A thesis submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, for the degree of Doctor of Philosophy / This thesis provides a comprehensive account of the geology of the Archaean granitoid-greenstone terrane centred around Three Sisters in the northeastern sector of the Barberton Mountain Land. The supracrustal succession in the region comprises a diverse variety of altered volcanic and sedimentary rock types that have been correlated with the principal lithostratigraphic units of the Barberton greenstone belt (BGB) as fellows: 1) schistose basic and ultrabasic lithologies correlated with the Theespruit Formation of the Gnverwacht Group are mainly developed in a narrow unit fringing the northern margin of the BGB; 2) ferruginous shale greywacke - banded iron-formation assemblages correlated with the Jheba and Belvue Road Formations constitute the dominant Fig Tree Group imks in the region. A sec «ence or silicic » .-stavolcaniclastic rocks, now altered to a variety of micaceous schists, occurs west, north ar.a northeast of Three Sisters. Viljoen and Viljoen (1970) cc rrela ted these schists ith the Theespruit Formation. In this study, the schists have been assigned'to a new lithostratigraphic unit, referred to as the Bien Venue Formation, which forms the uppermost formation of the Fig Tree Group in the northeastern part of the BGB. Isotopic studies on zircons indicate that the schists have an age of 3256 ± Ma, which is some 200 Ma younger titan the most recent age estimates for the lower portions of the Gnverwacht Group. Chemically, the silicic schists resemble calc-alkaline rocks found in modem arcs, suggesting that the Bien Venue Formation represents a period of arc-like volcanism; and 3) conglomeratic and quartzitic rocks constitute the dominant lithologies within the Moodies Group, which uncoriorroably or paraconformably overlies lithologies of the Fig Tree and Onverwacht Groups. North of the BGB is a complex suite of granitoid rocks, previously investigated by Robb et al. (1983) who defined a large (—60 kn ng and —6 km wide), elongate plutonic body of tonalitic-to-trondhjemitic composition known as the Stentor pluton. It was suggested that this pluton is correlatable with the irondhjemite gneiss plutons that intrude the southwestern parts of the BGB. Field evidence indicates, however, that the Stentor pluton forms a much smaller (* .14 km long and ~ 4 km wide) ovoid body located immediately north of the village of Louw’s Creek. Furthermore, the pluton consists of equigranular-textured graiodiorite-adamcllite, totally unlike any of the trondhjemite gneisses. In terms of texture, mineralogy and chemical composition, the Stentor pluton closely resembles the Hebron and Berlin plutohs which constitute a phase of the Nelspruit batholith. Thus, it is concluded that the Stentor pluton also forms an integral part of the batholith. Three deformation phases have been identified. The regional event affected all stratigraphic units in response to a northerly oriented compressions! stress and gave rise to east-northeasterly trending, tight-.« 5soclinal, upright and north-verging folds that are bounded by southward-dipping longitudinal reverse faults. The regional deformation occurred both prior and subsequent to the emplacement of the Stentor pluton at circa 3100 Ma. Deformation associated with the diapiric intrusion of the Stentor pluton into the greenstone assemblage during the regional deformation pnase, led to the formation of large-scale folds that have modified earlier formed structures. The final deformation episode is manifested by the presence of nortnwest- to northeast-striking, oblique-slip normal faults that exhibit both left- and right-lateral strike-slip components. / AC 2018

A thesis submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, for the degree of Doctor of Philosophy / This thesis provides a comprehensive account of the geology of the Archaean granitoid-greenstone terrane centred around Three Sisters in the northeastern sector of the Barberton Mountain Land. The supracrustal succession in the region comprises a diverse variety of altered volcanic and sedimentary rock types that have been correlated with the principal lithostratigraphic units of the Barberton greenstone belt (BGB) as fellows: 1) schistose basic and ultrabasic lithologies correlated with the Theespruit Formation of the Gnverwacht Group are mainly developed in a narrow unit fringing the northern margin of the BGB; 2) ferruginous shale greywacke - banded iron-formation assemblages correlated with the Jheba and Belvue Road Formations constitute the dominant Fig Tree Group imks in the region. A sec «ence or silicic » .-stavolcaniclastic rocks, now altered to a variety of micaceous schists, occurs west, north ar.a northeast of Three Sisters. Viljoen and Viljoen (1970) cc rrela ted these schists ith the Theespruit Formation. In this study, the schists have been assigned'to a new lithostratigraphic unit, referred to as the Bien Venue Formation, which forms the uppermost formation of the Fig Tree Group in the northeastern part of the BGB. Isotopic studies on zircons indicate that the schists have an age of 3256 ± Ma, which is some 200 Ma younger titan the most recent age estimates for the lower portions of the Gnverwacht Group. Chemically, the silicic schists resemble calc-alkaline rocks found in modem arcs, suggesting that the Bien Venue Formation represents a period of arc-like volcanism; and 3) conglomeratic and quartzitic rocks constitute the dominant lithologies within the Moodies Group, which uncoriorroably or paraconformably overlies lithologies of the Fig Tree and Onverwacht Groups. North of the BGB is a complex suite of granitoid rocks, previously investigated by Robb et al. (1983) who defined a large (—60 kn ng and —6 km wide), elongate plutonic body of tonalitic-to-trondhjemitic composition known as the Stentor pluton. It was suggested that this pluton is correlatable with the irondhjemite gneiss plutons that intrude the southwestern parts of the BGB. Field evidence indicates, however, that the Stentor pluton forms a much smaller (* .14 km long and ~ 4 km wide) ovoid body located immediately north of the village of Louw’s Creek. Furthermore, the pluton consists of equigranular-textured graiodiorite-adamcllite, totally unlike any of the trondhjemite gneisses. In terms of texture, mineralogy and chemical composition, the Stentor pluton closely resembles the Hebron and Berlin plutohs which constitute a phase of the Nelspruit batholith. Thus, it is concluded that the Stentor pluton also forms an integral part of the batholith. Three deformation phases have been identified. The regional event affected all stratigraphic units in response to a northerly oriented compressions! stress and gave rise to east-northeasterly trending, tight-.« 5soclinal, upright and north-verging folds that are bounded by southward-dipping longitudinal reverse faults. The regional deformation occurred both prior and subsequent to the emplacement of the Stentor pluton at circa 3100 Ma. Deformation associated with the diapiric intrusion of the Stentor pluton into the greenstone assemblage during the regional deformation pnase, led to the formation of large-scale folds that have modified earlier formed structures. The final deformation episode is manifested by the presence of nortnwest- to northeast-striking, oblique-slip normal faults that exhibit both left- and right-lateral strike-slip components. / AC 2018

The Pletersburg greenstone belt Is located In South Africa, about 300 km northeast of Johannesburg. It hosts a significant amount of gold mineralization and just over 1000 kg of gold have been produced from Its various reefs and secondary deposits. The greenstone belt is interpreted as an Archean ophiolite complex. It comprlses a volcano-sedimentary succession (the Pletersburg Group) which Is subdivided Into a basal greenstone sequence, interpreted as oceanic crust, and an upper sedimentary cover sequence. A number of major shear zones, which are thought to represent thrusts that developed during the subduction of the greenstone sequence, form an integral part of the stratigraphy . Four stages of deformation (D₁-D₄) and four phases of metamorphism (H₁-H₄) (three of which are correlatable with the peak stages of deformation) are recognized. The primary gold deposits are all shear zones related. but they are subdivided into greenstone, sedimentation and granIte-hosted types. Geographically, they occur In three distinct goldfields: Eerstellng, Roodepoort and Marbastad. The greenstone-hosted · Plenaar-Doreen shear complex Is In the Eersteiing goldfield and hosts eight gold occurrences. Within the complex, Girlie North Reef is the 640m-long "pay" section of the Girlie North shear zone. This reef is characterized, macroscopically, by a Quartz-carbonate-chlorite-sulphlde assemblage and, mlcroscoplcally, by the presence of tourmaline, arsenopyrlte and Au. Geochemical evidence Indicates that mineralizing fluids were H₂O and CO₂-bearing and rich In S, K and Al. The wall rock alteratlon was Isochemlcal but Is manifest as a change In mineralogy from a hornblende + plagioclase assemblage to an actlnollte/tremollte + Quartz + clay assemblage. This Is best developed In the hangIng wall of the reef and is thought to have been caused by hydrogen ion metasomatism. The Arsenopyrite Reef was one of the main sediment-hosted shear zone gold producers In the Harabastad goldfield. This reef Is Interpreted as the basal margin of a shear zone whose top contact Is probably represented by the Quartz Vein Reef. The shear zone consists predomonantly of quartz and carbonate, and the two "pay" reefs are characterized by tourmallne. arsenopyrite and Au. No wall rock alteration was identified In this study, Based on the mineralogy and geochemical signature of the Girlie Nortn Reef and the Arsenopyrite Reef, It Is proposed that both were formed at the $The Pletersburg greenstone belt Is located In South Africa, about 300 km northeast of Johannesburg. It hosts a significant amount of gold mineralization and just over 1000 kg of gold have been produced from Its various reefs and secondary deposits. The greenstone belt is interpreted as an Archean ophiolite complex. It comprlses a volcano-sedimentary succession (the Pletersburg Group) which Is subdivided Into a basal greenstone sequence, interpreted as oceanic crust, and an upper sedimentary cover sequence. A number of major shear zones, which are thought to represent thrusts that developed during the subduction of the greenstone sequence, form an integral part of the stratigraphy . Four stages of deformation (D₁-D₄) and four phases of metamorphism (H₁-H₄) (three of which are correlatable with the peak stages of deformation) are recognized. The primary gold deposits are all shear zones related. but they are subdivided into greenstone, sedimentation and granIte-hosted types. Geographically, they occur In three distinct goldfields: Eerstellng, Roodepoort and Marbastad. The greenstone-hosted · Plenaar-Doreen shear complex Is In the Eersteiing goldfield and hosts eight gold occurrences. Within the complex, Girlie North Reef is the 640m-long "pay" section of the Girlie North shear zone. This reef is characterized, macroscopically, by a Quartz-carbonate-chlorite-sulphlde assemblage and, mlcroscoplcally, by the presence of tourmaline, arsenopyrlte and Au. Geochemical evidence Indicates that mineralizing fluids were H₂O and CO₂-bearing and rich In S, K and Al. The wall rock alteratlon was Isochemlcal but Is manifest as a change In mineralogy from a hornblende + plagioclase assemblage to an actlnollte/tremollte + Quartz + clay assemblage. This Is best developed In the hangIng wall of the reef and is thought to have been caused by hydrogen ion metasomatism. The Arsenopyrite Reef was one of the main sediment-hosted shear zone gold producers In the Harabastad goldfield. This reef Is Interpreted as the basal margin of a shear zone whose top contact Is probably represented by the Quartz Vein Reef. The shear zone consists predomonantly of quartz and carbonate, and the two "pay" reefs are characterized by tourmallne. arsenopyrite and Au. No wall rock alteration was identified In this study, Based on the mineralogy and geochemical signature of the Girlie Nortn Reef and the Arsenopyrite Reef, It Is proposed that both were formed at the same time. Textural evidence Indicates that tourmaline, arsenopyrite and Au were all very late In the paragenesis of minerallzatlon. The presence of tourmaline also Indicates a probable granite association. It Is proposed that the maln gold mineralizing event was synchronous with the Intrusion of granitoids (and therefore also with (D₁-D₄) and (H₁-H₄) and that most of the Au was derived from felsic magma. Gold was partitioned Into a magmatic hydrothermal fluid and then transported into the greenstone belt as a chlorIde complex. These magmatiC fluids were channelled up shear zones whIch had already been mineralized with a quartz-carbonate-chlorlte - sulphide assemblage by previous metamorphic fluidS. generated during the dynamic (D₂-related) H₂-phase of metamorphism. The Au was then deposIted as the result of a change In a fluid variable, such as temperature, pH, f0₂, or the activity of Cl (some Au may have been transported In a sulphur complex and so the activity of reduced 5 could also have been Important).

A Thesis submitted to the Faculty of Science, University of the Witwatersrand, in fulfilment of the requirement for the degree of Doctor of Philosophy. Johannesburg March 2016 / This study aims to provide a comprehensive description of the Flora, biogeography and diversity of the serpentine outcrops of Barberton Greenstone Belt in Mpumalanga, South Africa in order to set conservation priorities for these areas. About 30 large and many smaller serpentine outcrops form part of the Barberton Greenstone Belt and consist of various combinations of serpentinized minerals. Seven outcrops were selected to be studied in detail. A floristic analysis recorded 744 species and subspecies, 319 genera and 94 families. The flora includes 33 taxa endemic to serpentine soils and six taxa, which are hyperaccumulators of nickel. The endemic taxa make up 41 % of the endemics of the Barberton Centre of Endemism. The serpentine flora was found to be different to the surrounding non-serpentine vegetation in terms of numbers of species per family, the ratios of dicotyledons to monocotyledons and familial composition. The Asteraceae and the Anacardiaceae support a higher number of endemics than expected, which suggests genetic pre-adaptation within these families and specifically within the genera Berkheya, Helichrysum and Ozoroa. Most of the endemic taxa exhibit long-range dispersal suggesting gene flow between populations on different outcrops. The endemics represent a mix of neo-endemics and paleoendemics. Non-parametric species richness estimators used to predict the species richness of each site, indicated that five serpentine outcrops have higher species richness than the surrounding non-serpentine areas. Indices of diversity calculated showed similar patterns to those of the species richness estimates. The Barberton Greenstone Belt serpentine outcrops show relatively high plant diversity when compared to some other serpentine outcrops around the world. Beta diversity calculated for each site was not correlated with altitude and weakly correlated with the size of outcrops. Species turnover between outcrops is high and is positively correlated with the geographical distance between outcrops. Diversity at higher taxonomic levels were calculated, and results suggest that genera have some potential for facilitating the ranking of outcrops in terms of biological richness to select sites for conservation planning. Less than 30% of serpentine outcrops are adequately conserved. Species and genus richness and endemism were used to select five outcrops that have high conservation priority / MT2016

The distribution of gold in igneous rocks and minerals is described and discussed. Not all the gold in igneous rocks is contained within early formed crystal lattices. Evidence that gold can be associated with late stage crystallizing phases is described. It is concluded that some of the gold in hydrothermal and volcanogenic deposits may have come from a primary magmatic source rather than having been leached from solid country rock. Gold is probably transported as chloride complexes at temperatures greater than about 300°C. At lower temperatures it is probably transported with other metals as sulphide and thio-sulphide complexes. The precipitation of gold from the transporting medium is brought about by changes in the physico-chemical conditions within that medium. Decrease in pressure is probably not a major cause of precipitation in volcanogenic environments. The geology of volcanogenic iron-formations is described and discussed, relative to the development of greenstone belts. Oxide facies iron-formations were formed in shallow oxidizing environments. They are associated with volcanogenic and clastic sediments. Sulphide facies iron-formations were precipitated in the deeper parts of geosynclinal structures. They are associated with mafic and ultramafic rocks similar to modern oceanic volcanic assemblages. Carbonate facies iron-formations were deposited in the regions between oxide facies and sulphide facies. Other banded iron-formations are found associated with base metal massive sulphide deposits related to arctype volcanic centres. These deposits are found in the regions where carbonate facies iron-formations were formed. Exploration for and exploitation of gold deposits in Archaean iron-formations are discussed. Geochemical exploration programmes are aided by the association of gold with trace amounts of base metals. Geophysical exploration methods that can be employed include magnetometer, I.P. and E.M. surveys. The metallurgical treatment of the ores should include "roasting" because a large proportion of the gold occurs as submicroscopic grains within sulphide mineral crystals.

The previously undifferentiated, "Melmoth Granite-Greenstone Remnant" (MGGR¹) crops out over an area of about 360 km² in northern Natal, South Africa. The greenstone sequence is comprised mainly of mafic metalavas with lesser serpentinite, talc schist, dacitic tuff, quartz-muscovite schist, quartzite and calc-silicate rocks. The greenstones are intruded by syntectonic trondhjemitic gneisses, late-tectonic granodioritic gneisses and post-tectonic granite dykes. Four phases of deformation and metamorphism are recognized. Epigenetic, disseminated and quartz vein-hosted gold mineralization is associated with D₂ shearing - a positive correlation existing between the intensity of the shearing, the thickness of the shear zone and the grade of ore it contains. Auriferous quartz veins are distinguished from an earlier generation of barren vein quartz on the basis of mineralogy, texture and relationship to the s-fabric. The mineralization occurs in zones of dilation associated with shear zone refraction. Associated wall rock alteration includes sericitization, argillization and chloritization. An ore genesis model based on the aforementioned parameters, is proposed. Finally, an exploration programme has been devised in order to locate undiscovered gold deposits in the MGGR. The programme could probably be applied, with minor modifications, to shear zone-hosted gold deposits in other granite-greenstone remnants in northern Natal. ¹- Name suggested by writer.

M.Sc. (Geology) / Please refer to full text to view abstract

Thesis (MSc)--Stellenbosch University, 2013. / ENGLISH ABSTRACT: The source of the K2O in the K2O-rich ~3.45 Ga felsic intrusive rocks of the H6 unit in the Hooggenoeg Formation of the Onverwacht Group in the Barberton Granite Greenstone Terrain (BGGT) is examined in this study. This is of particular research interest because the Paleoarchaean rock record is considered to lack K2O-rich magmatic rocks. Previous studies on the felsic igneous rocks of the H6 unit have proposed that these rhyolites are K-metasomatised eruptive equivalents of the sodium-rich ~3.45 Ga TTGs of the BGGT and that the K-feldspar crystals in the rocks formed as a consequence of subsolidus replacement of plagioclase by K-feldspar. Furthermore, the timing of K-metasomatism has previously been related to the formation of the Buck Ridge Chert (BRC), which overlies the H6 unit. However, it has recently been demonstrated from granitic clasts in the conglomerate layer at the base of the Moodies sucession that K2O-rich magmatic rocks formed concurrently with TTG magmas during each of three episodes of TTG magmatism observed in the BGGT. Consequently, the hypothesis of a metasomatic origin for the K2O-rich character of the felsic rocks of the H6 unit requires further examination. Previous studies of the chemistsry of felsic volcanic rocks within the H6 unit were based on relatively low numbers of samples. This study has examined a substantial set of the freshest material available. Two varieties of felsic volcanic rocks were identified; K2O-rich, CaO-poor, Na2O-poor rhyolites and Na2O-rich, CaO-poor, K2O-poor Na-rhyolites. The K2O- rich rhyolite variety is dominant. Consequently, it is possible that the K2O-rich character of these rocks represents a primary magmatic signature. However, this judgment is complicated by the presence of a greenschist-facies metamorphic overprint at 3.2 Ga, which has resulted in complete replacement of micrystalline groundmass and partial replacement of the phenocryst assemblages by greenschist- and sub-greenschist-facies mineral assemblages, which undoubtedly allowed possible shifts in chemical compositions In this thesis, I test the source of K2O in these rocks by using the porphyritic textures of the rocks as an indication of the primary composition of the magmas they were formed from. These textures are typically defined by K-feldspar or albite and quartz phenocrysts within a microcrystalline groundmass. The rocks containing albite are Na-rich (Na-rhyolites) whereas the rocks defined by K-feldspar phenocrysts are rhyolites. XRD study of the structural state of the K-feldspar phenocrysts in the rhyolites indicates that these crystals are orthoclase and intermediate microcline, i.e. medium temperature K-feldspar polymorphs. The modal proportions of K-feldspar, quartz and microcrystalline groundmass in the rhyolites were calculated by using image analysis software. The compositions of the feldspar minerals were determined by electron beam analysis. Minimum bulk rock K2O content of the rhyolites were calculated from the proportions of K-feldspar crystals and their compositions. Even where the proportion of K-feldspar phenocrysts is relatively low (~ 30%), the calculated minimum bulk-rock K2O content is still above 5 wt%. The HREE slope (GdN/LuN) of the felsic porphyritic rocks of the H6 rhyolites is similar to that of ~3.45 Ga TTG plutons and steeper than that of granitic clasts of identical age contained in the basal conglomerate of the Moodies Group. Hence this study has illustrated that the rhyolites of the H6 unit were primary K-feldspar-rich, K2O-rich magmas that formed contemporarily with the ~3.45 Ga TTGs. This implicitly means that rhyolitic volcanism was more wide spread than previously thought in the Paleoarchaean and that it occurred together with the intrusion of the ~3.45 Ga TTGs in the BGGT. / AFRIKAANSE OPSOMMING: Die bron van die K2O in die K2O-ryk ~ 3,45 Ga felsiese vulkaniese rotse van die H6-eenheid in die Hooggenoeg formasie van die Onverwacht Groep in die Barberton Graniet Groensteen Terrein (BGGT) is in hierdie studie ondersoek. Dit is van besondere navorsingsbelang omdat die Paleoargeïse gesteenterekord beskou word as vry van magmatiese K2O ryke gesteentes. Vorige studies oor die felsiese vulkaniese rotse van die H6 eenheid het voorgestel dat hierdie rioliete K-gemetasomatiese eruptiewe ekwivalente van die natrium-ryke ~ 3,45 Ga TTGs van die BGGT is en dat die K-veldspaat kristalle in die gesteentes gevorm is as gevolg van subsolidus vervanging van plagioklaas deur K-veldspaat. Verder is die tydsberekening van K-metasomatisme voorheen gekoppel aan die vorming van die Buck Ridge Chert (BRC) wat die felsiese H6 eenheid bedek. Dit is egter onlangs aangetoon dat K2O-ryke magmatiese rotse gelyktydig met TTG magmas gevorm is tydens elk van drie episodes van TTG magmatisme waargeneem in die BGGT. Gevolglik vereis die hipotese van 'n metasomatiese oorsprong vir die K2O-ryke karakter van die felsiese gesteentes van die H6 eenheid verdere ondersoek. Vorige studies van die felsiese vulkaniese gesteentechemie in die H6 eenheid is gebaseer op 'n relatief klein getal monsters. Hierdie studie het 'n aansienlike stel van die varsste materiaal beskikbaar vir analise ondersoek. Twee variëteite van peralumineuse felsiese vulkaniese gesteentes naamlik 'n K2O-ryk, CaO-arm, Na2O-arm rioliet en Na2O-ryk, CaO-arm, K2O-arm Na-rioliet. Die K2O-ryke rioliet variëteit is meer oorheersend as die Na-rioliete. Dit is dus moontlik dat die K2O-ryk karakter van hierdie rotse 'n primêre magmatiese kenmerke verteenwoordig. Hierdie uitspraak is egter bemoeilik deur die teenwoordigheid van 'n groenskisfasies metamorfe oorprint op 3,2 Ga, wat gelei het tot die volledige vervanging van mikrokrisstalyne grondmassa en gedeeltelike vervanging van fenokrist samestellings deur groenskis en sub-groenskisfasies minerale samestellings en wat ongetwyfeld toegelaat het vir 'n moontlike verskuiwing in chemiese samestelling. In hierdie tesis toets ek die bron van K2O in hierdie gesteentes deur gebruik te maak van die vulkaniese teksture van die gesteentes as 'n aanduiding van die primêre samestelling van die magmas waaruit hulle gevorm het. Hierdie teksture word gewoonlik gedefinieer deur K-veldspaat of albiet en kwarts fenokriste binne 'n grondmassa van wat vroeërglasoorblyfsels was. Die rotse wat albiet bevat is Na-ryk (Na-rioliete) terwyl die rotse gedefinieer deur K-veldspaat fenokriste rioliete is. XRD studie van die strukturele toestand van die K-veldspaat fenokriste in die rioliete dui aan dat hierdie kristalle ortoklaas en intermediêre mikroklien is, dit wil sê die hoër temperatuur K-veldspaat polimorfe. Die modale proporsies van K-veldspaat, kwarts en glasoorblyfsels in die rioliete is akkuraat bereken deur gebruik te maak van beeld analise sagteware. Verder is die samestellings van die veldspaat minerale bepaal deur die elektronstraal analise. Minimum grootmaat rots K2O inhoud van die rioliet is berekén vanaf die fase verhouding van K-veldspaat en hul komposisies. Resultate dui daarop dat selfs waar die verhouding van K-veldspaat phenocrysts is relatief laag (~ 30%), die berekende minimum K2O grootmaat rots samestelling is nog steeds bo 5 wt%. Die REE-helling (GDN / Lun) van felsiese porphyritic rotse van die H6 is soortgelyke relatief tot die REE helling van ~ 3,45 Ga TTGs en steiler REE helling relatief tot granitiese klaste vervat in die basale konglomeraat van die Moodies-groep. Dus het hierdie studie getoon dat die rioliete van die H6-eenheid primêre K-veldspaat-ryke, K2O-ryke en peralumineuse magmas was wat gevorm is terselfdertyd met die ~3,45 Ga TTGs. Dit beteken implisiet dat riolitiese vulkanisme meer wyd verspreid was as wat voorheen gedink is in die Paleoargeïkum en dat dit tesame met die indringing van die ~ 3,45 Ga TTGs in die BGGT plaasgevind het.

The Kalahari Goldridge mine is located within the Archaean Kraaipan Greenstone Belt about 60 km SW of Mafikeng in the Northwestern Province, South Africa. Several gold deposits are located within approximately north - south-striking banded iron-formation (BIF). Current opencast mining operations are focused on the largest of these (D Zone). The orebody is stratabound and hosted primarily in the BIF, which consists of alternating chert and magnetite-chloritestilpnomelane-sulphide-carbonate bands ranging from mm to cm scale. The ore body varies in thickness from 15 to 45 m along a strike length of about 1.5 km. The BlF is sandwiched between a sericite-carbonate-chlorite schist at the immediate footwall and carbonaceous meta-pelites in the hanging-wall. Further west in the footwall, the schists are underlain by mafic meta-volcanic amphibolite. Overlying the hanging-wall carbonaceous metapeiites are schist units and meta-greywackes that become increasingly conglomeratic up the stratigraphy. Stilpnomelane-, chlorite- and minnesotaite-bearing assemblages in the BlFs indicate metamorphic temperatures of 300 - 450°C and pressures of less than 5 kbars. The BIF generally strikes approximately 3400 and dips from 60 to 75°E. Brittle-ductile deformation is evidenced by small-scale isoclinal folds, brecciation, extension fractures and boudinaging of cherty BIF units. Fold axial planes are sub-parallel to the foliation orientation with sub-vertical plunges parallel to prominent rodding and mineral lineation in the footwall. Gold mineralization at the Kalahari Goldridge deposit is associated with two generations of subhorizontal quartz-carbonate veins dips approximately 20 to 40°W. The first generation consists of ladder vein sets (Group lIA) preferentially developed in Fe-rich meso bands, whilst the second generation consists of large quartz-carbonate veins (Group lIB), which crosscut the entire ore body extending into the footwall and hanging-wall in places. Major structures that control the ore body are related to meso-scale isoclinal folds with fold axes subparallel to mineral elongation lineations, which plunge approximately 067°E. These linear structures form orthogonal orientation with the plane of the mineralized shallowdipping veins indicating stretching and development of fluid - focusing conduits. A second-order controlling feature corresponds to the intersection of the mineralized veins and foliation planes of host rock, plunging approximately 008°N and trending 341°. G0ld is closely associated with sulphides, mainly pyrite and pyrrhotite and to a lesser extent with bismuth tellurides, and carbonate gangue. The ore fluid responsible for the gold deposition is in the C-O-H system with increased CH₄ contents attributed to localized hydrolysis reaction between interbedded carbonaceous sediment and ore fluid. The fluid is characterized by significant C0₂ contents and low salinities below 7.0 wt % NaCl equivalent (averages of 3.5 and 3.0 wt % NaCl equivalent for the first and second episodes of the mineralization respectively) . Calculated values of f0₂. ranging from 10⁻²⁹·⁹⁸ to 10⁻³²·⁹⁶ bars, bracket the C0₂-CH₄ and pyrite-pyrrhotite-magnetite buffer boundaries and reveal the reducing nature of the ore fluid at deposition. Calculated total sulphur content in the ore fluid (mΣs), ranges from 0.011 to 0.018M and is consistent with the range (10⁻³·⁵ to 10⁻¹M) reported for subamphibolite facies ore fluids. The close association of sulphides with the Au and nature of the fluid also give credence that the Au was carried in solution by the Au(HS)₂ - complex. Extensive epigenetic replacement of magnetite and chlorite in BIF and other meta-pelitic sediments in the deposit by sulphides and carbonates, both on meso scopic and microscopic scales gives evidence of an interaction by a CO₂- and H₂S-bearing fluid with the Fe-rich host rocks in the deposit. This facilitated Au precipitation due to changes in the physico-chemical conditions of the ore fluid such as a decrease in the mΣs and pH leading to the destabilization of the reduced sulphur complexes. Local gradients in f0₂ may account for gold precipitation in places within carbonaceous sediments. The fineness of the gold grams (1000*Au/(Au + Ag) ranges from 823 to 921. This compares favourably with the fineness reported for some Archaean BIFhosced deposits (851 - 970). Mass balance transfer calculations indicate that major chemical changes associated with the hydrothermal alteration of BIF include enrichment of Au, Ag, Bi, Te, volatiles (S and CO₂), MgO, Ba, K and Rb but significant depletion of SiO₂ and minor losses of Fe₂O₃. In addition, anomalous enrichment of Sc (average, 1247%) suggests its possible use as an exploration tool in the ferruginous sediments in the Kraaipan greenstone terrane. Evidence from light stable isotopes and fluid inclusions suggests that the mineralized veins crystallized from a single homogeneous fluid source during the two episodes of mineralization under the similar physicochemical conditions. Deposition occurred at temperatures rangmg from 350 to 400°C and fluid pressures ranging from 0.7 to 2.0kbars. Stable isotope constraints indicate the following range for the hydrothermal fluid; θ¹⁸H₂O = 6.65 to 10.48%0, 8¹³CΣc = -6.0 to -8.0 %0 and 8³⁴SΣs = + 1.69 to + 4.0%0 . These data do not offer conclusive evidence for the source of fluid associated with the mineralization at the Kalahari Goldridge deposit as they overlap the range prescribed for fluid derived from devolatization of deep-seated volcano-sedimentary piles near the brittle-ductile transition in greenstone belts during prograde metamorphism, and magmatic hydrothermal fluids. / KMBT_363 / Adobe Acrobat 9.54 Paper Capture Plug-in

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