Atomic precision measurements provide a strong testing ground for new theoretical ideas and fundamental laws of physics. Measurement of the Lamb shift in the hydrogen atom is one of the best examples towards this -it resulted in the birth of QED in 1949 by Dyson, Feynman, Schwinger and Tomonaga. The precision measurements of the hyperfine structure in hydrogen and deuterium by Nafe, Nelson and Rabi indicated that the g-factor for the electron was not exactly 2 as predicted by Dirac, but slightly greater, due to QED effects. Thus the precision measurements are indispensable not only for developing new theory but also for the verification and fine-tuning of theoretical parameters. Precision measurement of hyperfine structure provide valuable information about the nucleus structure, which is helpful in fine tuning of atomic wave-functions used in theoretical calculations. The aim of the work reported in this thesis is the measurement of hyperfine frequency and the observation of hyperfine structure constant in alkali atoms and in Yb atom. This thesis is organized as follows. In Chapter 1, an introduction to the importance of Alkali atoms and Yb atom in the field of precision measurement will be discussed. The scope of this thesis is also discussed in this chapter. In Chapter 2, an introduction to hyperfine structure starting from the beginning of the atomic physics will be discussed. We have discussed about the LS-coupling, jj-coupling, and the influence of the atomic nucleus on atomic spectra. We have also discussed the Zeeman effect and Doppler broadening. In chapter 3, the detail of experimental technique used in this thesis as copropagating satabs, hyperfine frequency measurement using AOM scan, AOM lock and ring cavity has been discussed. Experimental technique to observe the EIT signal in two electron Yb system has been discussed, which can be improved the precision in frequency measurement because of the narrow line-width. In chapter 4, we describe the co-propagating saturated-absorption spectroscopy and its application in frequency measurement. Saturated-absorption spectroscopy (satabs) in a vapor cell is a standard technique used to stabilise the laser frequency. In normal satabs we are getting some extra peaks known as a crossover peaks because laser interact with different velocity group in a vapor cell. In satabs the crossover peaks are stronger and often swamp the true peaks. So we have developed a technique of co-propagating satabs to remove the spurious peak, which has several advantages over conventional satabs. The co-propagating satabs signal appears on a flat background (Doppler-free) with good signal-to-noise ratio and does not have the problem of crossover resonances in between hyperfine transitions. We have adapted this technique to make measurements of hyperfine intervals by using one laser along with an acousto-optic modulator (to produce the scanning pump beam). In chapter 5, we describe the measurement of the hyperfine interval in the 2P1/2 state of 7Li using the SAS technique in hot Li vapor. This technique produces spurious ground crossover resonances that are more prominent that the real peaks. So we have used this ground crossover to measure the hyperfine interval using AOM locking technique. We have developed a technique to measure the absolute frequencies of optical transitions by using an evacuated Rb-stabilized ring-cavity resonator as a transfer cavity. In chapter 6, we study the wavelength-dependent errors due to dispersion at the cavity mirrors by measuring the frequency of the same transition in the Cs D 2 line (at 852 nm) at three cavity lengths. The spread in the values shows that dispersion errors are below 30 kHz, corresponding to a relative precision of 10−10 . We give an explanation for reduced dispersion errors in the ring-cavity geometry by calculating errors due to the lateral shift and the phase shift at the mirrors, and show that they are roughly equal but occur with opposite signs. In chapter 7, we describe precision measurement of hyperfine structure in the 3P2 state of 171,173Yb, and see an unambiguous signature of the magnetic octupole coefficient C in 173Yb. The frequencies of the 3P23S1 transition at 770 nm → are measured using a Rb-stabilized ring-cavity resonator with an accuracy of 200 kHz. In 173Yb we obtain the hyperfine coefficients as A = − 742.11(2) MHz and B = 1339.2(2) MHz, which represent a two orders-of-magnitude improvement in precision, and C = 0.54(2) MHz. Using atomic-structure calculations for two-electron atoms, we extract the nuclear moments quadrupole Q =2.46(12)b and octupole Ω = 34.4(21)b × µN . The observation of nuclear octupole moment in two-electron atoms, to the best of our knowledge, was never reported before. In 171Yb we obtain the hyperfine coefficient A = 2678.49(8) MHz. Using this measurement as well as the previous measurement of A coefficient from our lab, we have compared the hyperfine anomalies for 1P1, 3P1 and 3P2 states. In chapter 8, we describe the EIT in two electron system of 174Yb from 1S0(Fg = 0) 3P1(Fe = 1). We have observed the EIT in degenerate two level system and → after lifting the degeneracy by applying the magnetic field we are getting five peaks. We have also observed the EIT in 173Yb. In 173Yb there are three degenerate two level system Fg =5/2 Fe =3/2, Fg =5/2 Fe =5/2, Fg =5/2 Fe =7/2. →→→ We have observed the same type of EIT signal for all the three transitions Fg = FFe = F, ±F + 1. → In Chapter 9, we give a broad conclusion to the work reported in this thesis and suggest future avenues of research to continue the work started here.

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Made available in DSpace on 2014-10-09T12:51:12Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T13:56:53Z (GMT). No. of bitstreams: 0 / Neste trabalho investigou-se o comportamento sistemático do campo hiperfino magnético nos compostos intermetálicos Gd(Ni,Pd,Cu)In , Tb(Ni,Pd)In, Dy(Ni,Pd)In e Ho(Ni,Pd)In, com a técnica de Correlação Angular γ-γ Perturbada, nos sítios dos elementos terras raras com o núcleo de prova 140Ce e no sítio do In com o núcleo de prova 111Cd. Os resultados obtidos da dependência com a temperatura do Campo Hiperfino Magnético (Bhf) de cada composto foram primeiramente comparados com a teoria do campo molecular por meio da função de Brillouin, da qual foram extrapolados os valores de saturação de Bhf para cada composto estudado. Os valores extrapolados a zero Kelvin de Bhf (Bhf(T=0)) para os compostos estudados neste trabalho foram usados na comparação com valores de Bhf da literatura para outros compostos contendo o mesmo elemento R (R=Terra Rara). O resultado mostrou uma dependência linear com a temperatura de ordenamento magnético, o mesmo previsto pelo modelo RKKY o que indica que a principal contribuição para Bhf vem da polarização dos elétrons de condução (CEP) via interação de contato de Fermi. O comportamento de Bhf saturado para cada família de compostos de terras raras pesados RNiIn e RPdIn como função da projeção do spin 4f do elemento R mostrou também uma relação linear, com exceção dos resultados para os compostos RNiIn obtidos com 111Cd onde foi observado um leve desvio da linearidade. Foi feita uma investigação dos parâmetros hiperfinos elétricos em função da temperatura para os compostos RPdIn e GdNiIn com o núcleo de prova 111Cd, e os resultados mostram que para o composto GdPdIn pode ocorrer desordem Gd-In a altas temperaturas. / Tese (Doutoramento) / IPEN/T / Instituto de Pesquisas Energeticas e Nucleares - IPEN-CNEN/SP