The three-dimensional thermal maturity pattern has been investigated and the hydrocarbon generation potential assessed for the Permian and Triassic sequences of the southern Bowen and northern Gunnedah Basins and the lower part of the overlying Jurassic Cretaceous Surat Basin sequence in northern New South Wales. An oil-source rock correlation also has been investigated in the Gunnedah Basin. Vitrinite reflectance measurements were conducted on 256 samples from 28 boreholes. A total of 50 of these samples were subjected to Rock-Eval pyrolysis analysis, and 28 samples extracted for additional organic geochemical studies (GCMS). A re-evaluation of the stratigraphy in the southern Bowen Basin and a stratigraphic correlation between that area and the northern Gunnedah Basin was also included in the study. An overpressured shaly interval has been identified as a marker bed within the lower parts of the Triassic Moolayember and Napperby Formations, in the Bowen and Gunnedah Basins respectively. Suppressed vitrinite reflectance in the Permian sequence was used as another marker for mapping the stratigraphic sequence in the southern Bowen Basin. The Permian sequence in the Bowen Basin thins to the south, and probably pinches out over the Moree High and also to the west. The coal-bearing Kianga Formation is present in the north and northeastern parts of the study area. A disconformity surface between Digby and Napperby Formations in the Gunnedah Basin is probably time-equivalent to deposition of the Clematis Group and Showgrounds Sandstone in the Bowen Basin. The Clematis Group is absent in the study area, and the Moolayember Formation considered equivalent to the Napperby Formation. Although in many cases core samples were not available, handpicking of coal or shaly materials from cuttings samples where geophysical log signatures identify these materials helped in reducing contamination from caved debris. Histogram plots of reflectance also helped where the target and caved debris were of similar lithology. Vertical profiles of the vitrinite reflectance identified suppressed intervals in the study area due to marine influence (Back Creek Group and Maules Creek Formation) and liptinite rich source organic matter (Goonbri Formation). The suppression occurs due to the perhydrous character of the preserved organic matter. High reflectance values were noted within intrusion-affected intervals, and two types of igneous intrusion profiles were identified; these are simple and complex profiles. An isoreflectance map for the non-suppressed interval at the base of the Triassic sequence in the southern Bowen Basin shows that the organic matter is mature more towards the east close to the Goondiwindi Fault, and also towards the west where the Triassic sequence directly overlies the basement. High values also occur over the Gil Gil Ridge in the middle, to the south over the Moree High, and to the north where the sequence is thicker. The reflectance gradient in the suppressed intervals is higher than in the overlying non-suppressed sequences, especially when the rank has resulted from burial depth. Tmax from Rock-Eval pyrolysis was found to be lower in the perhydrous intervals, and was high in mature and igneous intrusion-affected intervals. Based on the source potential parameters, the Permian Back Creek Group is a better source than the Kianga Formation, while the Goonbri Formation is better than the Maules Creek Formation. The Triassic Napperby Formation has a fair capacity to generate oil, and is considered a better source rock than the equivalent Moolayember Formation. The Jurassic Walloon Coal Measures is a better source than Evergreen Formation, and has the best source rock characteristics, but is immature. The Rock-Eval S1 value shows better correlation with extracted hydrocarbon compounds (saturated and aromatics) than the total extractable organic matter. This suggests that solvent extraction has a greater ability to extract NSO compounds than temperature distillation over the Rock-Eval S1 interval. Terrestrial organic matter is the main source input for the sequences studied. This has been identified from organic petrology and from the n-alkane distributions and the relatively high C29 steranes and low sterane/hopane ratios. The absence of marine biomarker signatures in the Permian marine influenced sequence, could be attributed to their dilution by overwhelming amounts of non-marine organic matter. A mainly oxic to suboxic depositional environment is inferred from trace amounts of 25-NH, BNH and TNH. This is further supported by relatively high pr/ph ratios. Although C29/C30 is generally regarded as an environmental indicator, high values were noted in intrusion-affected samples. The 22S and 20S ratios were inverted ????reaches pseudo-equilibrium???? in such rapidly heated, high maturity samples. The ratio of C24 tetracyclic terpane to C21-C26 tricyclic terpanes decreases, instead of increasing, within the Napperby Formation close to a major igneous intrusive body. The 22S ratio, which is faster in reaction than the other terpane and sterane maturity parameters, shows that the Permian sequence lies within the oil generation stage in the Bowen Basin, except for a Kianga Formation sample. The Triassic sequence is marginally mature, and the Jurassic sequence is considered immature. In the Gunnedah Basin, the Permian sequence in Bellata-1 and Bohena-1, and the Triassic sequence in Coonarah-1A, lie within the oil generation range. In the intrusion-affected high maturity samples, the ratio is reaches pseudo-equilibrium. This and other terpane and sterane maturity parameters are not lowered (suppressed) in the perhydrous intervals. The ???????? sterane ratio, however, is slowest in reaction to maturity, and variations in low maturity samples are mainly due to facies changes. Diasterane/sterane ratios, in the current study, increase with increasing TOC content up to 5% TOC, but decrease in rocks with higher TOC contents including coals. Highly mature samples, as expected, in both cases are anomalous with high ratios. Calculated vitrinite reflectance based on the method of Radke and Welte (1983), as well as MPI 1 and MPI 2, shows the best comparison to observed values. These aromatic maturity parameters are lowered within the reflectance-suppressed intervals. Oil stains in the Jurassic Pilliga Sandstone in the Bellata-1 well have been identified as being indigenous and not due to contamination. The vitrinite reflectance calculated to the oil stain suggests that the source rock should be within a late mature zone. Such high maturity levels are only recognised within intrusion-affected intervals. A close similarity between the oil stain sample and the intruded interval of the Napperby Formation is evident from the thermal maturity and biomarker content. Hydrocarbon generation and expulsion from the lower part of the Napperby Formation as a result of igneous intrusion effects is suggested as the source of the oil in this particular occurrence. Terpane and sterane maturity parameters increase with increasing burial depth in the intervals with suppressed (perhydrous) vitrinite reflectance. The generation maturity parameters also increase through intervals with perhydrous vitrinite, which suggests that hydrocarbons continue to be generated and the actual amount is increasing even though traditional rank ????????????stress???????????? maturity parameters are lowered. Accordingly, the Permian sequences in the lower part of the Bowen Basin are at least within the peak oil generation zone, and probably within late oil generation in the north and northeast of the study area. To generate significant amounts of hydrocarbon, however, the thickness of the shaly and coaly intervals in the Permian sequence is probably a critical parameter. In the Gunnedah Basin, a significant amount of hydrocarbon generation is probably only possible as a result of igneous intrusions.

The three-dimensional thermal maturity pattern has been investigated and the hydrocarbon generation potential assessed for the Permian and Triassic sequences of the southern Bowen and northern Gunnedah Basins and the lower part of the overlying Jurassic Cretaceous Surat Basin sequence in northern New South Wales. An oil-source rock correlation also has been investigated in the Gunnedah Basin. Vitrinite reflectance measurements were conducted on 256 samples from 28 boreholes. A total of 50 of these samples were subjected to Rock-Eval pyrolysis analysis, and 28 samples extracted for additional organic geochemical studies (GCMS). A re-evaluation of the stratigraphy in the southern Bowen Basin and a stratigraphic correlation between that area and the northern Gunnedah Basin was also included in the study. An overpressured shaly interval has been identified as a marker bed within the lower parts of the Triassic Moolayember and Napperby Formations, in the Bowen and Gunnedah Basins respectively. Suppressed vitrinite reflectance in the Permian sequence was used as another marker for mapping the stratigraphic sequence in the southern Bowen Basin. The Permian sequence in the Bowen Basin thins to the south, and probably pinches out over the Moree High and also to the west. The coal-bearing Kianga Formation is present in the north and northeastern parts of the study area. A disconformity surface between Digby and Napperby Formations in the Gunnedah Basin is probably time-equivalent to deposition of the Clematis Group and Showgrounds Sandstone in the Bowen Basin. The Clematis Group is absent in the study area, and the Moolayember Formation considered equivalent to the Napperby Formation. Although in many cases core samples were not available, handpicking of coal or shaly materials from cuttings samples where geophysical log signatures identify these materials helped in reducing contamination from caved debris. Histogram plots of reflectance also helped where the target and caved debris were of similar lithology. Vertical profiles of the vitrinite reflectance identified suppressed intervals in the study area due to marine influence (Back Creek Group and Maules Creek Formation) and liptinite rich source organic matter (Goonbri Formation). The suppression occurs due to the perhydrous character of the preserved organic matter. High reflectance values were noted within intrusion-affected intervals, and two types of igneous intrusion profiles were identified; these are simple and complex profiles. An isoreflectance map for the non-suppressed interval at the base of the Triassic sequence in the southern Bowen Basin shows that the organic matter is mature more towards the east close to the Goondiwindi Fault, and also towards the west where the Triassic sequence directly overlies the basement. High values also occur over the Gil Gil Ridge in the middle, to the south over the Moree High, and to the north where the sequence is thicker. The reflectance gradient in the suppressed intervals is higher than in the overlying non-suppressed sequences, especially when the rank has resulted from burial depth. Tmax from Rock-Eval pyrolysis was found to be lower in the perhydrous intervals, and was high in mature and igneous intrusion-affected intervals. Based on the source potential parameters, the Permian Back Creek Group is a better source than the Kianga Formation, while the Goonbri Formation is better than the Maules Creek Formation. The Triassic Napperby Formation has a fair capacity to generate oil, and is considered a better source rock than the equivalent Moolayember Formation. The Jurassic Walloon Coal Measures is a better source than Evergreen Formation, and has the best source rock characteristics, but is immature. The Rock-Eval S1 value shows better correlation with extracted hydrocarbon compounds (saturated and aromatics) than the total extractable organic matter. This suggests that solvent extraction has a greater ability to extract NSO compounds than temperature distillation over the Rock-Eval S1 interval. Terrestrial organic matter is the main source input for the sequences studied. This has been identified from organic petrology and from the n-alkane distributions and the relatively high C29 steranes and low sterane/hopane ratios. The absence of marine biomarker signatures in the Permian marine influenced sequence, could be attributed to their dilution by overwhelming amounts of non-marine organic matter. A mainly oxic to suboxic depositional environment is inferred from trace amounts of 25-NH, BNH and TNH. This is further supported by relatively high pr/ph ratios. Although C29/C30 is generally regarded as an environmental indicator, high values were noted in intrusion-affected samples. The 22S and 20S ratios were inverted ????reaches pseudo-equilibrium???? in such rapidly heated, high maturity samples. The ratio of C24 tetracyclic terpane to C21-C26 tricyclic terpanes decreases, instead of increasing, within the Napperby Formation close to a major igneous intrusive body. The 22S ratio, which is faster in reaction than the other terpane and sterane maturity parameters, shows that the Permian sequence lies within the oil generation stage in the Bowen Basin, except for a Kianga Formation sample. The Triassic sequence is marginally mature, and the Jurassic sequence is considered immature. In the Gunnedah Basin, the Permian sequence in Bellata-1 and Bohena-1, and the Triassic sequence in Coonarah-1A, lie within the oil generation range. In the intrusion-affected high maturity samples, the ratio is reaches pseudo-equilibrium. This and other terpane and sterane maturity parameters are not lowered (suppressed) in the perhydrous intervals. The ???????? sterane ratio, however, is slowest in reaction to maturity, and variations in low maturity samples are mainly due to facies changes. Diasterane/sterane ratios, in the current study, increase with increasing TOC content up to 5% TOC, but decrease in rocks with higher TOC contents including coals. Highly mature samples, as expected, in both cases are anomalous with high ratios. Calculated vitrinite reflectance based on the method of Radke and Welte (1983), as well as MPI 1 and MPI 2, shows the best comparison to observed values. These aromatic maturity parameters are lowered within the reflectance-suppressed intervals. Oil stains in the Jurassic Pilliga Sandstone in the Bellata-1 well have been identified as being indigenous and not due to contamination. The vitrinite reflectance calculated to the oil stain suggests that the source rock should be within a late mature zone. Such high maturity levels are only recognised within intrusion-affected intervals. A close similarity between the oil stain sample and the intruded interval of the Napperby Formation is evident from the thermal maturity and biomarker content. Hydrocarbon generation and expulsion from the lower part of the Napperby Formation as a result of igneous intrusion effects is suggested as the source of the oil in this particular occurrence. Terpane and sterane maturity parameters increase with increasing burial depth in the intervals with suppressed (perhydrous) vitrinite reflectance. The generation maturity parameters also increase through intervals with perhydrous vitrinite, which suggests that hydrocarbons continue to be generated and the actual amount is increasing even though traditional rank ????????????stress???????????? maturity parameters are lowered. Accordingly, the Permian sequences in the lower part of the Bowen Basin are at least within the peak oil generation zone, and probably within late oil generation in the north and northeast of the study area. To generate significant amounts of hydrocarbon, however, the thickness of the shaly and coaly intervals in the Permian sequence is probably a critical parameter. In the Gunnedah Basin, a significant amount of hydrocarbon generation is probably only possible as a result of igneous intrusions.

Thesis (Ph. D.)--Macquarie University, Division of Environmental & Life Sciences, Department of Earth and Planetary Sciences, 2005. / Includes bibliographical references (leaves 202-224).

Thesis (PhD)--Macquarie University, Division of Environmental & Life Sciences, Department of Earth and Planetary Sciences, 2005. / Bibliography: leaves 202-224. / Introduction -- Geological setting of the New England Fold Belt -- Regional geophysical investigation -- Data acquisition and reduction -- Modelling and interpretation of magnetic data over the Peel Fault -- Modelling and interpretation of magnetic data over the Mooki Fault -- Gravity modelling of the Tamworth Belt and Gunnedah Basin -- Interpretation and discussion -- Conclusions. / This thesis presents new magnetic and gravity data for the Southern New England Fold Belt (SNEFB) and the Gunnedah Basin that adjoins to the west along the Mooki Fault in New South Wales. The SNEFB consists of the Tamworth Belt and Tablelands Complex that are separated by the Peel Fault. The Tablelands Complex to the east of the Peel Fault represents an accretionary wedge, and the Tamworth Belt to the west corresponds to the forearc basin. A total of five east-north-east trending gravity profiles with around 450 readings were conducted across the Tamworth Belt and Gunnedah Basin. Seven ground magnetic traverses of a total length of 60 km were surveyed across the bounding faults of the Tamworth belt, of which five were across the Peel Fault and two were across the Mooki Fault. The gravity data shows two distinct large positive anomalies, one over the Tamworth Belt, known as the Namoi Gravity High and another within the Gunnedah Basin, known as the Meandarra Gravity Ridge. All gravity profiles show similarity to each other. The magnetic data displays one distinct anomaly associated with the Peel Fault and an anomaly immediately east of the Mooki Fault. These new potential field data are used to better constrain the orientation of the Peel and Mooki Faults as well as the subsurface geometry of the Tamworth Belt and Gunnedah Basin, integrating with the published seismic data, geologic observations and new physical properties data. --Magnetic anomalies produced by the serpentinite associated with the Peel Fault were used to determine the orientation of the Peel fault. Five ground magnetic traverses were modelled to get the subsurface geometry of the serpentinite body. Modelling results of the magnetic anomalies across the Peel Fault indicate that the serpentinite body can be mostly modelled as subvertical to steeply eastward dipping tabular bodies with a minimum depth extent of 1-3 km, although the modelling does not constrain the vertical extent. This is consistent with the modelling of the magnetic traverses extracted from aeromagnetic data. Sensitivity analysis of a tabular magnetic body reveals that a minimum susceptibility of 4000x10⁻⁶cgs is needed to generate the observed high amplitude anomalies of around 2000 nT, which is consistent with the susceptibility measurements of serpentinite samples along the Peel Fault ranging from 2000 to 9000 x 10⁻⁶ cgs. Rock magnetic study indicates that the serpentinite retains a strong remanence at some locations. This remanence is a viscous remanent magnetisation (VRM) which is parallel to the present Earth's magnetic field, and explains the large anomaly amplitude over the Peel fault at these locations. The remanence of serpentinite at other localities is not consistent enough to contribute to the observed magnetic anomalies. A much greater depth extent of the Peel Fault was inferred from gravity models. It is proposed that the serpentinite along the Peel Fault was emplaced as a slice of oceanic floor that has been accreted to the front of the arc, or as diapirs rising off the serpentinised part of the mantle wedge above the supra subduction zone. / Magnetic anomalies immediately east of the Mooki Fault once suggested to be produced by a dyke-like body emplaced along the fault were modelled along two ground magnetic traverses and three extracted aeromagnetic lines. Modelling results indicate that the anomalies can be modelled as an east-dipping overturned western limb of an anticline formed as a result of a fault-propagation fold with a shallow thrust step-up angle from the décollement. Interpretation of aeromagnetic data and modelling of the magnetic traverses indicate that the anomalies along the Mooki Fault are produced by the susceptibility contrast between the high magnetic Late Carboniferous Currabubula Formation and/or Early Permian volcanic rocks of the Tamworth Belt and the less magnetic Late Permian-Triassic Sydney-Gunnedah Basin rocks. Gravity modelling indicates that the Mooki Fault has a shallow dip ( ̃25°) to the east. Modelling of the five gravity profiles shows that the Tamworth Belt is thrust westward over the Sydney-Gunnedah Basin for 15-30 km. --The Meandarra Gravity Ridge within the Gunnedah Basin was modelled as a high density volcanic rock unit with a density contrast of 0.25 tm⁻³, compared to the rocks of the Lachlan Fold Belt in all profiles. The volcanic rock unit has a steep western margin and a gently dipping eastern margin with a thickness ranging from 4.5-6 km, and has been generally agreed to have formed within an extensional basin. --The Tamworth Belt, being mainly the product of volcanism of mafic character and thus has high density units, together with the high density Woolomin Association, which is composed chiefly of chert/jasper, basalt, dolerite and metabasalt, produces the Namoi Gravity High. Gravity modelling results indicate that the anomaly over the Tamworth Belt can be modelled as either a configuration where the Tablelands Complex extends westward underthrusting the Tamworth Belt, or a configuration where the Tablelands Complex has been thrust over the Tamworth Belt. When the gravity profiles were modelled with the first configuration, the Peel Fault with a depth extent of around 1 km can only be modelled for the Manilla and Quirindi profiles, modelling of the rest of the gravity profiles indicates that the Tablelands Complex underthrust beneath the Tamworth belt at a much deeper location. / Mode of access: World Wide Web. / xi, 242 leaves ill., maps