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Photocopy of typescript. / Digitized by Kansas Correctional Industries

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Thesis (Ph. D.)--University of Washington, 2007. / Vita. Includes bibliographical references (p. 210-216).

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Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Earth and Planetary Science, 1982. / Microfiche copy available in Archives and Science. / Bibliography: leaves 265-290. / by Mark David Kurz. / Ph.D.

The Kane Oceanic Core Complex (OCC) is a valuable window into crustal architecture and chemical composition of the lithosphere beneath a slow-spreading ocean ridge. A suite of > 30 samples (comprised of whole rocks, mineral separates and basalt glasses) has been analyzed for ��He/���He isotope ratios and He concentrations. Gas extraction experiments included crushing in vacuum, step heating and fusion in a high-vacuum furnace. We found ��He/���He in the two freshest peridotites (harzburgite and olivine websterite) to be identical to ratios measured in basalt glasses collected from the Kane fracture zone-ridge axis intersection (8.4���8.7 R[subscript A]). Notably, the freshest and least deformed peridotite (a porphyroclastic harzburgite) has the highest helium content of any of the OCC ultramafic rocks (170 ncc STP/g), while the majority of its helium (70%) is released only upon melting. Lower helium contents (1-45 ncc STP/g) and more variable ��He/���He (2.0-6.3 R[subscript A]) are found in other more altered/deformed peridotite samples (whole rocks, clinopyroxene and orthopyroxene separates). For example, three mylonitized peridotites have lower helium contents compared to the less deformed peridotites. Troctolite intrusions from the Adam and Eve Domes appear to record very late-stage melt impregnation fed through dunite conduits near the MOHO. ��He/���He in these troctolites overlaps with values in the fresh peridotites and axial basalts, but extends to slightly higher values (8.6-9.0 RA). Collectively, fresh Kane peridotites and troctolites having He concentrations above 10 ncc STP/g show ��He/���He ratios of 8.4-9.0 RA that are higher than the median value (8.0-8.2 R[subscript A]) for mid-ocean ridge basalts. This suggests that domains of depleted upper mantle in the Kane region tend to have ��He/���He ratios of 9 RA or higher, similar to what is observed in the most trace-element depleted MORBs globally. Kane gabbroic rocks are more variable in 3He/���He. A subset of gabbros show systematically lower ��He/4He ratios (0.9-7.2 R[subscript A]), with He concentrations of 1-24 ncc STP/g, reflecting the increased importance of atmospheric and radiogenic components in several cases. Nonetheless, two whole rock gabbroic samples plus an amphibole separate have ��He/���He ratios of 7.6-8.0 R[subscript A] and He contents between 13 and 57 ncc STP/g. Variation in the sampling of a lithologically heterogeneous mantle source by the partial melting process may account for the observed ��He/���He variability of 7.6-9.0 R[subscript A] in peridotite, gabbro and basalt in the Kane area. / Graduation date: 2013

abstract: The origin of the solar system and formation of planets such as Earth are among the most fascinating, outstanding scientific problems. From theoretical models to natural observations, it is possible to infer a general way of how the solar system evolved from the gravitational collapse of the molecular cloud to accretion and differentiation of planetary-sized bodies. This dissertation attempts to place additional constraints on the source, distribution, and evolution of chemical variability in the early solar system, Mars, and Earth. A new method was developed for the measurement of titanium isotopes in calcium-aluminum-rich inclusions (CAIs) by laser ablation multi-collector inductively coupled plasma mass spectrometry. The isotopic compositions of 17 Allende CAIs define a narrow range with clearly resolved excesses in 46Ti and 50Ti and suggests that "normal" CAIs formed from a relatively uniform reservoir. Petrologic and isotopic analysis of a new FUN (Fractionated and Unknown Nuclear effects) CAI suggests that normal and FUN CAIs condensed in similar environments, but subsequently evolved under vastly different conditions. Volatiles may have influenced the formation and evolution of basaltic magmas on Mars. Light lithophile element (LLE) and fluorine (F) concentrations and isotopic compositions of pyroxene determined in situ in several Martian meteorites suggests that the primary magmatic signature of LLE and F zonation in Shergottite pyroxene has been disturbed by post-crystallization diffusive equilibration. Using relevant crystal-melt partition coefficients the F contents for Martian meteorite parental melts are ~910 and ~220 ppm. Estimates of the F content in the Shergottite and Nakhlite source regions are similar to that of mid-ocean ridge basalts (MORB) and ocean island basalts (OIB), respectively, here on Earth. Noble gas systematics of OIBs relative to MORBs, suggests OIBs preferentially sample a primordial reservoir located within Earth's mantle. Geodynamic calculations were performed to investigate the time-dependent rate of material entrained into plumes from these primordial reservoirs. These models predict melts rising to the surface will contain variable proportions of primordial material. The results demonstrate that although high 3He/4He ratios may mandate a mantle plume that samples a primordial reservoir, more MORB-like 3He/4He ratios in OIBs do not preclude a deep plume source. / Dissertation/Thesis / Doctoral Dissertation Geological Sciences 2014

We perform high precision measurements of an isotope shift between the two stable isotopes of helium. We use laser excitation of the 2^3 S_1-2^3 P_0 transition at 1083 nm in a metastable beam of 3He and 4He atoms. A newly developed tunable laser frequency selector along with our previous electro-optic frequency modulation technique provides extremely reliable, adaptable, and precise frequency and intensity control. The intensity control contributes negligibly to overall experimental uncertainty by stabilizing the intensity of the required sideband and eliminating the unwanted frequencies generated during the modulation of 1083 nm laser carrier frequency. The selection technique uses a MEMS based fiber switch and several temperature stabilized narrow band (~3 GHz) fiber gratings. A fiber based optical circulator and an inline fiber amplifier provide the desired isolation and the net gain for the selected frequency. Also rapid (~2 sec.) alternating measurements of the 2^3 S_1-2^3 P_0 interval for both species of helium is achieved with a custom fiber laser for simultaneous optical pumping. A servo-controlled retro-reflected laser beam eliminates residual Doppler effects during the isotope shift measurement. An improved detection design and software control makes negligible subtle potential biases in the data collection. With these advances, combined with new internal and external consistency checks, we are able to obtain results consistent with the best previous measurements, but with substantially improved precision. Our measurement of the 2^3 S_1-2^3 P_0 isotope shift between 3He and 4He is 31 097 535.2 (5) kHz. The most recent theoretic calculation combined with this measurement yields a new determination for nuclear size differences between 3He and 4He: ∆r_c=0.292 6 (1)_exp (8)_th (52)_exp fm, with a precision of less than a part in 〖10〗^4 coming from the experimental uncertainty (first parenthesis), and a part in 〖10〗^3 coming from theory. This value is consistent with electron scattering measurement, but a factor of 10 more precise. It is inconsistent (4 sigma) with a recent isotope shift measurement on another helium transition (2^1 S_0-2^3 S_1). Comparisons with ongoing muonic helium measurements may provide clues to the origin of what is currently called the proton puzzle: electronic and muonic measurements of the proton size do not agree. In the future, the experimental improvements described here can be used for higher precision tests of atomic theory and quantum electrodynamics, as well as an important atomic physics source of the fine structure constant.

In this dissertation, I explore elements of the changing Arctic Ocean through the application of Stable Isotope, Noble Gas Isotopes, and sulfur hexafluoride (SF6) to better understand ice dynamics for freshwater balance, air/sea gas exchange and ocean circulation. For the tracer studies of stable isotope fractionation, our approach is to use sea ice core data to determine the stable oxygen isotope effective fractionation coefficient. The result is an average value close to 2.2 ‰, which is compared to literature values. For the tracer studies of air/sea gas exchange, we use Neon (Ne) and Helium (He) isotope data sets collected in the ‘Switchyard’ region of the Arctic Ocean between 2005 and 2013 and in the Greenland and Norwegian seas between 1994 and 1999. The Switchyard data show a distinct excess in Ne concentrations in the upper waters. We hypothesize that rejection of Ne during sea ice formation accounts for the Ne excess in the Switchyard area of the Arctic Ocean. Based on this hypothesis we estimate sea-ice formation rates by integrating the Ne excess from the surface to the Atlantic Water layer. The resulting amount of excess Ne corresponds to formation of a nearly 4 m thick sea ice layer. We compare the sea ice formation obtained from the Ne excess method with an independent estimate based on oxygen isotope ratio anomalies ?18O, which is nearly 6.07 m. The difference in the sea ice formation estimated by these two methods indicates loss of Ne through leads. We estimate that the gas exchange rate through the sea-ice cover is ca. 11.3 percent per year. The gas exchange rate through sea-ice covered water would be 0.015 meters per day. For the tracer studies of mean residence times, we analyzed tritium (3H), helium isotope (3He and 4He) and sulfur hexafluoride (SF6) samples collected in the ‘Switchyard’ region of the Arctic Ocean between 2008 and 2013. We calculated apparent tracer ages using the 3H/3He ratios and the partial pressure of SF6 and compare their values for the depth interval between the surface and the core of the Atlantic Water layer. The apparent tracer ages range from zero to about 30 years. Generally, the linear correlation between the 3H/3He and SF6 apparent ages was strong, with the coefficient of determination R2 of 0.94. We explore deviations from this linear trend and discuss them in the context of mixing, air-sea gas exchange, and the impact of sea ice formation on the helium and SF6 gas balances in the surface mixed layer.