lero deposit for instance). It is therefore recommended that targets selection around the Koulekoun deposit and within the TriK-block for further exploration programs be concentrated along NW-SE structures, in objective to determine possible intersection zones with NE-SW structures.