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Elliptical hollow sections (EHS) are the newest steel shape to emerge in the industry, but appropriate design guidance is lacking, being completely absent from Canadian codes and guidelines. Geometric property and compressive resistance tables were established to be potentially added to the Canadian guides. The equivalent RHS method, originally proposed by Zhao and Packer in 2009, was simplified and modified to validate its use for the design of EHS columns and beams. An experimental programme was developed to investigate the behaviour of EHS-to-EHS welded connections. Twelve T and X connection tests were performed to study the effect of connection angle, orientation type and loading. Two methods were developed to predict connection capacities and failure modes: the equivalent CHS and the equivalent RHS approaches. Both methods proved to be conservative on average, but the equivalent RHS approach proved to be more successful at capturing the actual failure mode of EHS-to-EHS connections.

Elliptical hollow sections (EHS) are the newest steel shape to emerge in the industry, but appropriate design guidance is lacking, being completely absent from Canadian codes and guidelines. Geometric property and compressive resistance tables were established to be potentially added to the Canadian guides. The equivalent RHS method, originally proposed by Zhao and Packer in 2009, was simplified and modified to validate its use for the design of EHS columns and beams. An experimental programme was developed to investigate the behaviour of EHS-to-EHS welded connections. Twelve T and X connection tests were performed to study the effect of connection angle, orientation type and loading. Two methods were developed to predict connection capacities and failure modes: the equivalent CHS and the equivalent RHS approaches. Both methods proved to be conservative on average, but the equivalent RHS approach proved to be more successful at capturing the actual failure mode of EHS-to-EHS connections.

Anti-resonant hollow core fibre is a new kind of optical fibre waveguide in which light is trapped in a hollow core surrounded by the capillary formed microstructured cladding. This fibre exhibits high damage threshold, low dispersion and ultra-low nonlinearity with relatively low loss of a few tens of dB/km. Its intrinsic feature of multimode delivery limits the applications with high requirements of single mode transmission. In my thesis, I demonstrate how the design of hollow core fibre can be improved with single mode guidance. S2 imaging measurement was used to analyse the mode content of the solid core fibres. In my research, I established S2 measurement to measure the mode contents in hollow core fibres for the first time. Two hollow core fibres with 8 capillaries and 7 capillaries in their claddings were fabricated in same fashion and showed differences in low attenuations. By comparing the mode contents in both of the fibres via S2 imaging measurement, 7-capillary HCF was demonstrated to give better performance on single mode guidance. Among the applications of the HCF, the property of delivering high power in HCF makes the gas filled HCF laser possible. In my research, a continuous-wave mid-infrared acetylene filled hollow core laser was built with a slope efficiency of 33% and an output power of over 1 watt at the wavelength region of 3.1~3.2 μm. The pump source is an Erbium-doped fibre amplified tunable laser diode which works at C-band wavelength. The fibre without the gain medium has two transmission bands with low attenuation of 0.037 dB/m and 0.063 dB/m at pumping and lasing wavelengths respectively. This laser system works in either cavity-based configuration or single pass ASE configuration. The latter configuration shows a better performance in high output power and high slope efficiency. The optimized laser system was studied experimentally with the proper fibre length and gas pressure. This laser system could be extended to be filled with other molecules to longer wavelengths and has potential for high power output.

Three kinds of propagating waves physically admissible in a tubular section are derived to establish their dispersion characteristics in response to the presence of multi-layered viscoelastic coatings. One is the longitudinal wave that propagates in the axial direction. The other two are shear and longitudinal waves along the circumferential direction. To characterize the hollow cylinder with coating layers, wave dispersion and attenuation are studied using the “global matrix” technique. Since each layer is considered to be perfectly bonded to each other, displacement and strain continuity are imposed as the interfacial boundary conditions. Viscoelastic coating materials such as bitumen and epoxy serve to improve pipeline reliability, but they also dampen and dissipate wave energy. The viscoelastic materials are studied as well. By replacing the real material constants with complex material constants in the characteristic equation, the impact of the viscoelastic coatings on wave dispersion is established. Bisection method is followed to find the real and complex roots of the three characteristic equations derived. Roots thus obtained are manipulated to allow the phase velocity and attenuation dispersion to be plotted against frequency. The dispersion of phase velocity and wave attenuation for coated pipes are evaluated against a baseline model which is the bare, uncoated tubing to establish the propagation characteristics of the guided shear and longitudinal waves in the presence of multiple coating layers. The effects of increasing attenuation parameter and coating thickness are also investigated.

Polymeric hollow fiber sorbents were functionalized with amine moieties for improving the carbon dioxide sorption capacity from flue gas to reduce the greenhouse gas emissions from coal-fired power plants. Three different experimental pathways were studied to form the amine-functionalized hollow fiber sorbents. Aminosilane functionalized cellulose acetate (CA) fibers, polyethyleneimine (PEI) functionalized polyamide-imide (PAI, Torlon®) fibers and PEI post-infused and functionalized Torlon®-silica fibers were formed. CO2 equilibrium sorption capacity data were collected by using the pressure decay sorption cell and thermal gravimetric analyzer. Other physio-chemical properties of the amine-functionalized fiber sorbents were characterized by using fourier-transform infrared spectroscopy, elemental analysis, and scanning electronic microscopy. Different reaction conditions were studied on the effect of sorption isotherms. Aminosilane-CA fibers were the first proof-of-concept for forming the amine functionalized polymer hollow fibers. PEI-PAI fibers were designed as a new method to reach enhanced sorption capacities than Aminosilane-functionalized CA fibers. PEI post-infused and functionalized Torlon®-silica fibers have further enhanced sorption capacity; however they easily degrade with similar reaction for forming PEI-PAI fibers. Lumen-side barrier layers were created successfully via post-treatment technique of using the crosslinked Neoprene® polymer onto PEI-functionalized PAI fibers. PEI-functionalized PAI fibers also have good cyclic stability and low heat of sorption.

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