Harmattan and Dust (sand) storms together with anthropogenic activities including the use of firewood and kerosene as fuel for cooking, and diesel/petrol generators for electricity generation are potential sources of particulate and gaseous pollutants in homes in Damaturu town, Nigeria. Other activities like the burning of locally produced incense and mosquito coils as well as the use of aerosol sprays are further possible sources of indoor pollution, which may result in exposure of people to a range of pollutants through inhalation, by ingestion of settled dusts as well as dermal contact. Local people associate occurrence of dust events with adverse health effects and hence there is a need for an understanding of the composition of the settled and airborne dusts in order to assess the possible associated health risks. The first phase of the study involved selection and development of methods of dust sampling and analysis. For validation of the methods employed and to establish a broad understanding of the characteristics of the settled dusts, an initial survey study was conducted involving the application of thermal desorption/gas chromatography/mass spectrometry (TD/GC/MS) analysis for organic compound analysis, scanning electron microscopy (SEM), inductively coupled plasma-mass spectrometry (ICP-MS) for analysis of metals, and microbiological analysis. Airborne samples were also collected using sorbent tubes to determine organic compounds in air during activities such as cooking with kerosene, gas, and firewood as well as during electricity generation with fossil fuels. Carbon monoxide (CO) and ultrafine particles (UFPs) monitored simultaneously during some of the household activities. The study involved a novel method of extracting organic chemical emissions from dust by heating of the dusts directly in a micro chamber (μ-CTETM) and collection of emissions on sampling tubes. The method provided a relatively quick way of collecting chemical emissions from dusts that are readily available for release. The sampled tubes were analysed by TD/GC/MS. The conventional solvent extraction of the dusts was also carried out and the extracts were analysed by liquid injection-GC/MS and results of the two methods compared. The study determined a number of constituents (metals, SVOCs, phthalates and physical properties) of dusts collected from households in Damaturu during different weather events and from different indoor/outdoor locations; and compared with some UK samples. The samples investigated include dusts deposited; during two notable dusty-weather events (Harmattan and Storm) as well as when there was no notable dust event; during human activities; and dusts from different types of buildings (modern and traditional homes) as well as inside and outside homes. A standard reference material for organic chemicals (SRM 2585) was also analysed. The physical characterization of the settled house dust samples analysed revealed the various shapes and sizes, and elemental composition of the constituents, which included respirable particles. The microbial analysis also indicated the presence of the spores of a host of fungi and bacterial species; and the possible contributions of household activities to the increased production of pollutants (UFP and CO) ascertained. The μ-CTE extraction of the house dusts by heating with TD/GC/MS analysis of the emissions as well as the solvent extraction-GC/MS revealed the presence of many organic chemical compounds with different analytical retention times and varying concentrations in the dust samples. Chemicals of interest quantified: benzene, hexanal, nonanal, diethyl phthalate (DEP), diisobutylphthalate (DIBP), dibutylphthalate (DBP), and diethylhexylphthalate (DEHP). A host of other chemicals commonly present in the analysed samples identified using the NIST library associated with the MS system software. These chemicals included naphthalene and C10-C16 aliphatic and aromatic hydrocarbons, which would need confirmation by running the pure compound samples. There was an observed higher concentration of the chemicals in the solvent extracts than the μ-CTE extracted dust. The higher concentration of the chemicals in the solvent extracts expected due to the aggressive removal of the chemicals by the organic solvent whereas in the case of thermal extraction only the readily available chemicals (loosely bound to the matrix) released by increases in temperature were removed. Generally, the concentrations of the chemicals found were higher in the indoor than in the outdoor dust samples. In the analysis of the dusts collected during weather events; higher chemical concentrations observed in the samples collected during Harmattan period than the other periods. The Harmattan dust period may pose increased exposures to dust and possible health risks. More exposure is expected to occur in the traditional homes compared with the modern homes due to the higher concentrations of the chemicals in both the indoors and the outdoors and this may be especially important to women and children who spend most of their times at home. Metal analysis involved microwave-assisted digestion of the dust samples followed by ICP-MS analysis. The total quant method of metal analysis for a general profiling indicated the presence of more than 50 elemental contaminants in house dust. The results of the quantitative analysis for six target metals: Cd, Cr, Cu, Ni, Pb, and Zn showed their presence in all indoor and the outdoor dust samples. The mean concentrations showed that the metals were in higher concentrations in the indoor dusts than in the outdoor dusts. The quantitative analysis carried out indicated higher metal contents in the storm dusts than the dusts during the other periods. Results of the dusts collected from modern and traditional homes indicated the presence of the metals in higher concentrations in the dusts from traditional homes than the dusts from the modern homes. The estimated mean concentrations of the metals and phthalates inadvertently ingested as a constituent of dust indicated that some of the pollutants could exceed the tolerable daily intake (TDI) due to high exposures to dust expected to be the case in Damaturu. The results of the investigation of the dust composition, combined with information on exposure to dust and pollutants, show that dusts are a risk to the health of people in the Damataru community. Recommendations are made for more studies to provide a better understanding of dust ingestion and exposure to some phthalates and heavy metals in particular and the possible health risks. To the best of my knowledge, this is the first ever research study of airborne and settled dusts undertaken in North-Eastern Nigeria.

<p> The Lower Cretaceous (Albian) Viking Formation at Harmattan East and Crossfield, Alberta, contains two regionally extensive erosion surfaces, VE3 and VE4, separating three allomembers, A-B, D and E. These erosion surfaces can be mapped over large areas of the Alberta basin allowing for the creation of a Viking allostratigraphy. </p> <p> The allostratigraphic base of the Viking alloformation in the study area is informally designated BV. The BV log marker is overlain by allomember A-B, which in turn is overlain by the regionally extensive ravinement surface VE3. The VE3 surface is sharply overlain by allomember D, a northeastward thinning clastic wedge composed of storm dominated facies and nonmarine deposits. Allomember D is in turn overlain by the regionally extensive ravinement surface VE4. Allomember E, which overlies this unconformity is a complex succession of coarse grained facies interbedded with dark mudstones. The upper . part of allomember E is composed of dark mudstones bounded at the top by a regionally extensive condensed section (Base of Fish Scales) that informally marks the allostratigraphic top of the Viking alloformation in the study area. </p> <p> Viking sedimentation began with the deposition of basinal and offshore transitional mudstones, siltstones and sandstones of allomember A-B. A major drop in sea level allowed valleys to incise into these sediments. Nonmarine and upper shoreface deposits of allomember A-B were eroded at Harmattan East during the ensuing transgression that produced the VE3 ravinement surface. A second relative sea level lowering resulted in northeastward progradation of allomember D. Renewed transgression modified the older subaerial erosion surface on top of allomember D, forming the marine ravinement surface VE4 and the overlying deposits of allomember E. Multiple stillstands or slow rates of transgression produced the "steplike" southwestward climbing morphology on the VE4 surface. Fluvial systems supplied coarse sediment to each shoreface incision ("step"). During minor sea level falls, storm and tidal currents reworked sediment at these shorefaces and also transported sediment basinward over older "stepped" shorelines forming onlap markers EO to E5. Continued transgression blanketed the coarse grained interbeds with offshore dark mudstones (Colorado Shale). A major pause in basin deposition led to the formation of a condensed section of fish skeletal remains (Base of Fish Scales). The base of this unit marks the end of Viking depostion in the study area. </p> <p> The Harmattan East Viking oil field is producing from the coarse grained transgressive lag that overlies VE4. It is separated from Caroline field (along depositional strike) by a rise in the VE4 surface. </p> / Thesis / Master of Science (MSc)

Reproduction de : Thèse de doctorat : Sciences de l'univers : Toulon : 2006. / Thèse rédigée en anglais. Titre provenant du cadre-titre. Bibliographie f.107-113.

Les paramètres physiques qui caractérisent les poussières sahariennes en Afrique da l'ouest pendant les mois compris entre novembre et mars de chaque année ont été déterminés sur une longue période de 7 années entre de la période 1997 et 2005. Les mesures ont été effectuées au Ghana. Les concentrations et distributions en taille des particules, le transport et les (lux de dépôt des aérosols sahariennes ont été déterminées dans un intervalle clé 0,5prn à 25pm. Les valeurs moyennées sur toute la saison d'Harmattan montrent des concentrations en nombre comprises entre 24 et 63 particules cm-3 et clés concentrations en masse comprises entre 168 et 1331 pg m-3. La taille (diamètre) moyenne (sur l'ensemble des 7 années] est clé l'ordre de 1,5 /jm. Les résultats montrent des taux de dépôt de 12,7 tonnes/km'/an en 2002 (soit une épaisseur de 4,6 /m de dépôt au sol] et de 31,4 tonnes/km2/an en 3005 (soit une épaisseur de 11¤m)