<p><font face="Times New Roman"><font face="Times New Roman"> <p align="left">The research problem for this study is the limited and unsuccessful implementation of the IWRM concept. This thesis has argued that comprehensive assessment of physical and socioeconomic conditions is essential to provide explanation on factors that limit the successful execution of the IWRM approach. It has further argued that the local IWRM works as proxy for full and successful implementation of the IWRM approach. To contextualise this thesis, the prevailing physical and socioeconomic factors in Malawi in relation to current management and usage of water resources were explained. With 1,321m per year, this study showed that Malawi is a physically water stressed country but not physically water scarce country although economically it is a water scarce country. This novelty is against some literature that present Malawi as a water abundant country. Again, this study showed that executing a full and successful IWRM in Malawi remains a challenge because of the prevailing socioeconomic situation in terms of water policies, water laws, institutions and management instruments. These aspects have not been reformed and harmonised to facilitate a successful operation of the IWRM approach. The main water-related problem in Malawi is the mismanagement of the available water resources. This is largely due to the lack of implementing management approaches which can generate systematic data for practical assessment of water resources to guide the coordinated procedure among water stakeholders working in catchments. This lack of implementing a coordinated management approach commonly known as integrated water resources management (IWRM) can be attributed to various reasons that include i) lack of comprehensive assessment of factors that can explain lack of successful IWRM implementation at catchment level and ii) lack of methods to demonstrate data generation and analysis on quantity, quality and governance of water that show practical operation of IWRM at community level using groundwater as a showcase among others. This study revealed that introducing local IWRM requires a prior knowledge of the evolution and role of the full IWRM concept in the international water policy which aimed at addressing broader developmental objectives. Globally, the current status of the IWRM concept has potential to address such broader developmental objectives, but sustaining IWRM projects where they have been piloted showed slow progress. Basing<font face="Times New Roman">&nbsp / on the factors that slow such a progress, local IWRM approach has emerged as a proxy to execute the full IWRM as demonstrated in chapter 8 in this thesis. However, the observed lack of sustainable resources to fund continual functioning of local IWRM activities will defeat its potential solution to water management challenges. The main threat for sustainable local IWRM activities is the tendency of national governments to decentralise roles and responsibilities to local governments and communities without the accompanying financial resources to enable the implementation of the local participation, investments and initiatives at local level. If this tendency could be reversed, the contribution by local IWRM towards solving management problems in the water sector will be enormous. Chapter four has provided the general case-study approach used in this study in terms of research design, data collection methods, data analysis methods, ethical consideration and limitation of the current study within the context of water resource management with a focus on groundwater management. Using geologic map, satellite images, photographs and hydrogeologic conceptual model, the following results emerged: 1) that the Upper Limphasa River catchment has fractured rock aquifer with limited permeability and storage capacity / 2) The topographic nature and north-south strikes of the lineaments explained the north-south flow direction of groundwater in the catchment / 3) The drainage system observed in the Kandoli and Kaning&rsquo / ina Mountains to the east and west of the Upper Limphasa River catchment respectively (Fig. 5.1 / Fig.5.2) formed a groundwater recharge boundary / 4) The regional faults in the same mountains (Fig. 5.1 / Fig.5.2) formed structural boundary as well as hydrogeologic boundary which controlled flow direction of the groundwater / 5) the hydrogeologic conceptual model showed the existence of the forested weathered bedrock in the upland areas of the entire catchment which formed no-flow boundary and groundwater divide thereby controlling the water flow direction downwards (Fig. 5.9) / 6) The major agricultural commercial activities existed in Lower Limphasa catchment while only subsistence farming existed in Upper Limphasa catchment. This knowledge and visualization from the map (Fig. 5.3) and conceptual model (Fig.5.9) showe interactions between upland and lowland areas and the role of physical factors in controlling groundwater flow direction in the catchment. It also provided the enlightenment on implications of socioeconomic farming activities on water management. These insights enabled this study to recommend the need for expedited implementation of holistic effective management for sustainable water utilization. <font face="Times New Roman">Using different physical factors, water scarcity indices and methodologies, this study showed that Malawi is a physically water stressed as well as an economic water scarce country. This novelty is against some literature that present Malawi as a water abundant country. Again, despite the high proportion (85%) of Malawians relying on groundwater resource, groundwater availability (storage in km 6.10) compared to other countries within SADC and Africa. Given the complexity of</font><font face="Times New Roman"> groundwater abstraction, the available groundwater for use is further reduced for Malawians who depend on such a resource for their domestic and productive livelihoods. Such insights provided the basis for discussing the need for IWRM. Although daily statistics on groundwater demand (i: 21.20 litres / 116.91 litres / 80,550.99 litres), use (ii: 16.8 litres / 92.55 litres / 63,766.95 litres) and abstracted but not used (iii: 4.4 / 24.36 / 16,784.04 litres) were relatively low per person, per household and per sub-catchment respectively, such statistics when calculated on monthly basis (i. Demand: 636 litres / 3,507.30 litres / 2,416,529.70 litres / ii.Use:504 litres / 2,776.5 litres / 1, 913, 008.5 litres iii. Abstracted but not used: 132 litres / 730 litres / 503, 521.2) / and on yearly basis (i. Demand: 7,632 litres / 42,087.6 litres / 28,998,356.4 litres / ii. Use: 6,048 litres / 33,318 litres / 22, 956, 102 litres / iii: Abstracted but not used: 1,584 litres / 8,769.6 litres / 6,042,254.4 litres) per person, per household and per sub-catchment provided huge amount of groundwater (Table 6.5). Given the limited storage capacity of fractured rock aquifer in the basement complex geology, the monthly and yearly groundwater demand and use on one hand and abstracted but not used on the other was considered enormous. With the population growth rate of 2.8 for Nkhata Bay (NSO, 2009) and the observed desire to intensify productive livelihoods activities coupled with expected negative effects of climate change, the need to implement IWRM approach for such groundwater resource in the study catchment remains imperative and is urgently needed. In addition to identifying and describing factors that explain the limited groundwater availability in the study catchment, the study developed a methodology for calculating groundwater demand, use and unused at both households and sub-catchment levels. This methodology provided step-by-step procedure for collecting data on groundwater demand and use as a tool that would improve availability of data on groundwater. Implications of such results for IWRM in similar environments were discussed. Despite<font face="Times New Roman">&nbsp / the time-consuming procedure involved in using the developed methodology, the calculations are simple and interpretation of results is easily understood among various stakeholders. Hence, such an approach is recommended for the IWRM approach which requires stakeholders from various disciplines to interact and collaborate. Nonetheless, this recommends the use of this method as its further refinement is being sought. The analysis on groundwater quality has shown that the dominant water type in the aquifers of Upper Limphasa catchment was Ca-HCO had shallow, fresh groundwater with recent recharged aquifer. Analyses on</font><font face="Times New Roman"> physicochemical parameters revealed that none of the sampled boreholes (BHs) and protected shallow dug wells (PSWs) had physical or chemical concentration levels of health concern when such levels were compared with 2008-World Health Organisation (WHO) guidelines and 2005-Malawi Bureau of Standards (MBS). Conversely, although the compliance with 2008-WHO and 2005-MBS of pathogenic bacteria (E.coli) in BHs water was 100% suggesting that water from BHs had low risk and free from bacteriological contamination, water from PSWs showed 0% compliance with 2008- WHO and 2005-MBS values implying high risk to human health. The overall assessment on risk to health classification showed that PSWs were risky sources to supply potable water, hence the need to implement strategies that protect groundwater. On the basis of such findings, the analysis in this study demonstrated the feasibility of using IWRM approach as a platform for implementing environmental and engineering interventions through education programmes to create and raise public awareness on groundwater protection and on the need for collaborative efforts to implement protective measures for their drinking water sources. The use of different analytical methods which were applied to identify the exact sources of the observed contaminants in the PSWs proved futile. Therefore, this study concluded that rolling-out PSWs either as improved or safe sources of drinking water requires further detailed investigations. However, this research recommended using rapid assessment of drinking water-quality (RADWQ) methods for assessing the quality of groundwater sources for drinking. Despite the study area being in the humid climatic region with annual rainfall above 1,000 mm, many of the physical factors were not favourable for availability of more groundwater in the aquifers. Such observation provided compelling evidence in this<font face="Times New Roman">&nbsp / study to commend the local IWRM as a proxy for the full IWRM implementation for sustainable utilization of such waters. Although institutional arrangements, water laws and water policy were found problematic to facilitate a successful implementation of full IWRM at national level in Malawi, this thesis demonstrated that local institutional arrangements, coordination among institutions, data collection efforts by local community members (active participation), self-regulation among local community committees were favourable conditions for a successful local IWRM in the Upper Limphasa River catchment. This research recommends continuation of such local participation, investment and initiatives as proxy for the full and successful IWRM beyond the study catchment. However, the observed lack of financial resource from central government to facilitates local IWRM activities were seen as counterproductive. In addition, this thesis recommended further studies which should aim at improving some observed negative implications of self-regulations on community members and the limited decentralisation elements from the Department of Water Development. Finally, one of the contributions from this study is the scientific value in using different methods to assess the quality of groundwater as presented in chapter 7. The second value is the demonstration of applying practical techniques to evaluate factors that explain the amount of groundwater storage in the aquifers that can be understood by water scientists, water users, water developers and water managers to implement IWRM collaboratively using groundwater as a showcase. The third contribution is the provision of the procedure to systematically generate data on demand (abstraction) and use of groundwater in unmetered rural areas which has the potential to guide water allocation process in the catchment. Fourthly, the thesis has provided a hydrogeologic conceptual model for the first time for Limphasa River catchment to be used as a visual tool for planning and developing management practices and addressing current water problems. Fifthly, the study has shown how local IWRM works at community level as a proxy for the full implementation of IWRM despite the absence of Catchment Management Agencies. The last contribution is the dissemination of results from this study made through publications and conference presentations as outlined in the appendix.</font></font></font></font></p> </font></font></p>

<p><font face="Times New Roman"><font face="Times New Roman"> <p align="left">The research problem for this study is the limited and unsuccessful implementation of the IWRM concept. This thesis has argued that comprehensive assessment of physical and socioeconomic conditions is essential to provide explanation on factors that limit the successful execution of the IWRM approach. It has further argued that the local IWRM works as proxy for full and successful implementation of the IWRM approach. To contextualise this thesis, the prevailing physical and socioeconomic factors in Malawi in relation to current management and usage of water resources were explained. With 1,321m per year, this study showed that Malawi is a physically water stressed country but not physically water scarce country although economically it is a water scarce country. This novelty is against some literature that present Malawi as a water abundant country. Again, this study showed that executing a full and successful IWRM in Malawi remains a challenge because of the prevailing socioeconomic situation in terms of water policies, water laws, institutions and management instruments. These aspects have not been reformed and harmonised to facilitate a successful operation of the IWRM approach. The main water-related problem in Malawi is the mismanagement of the available water resources. This is largely due to the lack of implementing management approaches which can generate systematic data for practical assessment of water resources to guide the coordinated procedure among water stakeholders working in catchments. This lack of implementing a coordinated management approach commonly known as integrated water resources management (IWRM) can be attributed to various reasons that include i) lack of comprehensive assessment of factors that can explain lack of successful IWRM implementation at catchment level and ii) lack of methods to demonstrate data generation and analysis on quantity, quality and governance of water that show practical operation of IWRM at community level using groundwater as a showcase among others. This study revealed that introducing local IWRM requires a prior knowledge of the evolution and role of the full IWRM concept in the international water policy which aimed at addressing broader developmental objectives. Globally, the current status of the IWRM concept has potential to address such broader developmental objectives, but sustaining IWRM projects where they have been piloted showed slow progress. Basing<font face="Times New Roman">&nbsp / on the factors that slow such a progress, local IWRM approach has emerged as a proxy to execute the full IWRM as demonstrated in chapter 8 in this thesis. However, the observed lack of sustainable resources to fund continual functioning of local IWRM activities will defeat its potential solution to water management challenges. The main threat for sustainable local IWRM activities is the tendency of national governments to decentralise roles and responsibilities to local governments and communities without the accompanying financial resources to enable the implementation of the local participation, investments and initiatives at local level. If this tendency could be reversed, the contribution by local IWRM towards solving management problems in the water sector will be enormous. Chapter four has provided the general case-study approach used in this study in terms of research design, data collection methods, data analysis methods, ethical consideration and limitation of the current study within the context of water resource management with a focus on groundwater management. Using geologic map, satellite images, photographs and hydrogeologic conceptual model, the following results emerged: 1) that the Upper Limphasa River catchment has fractured rock aquifer with limited permeability and storage capacity / 2) The topographic nature and north-south strikes of the lineaments explained the north-south flow direction of groundwater in the catchment / 3) The drainage system observed in the Kandoli and Kaning&rsquo / ina Mountains to the east and west of the Upper Limphasa River catchment respectively (Fig. 5.1 / Fig.5.2) formed a groundwater recharge boundary / 4) The regional faults in the same mountains (Fig. 5.1 / Fig.5.2) formed structural boundary as well as hydrogeologic boundary which controlled flow direction of the groundwater / 5) the hydrogeologic conceptual model showed the existence of the forested weathered bedrock in the upland areas of the entire catchment which formed no-flow boundary and groundwater divide thereby controlling the water flow direction downwards (Fig. 5.9) / 6) The major agricultural commercial activities existed in Lower Limphasa catchment while only subsistence farming existed in Upper Limphasa catchment. This knowledge and visualization from the map (Fig. 5.3) and conceptual model (Fig.5.9) showe interactions between upland and lowland areas and the role of physical factors in controlling groundwater flow direction in the catchment. It also provided the enlightenment on implications of socioeconomic farming activities on water management. These insights enabled this study to recommend the need for expedited implementation of holistic effective management for sustainable water utilization. <font face="Times New Roman">Using different physical factors, water scarcity indices and methodologies, this study showed that Malawi is a physically water stressed as well as an economic water scarce country. This novelty is against some literature that present Malawi as a water abundant country. Again, despite the high proportion (85%) of Malawians relying on groundwater resource, groundwater availability (storage in km 6.10) compared to other countries within SADC and Africa. Given the complexity of</font><font face="Times New Roman"> groundwater abstraction, the available groundwater for use is further reduced for Malawians who depend on such a resource for their domestic and productive livelihoods. Such insights provided the basis for discussing the need for IWRM. Although daily statistics on groundwater demand (i: 21.20 litres / 116.91 litres / 80,550.99 litres), use (ii: 16.8 litres / 92.55 litres / 63,766.95 litres) and abstracted but not used (iii: 4.4 / 24.36 / 16,784.04 litres) were relatively low per person, per household and per sub-catchment respectively, such statistics when calculated on monthly basis (i. Demand: 636 litres / 3,507.30 litres / 2,416,529.70 litres / ii.Use:504 litres / 2,776.5 litres / 1, 913, 008.5 litres iii. Abstracted but not used: 132 litres / 730 litres / 503, 521.2) / and on yearly basis (i. Demand: 7,632 litres / 42,087.6 litres / 28,998,356.4 litres / ii. Use: 6,048 litres / 33,318 litres / 22, 956, 102 litres / iii: Abstracted but not used: 1,584 litres / 8,769.6 litres / 6,042,254.4 litres) per person, per household and per sub-catchment provided huge amount of groundwater (Table 6.5). Given the limited storage capacity of fractured rock aquifer in the basement complex geology, the monthly and yearly groundwater demand and use on one hand and abstracted but not used on the other was considered enormous. With the population growth rate of 2.8 for Nkhata Bay (NSO, 2009) and the observed desire to intensify productive livelihoods activities coupled with expected negative effects of climate change, the need to implement IWRM approach for such groundwater resource in the study catchment remains imperative and is urgently needed. In addition to identifying and describing factors that explain the limited groundwater availability in the study catchment, the study developed a methodology for calculating groundwater demand, use and unused at both households and sub-catchment levels. This methodology provided step-by-step procedure for collecting data on groundwater demand and use as a tool that would improve availability of data on groundwater. Implications of such results for IWRM in similar environments were discussed. Despite<font face="Times New Roman">&nbsp / the time-consuming procedure involved in using the developed methodology, the calculations are simple and interpretation of results is easily understood among various stakeholders. Hence, such an approach is recommended for the IWRM approach which requires stakeholders from various disciplines to interact and collaborate. Nonetheless, this recommends the use of this method as its further refinement is being sought. The analysis on groundwater quality has shown that the dominant water type in the aquifers of Upper Limphasa catchment was Ca-HCO had shallow, fresh groundwater with recent recharged aquifer. Analyses on</font><font face="Times New Roman"> physicochemical parameters revealed that none of the sampled boreholes (BHs) and protected shallow dug wells (PSWs) had physical or chemical concentration levels of health concern when such levels were compared with 2008-World Health Organisation (WHO) guidelines and 2005-Malawi Bureau of Standards (MBS). Conversely, although the compliance with 2008-WHO and 2005-MBS of pathogenic bacteria (E.coli) in BHs water was 100% suggesting that water from BHs had low risk and free from bacteriological contamination, water from PSWs showed 0% compliance with 2008- WHO and 2005-MBS values implying high risk to human health. The overall assessment on risk to health classification showed that PSWs were risky sources to supply potable water, hence the need to implement strategies that protect groundwater. On the basis of such findings, the analysis in this study demonstrated the feasibility of using IWRM approach as a platform for implementing environmental and engineering interventions through education programmes to create and raise public awareness on groundwater protection and on the need for collaborative efforts to implement protective measures for their drinking water sources. The use of different analytical methods which were applied to identify the exact sources of the observed contaminants in the PSWs proved futile. Therefore, this study concluded that rolling-out PSWs either as improved or safe sources of drinking water requires further detailed investigations. However, this research recommended using rapid assessment of drinking water-quality (RADWQ) methods for assessing the quality of groundwater sources for drinking. Despite the study area being in the humid climatic region with annual rainfall above 1,000 mm, many of the physical factors were not favourable for availability of more groundwater in the aquifers. Such observation provided compelling evidence in this<font face="Times New Roman">&nbsp / study to commend the local IWRM as a proxy for the full IWRM implementation for sustainable utilization of such waters. Although institutional arrangements, water laws and water policy were found problematic to facilitate a successful implementation of full IWRM at national level in Malawi, this thesis demonstrated that local institutional arrangements, coordination among institutions, data collection efforts by local community members (active participation), self-regulation among local community committees were favourable conditions for a successful local IWRM in the Upper Limphasa River catchment. This research recommends continuation of such local participation, investment and initiatives as proxy for the full and successful IWRM beyond the study catchment. However, the observed lack of financial resource from central government to facilitates local IWRM activities were seen as counterproductive. In addition, this thesis recommended further studies which should aim at improving some observed negative implications of self-regulations on community members and the limited decentralisation elements from the Department of Water Development. Finally, one of the contributions from this study is the scientific value in using different methods to assess the quality of groundwater as presented in chapter 7. The second value is the demonstration of applying practical techniques to evaluate factors that explain the amount of groundwater storage in the aquifers that can be understood by water scientists, water users, water developers and water managers to implement IWRM collaboratively using groundwater as a showcase. The third contribution is the provision of the procedure to systematically generate data on demand (abstraction) and use of groundwater in unmetered rural areas which has the potential to guide water allocation process in the catchment. Fourthly, the thesis has provided a hydrogeologic conceptual model for the first time for Limphasa River catchment to be used as a visual tool for planning and developing management practices and addressing current water problems. Fifthly, the study has shown how local IWRM works at community level as a proxy for the full implementation of IWRM despite the absence of Catchment Management Agencies. The last contribution is the dissemination of results from this study made through publications and conference presentations as outlined in the appendix.</font></font></font></font></p> </font></font></p>

The need to renew and expand civil infrastructure, combined with an increased acknowledgement of a changing climate, has highlighted the need to incorporate the influence of climatic factors into the design of infrastructure. In geotechnical engineering, this includes understanding how climate influences the performance of slopes associated with engineered cuttings in pre- existing natural landforms. This understanding extends to both hydrological and hydrogeological conditions, both of which are often analyzed using numerical modeling of surface water and groundwater. Climate change predictions for Northern Ireland indicate that the amount and intensity of rainfall and extreme weather events will increase. This has raised concerns regarding the stability of existing engineered cut-slopes and the design of future highway and railway infrastructure. Recent studies have indicated that there is a link between pore pressure cycles and softening of slope structures, especially in clay rich materials typical of glacial till drumlins in Northern Ireland. These pore pressure fluctuations are caused by seasonal changes in the rate of recharge which then propagate through the deeper hydrogeologic system. As a consequence, the design of these cuttings requires that the hydrogeological response of these landforms to seasonal climate variations be incorporated into geotechnical designs. Two dimensional hydrogeological simulations are typically used in engineering practice. The main objective of this study was to evaluate the sensitivity of these simulations to dimensionality (two- and three-dimensions). The primary focus was on steady state groundwater flow within two drumlins with large slope cuts. Two- and three-dimensional groundwater models were developed using available information for a highway and a railway study site. The performance of each of these models was then compared to field monitoring from each site. A series of sensitivity studies were undertaken to evaluate the influence of key material properties and boundary conditions. Estimated recharge rates were found to range from 21 to 31 mm year-1 for both the railway (Craigmore) and highway (Loughbrickland) study sites. The hydraulic head distribution at the Craigmore site was similar for both dimensional simulations with a “best-fit” recharge rate of 50 to 60 mm year-1. At the Loughbrickland site, similar hydraulic head distributions with the “best-fit” recharge rate of 80 mm year-1 were reached in both dimensions. Overall, the research completed here emphasized the importance of gathering appropriate data prior to conducting development of hydrogeological models. As more data is made available, the overall complexity of the system can be better understood. As the complexity of the problem increases, the requirements for understanding the hydrogeological system in all three-dimensions becomes more important.

A numerical model was utilized to assess the effects of elevated temperature on the application of in situ chemical oxidation (ISCO) and enhanced in situ bioremediation (EISB) for the subsurface remediation of trichloroethene (TCE) and tetrachloroethene (PCE). Temperature adjustment of the contaminant physicochemical properties as well as the chemical/biological reactions associated with ISCO and EISB were accounted for in the model domain. ISCO reaction rates were estimated using Arrhenius principles; microbial growth rates for EISB were estimated using non-linear fits to published literature data. The results from this study showed that temperature did provide remedial benefits to ISCO and EISB treatment during the short-term timeframe of oxidant/substrate injection. During these time periods, heated ISCO and EISB treatment exhibited greater DNAPL mass removal and mass flux reduction compared to heated abiotic dissolution. In the long term, after oxidant/substrate injection was terminated, the treatment enhancements achieved by ISCO and EISB were negated. Permeability (k) reduction due to rind formation (ISCO) and bioclogging (EISB) inhibited DNAPL dissolution and contributed to greater dissolution tailing effects. Tailing effects caused by ISCO were more severe compared to EISB since rind formation contributed to permanent k reduction; partial k recovery was observed in the EISB scenarios due to biomass decay. Even though higher temperatures were beneficial to ISCO and EISB during the short-term oxidant/substrate injection period, treatment efficacy was ultimately controlled by the detrimental by-products (rind from ISCO and biomass from EISB) formed as a result of the associative chemical/biological reactions. / Thesis (Master, Civil Engineering) -- Queen's University, 2014-02-10 18:59:23.177

Colloid filtration experiments were performed using latex particles (50 nm, 110 nm and 1500 nm) in both the presence and absence of 5.0 mg/L humic acid (HAs). At low ionic strengths (1 -- 10 mM KCl), an increase in attachment efficiency (alpha) with increasing particle size was observed, which contrasts with predictions based on DLVO theory. The presence of HAs generally resulted in a decrease in alpha. Characterization experiments to better understand this behaviour included particle sizing using dynamic light scattering (DLS) and zeta potential using laser Doppler velocimetry (LDV). The particles' hydrodynamic diameters were unchanged in the presence of HAs. HAs lead to an increase in absolute zeta potential for the 50 nm and 110 nm colloids and a decrease in zeta potential for the 1500 nm particles. A discussion of the apparent deviations from Derjaguin-Landau-Verwey-Overbeek (DLVO) theory and explanations for the observed behaviour are provided.

In fractured geologic media, flow and contaminant transport are predominantly controlled by the fractures, their distribution and connectivity. The accurate characterization of fractured geologic medium, imaging of fracture patterns and their connectivity have been a challenge for decades. Given the complexities of fractured networks in the subsurface and Dense Non Aqueous Phase Liquid (DNAPL) contamination, in this thesis, transient hydraulic tomography (THT), a recently developed tool for characterizing aquifer heterogeneity is evaluated under laboratory conditions to delineate discrete fractures. Laboratory experiments and modeling studies are also conducted to understand TCE plume behavior. A dolomite rock sample, which is 91.5 cm in length, 60.5 cm in height and 5 cm thick, was fractured in the laboratory to perform the experiments. After the fractured block was enclosed in a flow cell, flow-through and pumping tests were conducted to characterize the fractured rock block. The data from the pumping tests were then analyzed using the SSLE code developed by Zhu and Yeh [2005] and transient hydraulic tomography (THT) was conducted to image the fracture pattern and their connectivity through the delineation of K and Ss distributions (the tomograms). Synthetic pumping tests, identical in configuration to the laboratory ones were also conducted using HydroGeoSphere (HGS) [Therrien et al, 2009] in a synthetic replica of the fractured block to compare the observed and simulated drawdowns. Then synthetic THT analysis was performed utilizing the synthetic pumping test data to compare the tomograms obtained from the THT analysis of synthetic and laboratory pumping tests. Results suggest that the THT analysis of multiple laboratory pumping tests captured the fracture pattern and their connectivity quite well and they became more vivid with the additional pumping tests. The estimated high hydraulic conductivity (K) and low specific storage (Ss) zones clearly show the fractures and their connectivity. The pattern of K and Ss tomograms obtained from the analyses of synthetic and laboratory pumping tests were similar. Estimated K and Ss values for the fractures and the matrix may not exactly replicate the actual K and Ss values for the fractured rock, but the model also provides uncertainty estimates associated with the resulting K and Ss tomograms. In this study, two cases of transient hydraulic tomography (THT) analysis of the laboratory pumping tests were performed by changing the location of 2nd and 3rd pumping tests among the three to examine if there is any significant impact of these pumped location on the pattern of resulting hydraulic conductivity (K) and specific storage (Ss). The initial pumping test was the same for two cases. Results show that the patterns of estimated K and Ss tomograms obtained from these two cases are similar, although the pumped locations (2nd and 3rd tests among the three) utilized for the inversion were different for two cases suggesting that the location of these later pumping tests does not significantly impact the estimates for this fractured rock block. However, the initial test should be selected carefully as that seems to set the pattern of the tomograms. The estimated K and Ss tomograms were validated by predicting five independent pumping tests conducted in the fractured rock block. These five pumping tests were not included during the construction of the K and Ss tomograms. For most of the independent pumping tests, good correspondence between the simulated and observed drawdown was achieved. The study indicates that, it is possible to delineate discrete fractures, their pattern and connectivity by carefully applying of THT analysis of multiple pumping tests based on the inverse code SSLE [Zhu and Yeh, 2005]. In addition, hydraulic tomography seems to be a cost effective tool for characterizing fractured rock since it does not require the detailed information on fracture geometry parameters such as aperture, trace length, orientation, spatial distribution, and connectivity, which are difficult to quantify. These parameters are usually unavailable between boreholes. Therefore, THT appears to be a promising approach in delineating fractures and their connectivity in subsurface. However, it is still at the early stage as the study was conducted in the laboratory under controlled conditions. Small scale field experiments need to be conducted to validate THT as a tool for the characterization of hydraulic parameters of fractured rocks. Upon completion of the hydraulic characterization, several conservative tracer tests were conducted using bromide (Br-) as a conservative tracer to aid in the design of TCE dissolution experiment. Once the tracer experiments were completed, a known volume of pure phase TCE was injected at a known location in the flow cell to create a well-defined source zone. A constant hydraulic gradient was maintained by fixing the hydraulic heads at the two head tanks to induce steady groundwater flow through the flow cell. Water samples were obtained at a down gradient monitoring port for 3 months to obtain a long-term breakthrough curve of TCE in the aqueous phase. The purpose of this experiment was to study TCE dissolution behaviour in the fractured rock sample. Then HydroGeoSphere (HGS) was used to model the aqueous phase TCE transport using two separate approaches: 1) the Discrete Fracture Network modeling approach and 2) the stochastic continuum approach, to investigate whether they can capture the dissolution behavior. Both approaches were able to capture the pattern of the breakthrough curve in the fractured rock. The discrete fracture approach captured the observed TCE plume and the dissolution behavior quite well. On the other hand, the stochastic continuum approach, in which the fractured rock block was treated as porous medium having a heterogeneous K field obtained from THT analysis, also appeared to be promising in capturing the aqueous phase transport of TCE. Despite some early time deviation, the simulated breakthrough curve captured the overall observed concentration profile. However, the stochastic continuum approach seems to be more cost effective as it does not require detailed information about fracture aperture and their spatial distribution which are difficult if not impossible to obtain between boreholes. Note that, the studies were conducted based on a laboratory experiment conducted in a controlled environment. The experimental block was well characterized and the geometry of the experimental block as well as the flow through the system was well understood from the hydraulic and tracer experiments. Thus small scale field experiment is required to support this conclusion.

With increasing demand and pressures on groundwater resources, accurate and reliable groundwater prediction models are essential for sustainable groundwater management. Groundwater models are merely approximations of reality, and we are unable to either fully characterize or mathematically describe the true complexity of the hydrologic system; therefore, inherent in all models are varying degree of uncertainty. A robust management policy should consider uncertainties in both the imprecise nature of conceptual/numerical models and their parameters. This study addresses the critical question of whether the use of multiple conceptual models to explicitly account for conceptual model uncertainty improves the ability of the models to assist in management decisions. Twelve unique conceptual models, characterized by three alternative geological interpretations, two recharge estimations, and two boundary condition implementations, were formulated to estimate sustainable extraction rates from Thailand’s Thaphra Area, where increasing groundwater withdrawals may result in water level declination and saline water upconing. The models were developed with MODFLOW and calibrated using PEST with the same set of observed hydraulic head data. All of the models were found to reasonably produce predictions of the available heads data. To select the best among the alternative models, multiple criteria have been defined and applied to evaluate the quality of individual models. It was found that models perform differently with respect to different evaluation criteria, and that it is unlikely that a single inter-model comparison criterion will ever be sufficient for general use. The chosen alternative models were applied both individually and jointly to quantify uncertainty in the groundwater management context. Different model-averaging methods were assessed in terms of their ability to assist in quantifying uncertainty in sustainable yield estimation. The twelve groundwater simulation models were additionally linked with optimization techniques to determine appropriate groundwater abstraction rates in the TPA Phu Thok aquifer. The management models aim to obtain maximal yields while protecting water level decline. Despite similar performances among the calibrated models, total sustainable yield estimates vary substantially depending on the conceptual model used and range widely, by a factor of 0.6 in total, and by as much as a factor of 4 in each management area. The comparison results demonstrate that simple averaging achieves a better performance than formal and sophisticated averaging methods such as Maximum Likelihood Bayesian Model Averaging, and produce a similar performance to GLUE and combined-multiple criteria averaging methods for both validation testing and management applications, but is much simpler to implement and use, and computationally much less demanding. The joint assessment of parameter and conceptual model uncertainty was performed by generating the multiple realizations of random parameters from the feasible space for each calibrated model using a simple Monte Carlo approach. The multi-model averaging methods produce a higher percentage of predictive coverage than do any individual models. Using model-averaging predictions, lower optimal rates were obtained to minimize head constraint violations, which do not ensue if a single best model is used with parameter uncertainty analysis. Although accounting for all sources of uncertainty is very important in predicting environmental and management problems, the available techniques used in the literature may be too computationally demanding and, in some cases, unnecessary complex, particularly in data-poor systems. The methods presented here to account for the main sources of uncertainty provide the required practical and comprehensive uncertainty analysis and can be applied to other case studies to provide reliable and accurate predictions for groundwater management applications.

The influence of the viable but non-culturable (VBNC) state on specific phenotypic traits of Escherichia coli O157:H7 as well as its transport behaviour in porous media was examined in this study. E.coli O157:H7 is a human pathogen capable of entering a VBNC state following exposure to sublethal stress. In the VBNC state, E.coli O157:H7 is not detectable by culture assays; yet, is able to retain its ability to cause human illness. This study examined specific transport-related properties of culturable and VBNC E.coli O157:H7 cells. As well, transport behaviors of the two cellular states were compared using sand-packed columns under steady-state flow. When E.coli O157:H7 cells entered a VBNC state, significant decreases in the hydrophobicity and lengths/widths of the cells, and a significant increase in extracellular polymeric substances on the cell surfaces were measured. Transport experiments indicated significantly (p<0.05) greater mass transport of VBNC cells through unwashed sand compared to culturable cells. This research contributes to the current knowledge describing VBNC E.coli O157:H7 cells, raises questions concerning the accuracy of culture-based E.coli O157:H7 identification protocols, and suggests that bacteria transport in the subsurface is a truly dynamic process. / Soil Science

Thesis (Ph. D.)--University of Hawaii at Manoa, 1995. / Includes bibliographical references (leaves 174-180). / Microfiche. / xvii, 180 leaves, bound ill. 29 cm

Thesis (Ph. D.)--University of Hawaii at Manoa, 1995. / Includes bibliographical references (leaves 207-215). / Microfiche. / xiii, 215 leaves, bound maps (some col.) 29 cm